欢迎登录材料期刊网

材料期刊网

高级检索

开发性能优良的阴极材料是降低中低温(500~800℃)固体氧化物燃料电池(IT-SOFCs)成本的关键.回顾了IT-SOFCs阴极材料的最新研究进展.阴极材料对高电子电导率的需要,使钙钛矿结构氧化物及类钙钛矿结构氧化物在该领域的研究占据主导地位.除了电子电导率外,阴极材料的研究正在转向具有高离子电导率的组分,这种要求使具有无序自由氧离子迁移通道的双钙钛矿结构氧化物和在间隙位置可引入过量氧的K2NiF4结构及其它间隙氧化物最近受到极大的重视.

参考文献

[1] Yamamoto O .Solid oxide fuel cells:Fundamental aspects and prospects[J].Electrochimica Acta,2000,45:2423.
[2] Richter J;Holtappels P;Graule T et al.Materials design for perovskite SOFC cathodes[J].Monatshefte Fur Chemie,2009,140:985.
[3] Skinner S J .Recent advances in perovskite type materials for solid oxide fuel cell cathodes[J].International Journal of Inorganic Materials,2001,3:113.
[4] Sun C W;Hui R;Roller J.Cathode materials for solid fuel cells:A review[J].Journal of Solid State Electrochemistry,2009
[5] Sato K;Kinoshita T;Abe H .Performance and durability of nanostructured (La0.85 Sr0.15)0.98 MnO3 / yttria-stabilized zirconia cathodes for intermediate-temperature solid oxide fuel cells[J].Journal of Power Sources,2010,195:4114.
[6] KaoWX;LeeMC;ChangYC et al.Fabrication and evaluation of the electrochemical performance of the anode-supported solid oxide fuel cell with the composite cathode of La0.8 Sr0.2 MnO3-δ/Gadolinia-doped ceria oxide/ La0.8 Sr0.2-MnO3-δ[J].Journal of Power Sources,2010,195:6468.
[7] Datta P;Bronin D I;Majewski P et al.Cermet cathodes for strontium and magnesium-doped LaGaO3-based solid oxide fuel cells[J].Materials Chemistry and Physics,2009,114:356.
[8] Bidrawn F;Kim G;Gorte R J et al.Dopant to enhance SOFC cathodes based on Srdoped LaFeO3 and LaMnC3[J].Journal of Power Sources,2010,195:720.
[9] Yaroslavtsev, IY;Kuzin, BL;Bronin, DI;Vdovin, GK;Bogdanovich, NM .Cathodes Based on (La, Sr)MnO3 Modified with PrO2-x[J].Russian journal of electrochemistry,2009(8):875-880.
[10] Chang, HC;Tsai, DS;Chung, WH;Huang, YS;Le, MV .A ceria layer as diffusion barrier between LAMOX and lanthanum strontium cobalt ferrite along with the impedance analysis[J].Solid state ionics,2009(4/5):412-417.
[11] Zhao F;Peng R;Xia C .A La0.6Sr0.4CoO3-δ based electrode with high durability or intermediate temperature solid oxide fuel cells[J].Materials Research Bulletin,2008,43(02):370.
[12] Tai LW.;Anderson HU.;Sparlin DM.;Sehlin SR.;Nasrallah MM. .STRUCTURE AND ELECTRICAL PROPERTIES OF LA1-XSRXCO1-YFEYO3 .2. THE SYSTEM LA1-XSRXCO0.2FE0.8O3[J].Solid state ionics,1995(3/4):273-283.
[13] Xia CR.;Rauch W.;Chen FL.;Liu ML. .Sm0.5Sr0.5CoO3 cathodes for low-temperature SOFCs[J].Solid state ionics,2002(1/2):11-19.
[14] Rossignol C;Ralph J M;Bae J M et al.Ln1-x SrxCoO3(Ln=Gd,Pr) as a cathode for intermediate-temperature solid oxide fuel cells[J].Solid-State Ionicis,2004,175:59.
[15] Hansen KK;Hansen KV .A-site deficient (La0.6Sr0.4)(1-s)Fe0.8Co0.2O3-delta perovskites as SOFC cathodes[J].Solid state ionics,2007(23/24):1379-1384.
[16] Shao, ZP;Haile, SM .A high-performance cathode for the next generation of solid-oxide fuel cells[J].Nature,2004(7005):170-173.
[17] Yan A Y;Cheng M J;Dong Y L et al.Investigation of a Ba0.5 Sr0.5 Co0.8 Fe0.2 O3-δ based cathode IT-SOFC:The effect of CO2 on the cell performance[J].Applied Catalysis B:Environmental,2006,66:64.
[18] Efimov K;Xu Q;Feldhoff A.Transmission electron microscopy study of Ba0.5 Sr0.5 Co0.8 Fe0.2 O3-δ perovskite decomposition at intermediate temperatures[J].Chemistry of Materials
[19] Zhu C;Liu X M;Yi C et al.Novel BaCo0.7 Fe0.3-yNbyO3-δ(y=0~0.12) as a cathode for intermediate temperature solid oxide fuel cell[J].Electrochem Cor,2009,11:958.
[20] Vidal K;Rodríguez-Martínezb L M;Arriortua M I et al.The effect of doping in the electrochemical performance of (Ln1-xMx) FeO3-δ SOFC cathodes[J].Journal of Power Sources,2009,192:175.
[21] Hou S;Alonso J A;Rajasekhara S .Defective Ni perovskites as cathode materials in intermediate-temperature solidoxide fuel cells:A structure-properties correlation[J].Chemistry of Materials,2010,22:1071.
[22] Montini T;Bevilacqua M;Fonda E et al.Relationship between electrical behavior and structural characteristics in Srdoped LaNi0.6 Fe0.4 O3-δ mixed oxides[J].Chemistry of Materials,2009,21:1768.
[23] Hou S;Alonso J A;Goodenough J B .Co-free iron perovskites as cathode materials for intermediate-temperature solid oxide fuel cells[J].Journal of Power Sources,2010,195:280.
[24] Kharton VV.;Yaremchenko AA.;Shaula AL.;Patrakeev MV.;Naumovich EN. Loginovich DI.;Frade JR.;Marques FMB. .Transport properties and stability of Ni-containing mixed conductors with perovskite- and K2NiF4-type structure[J].International Journal of Quantum Chemistry,2004(1):26-37.
[25] Kilner JA.;Shaw CKM. .Mass transport in La2Ni1-xCoxO4+delta oxides with the K2NiF4 structure[J].Solid state ionics,2002(Pt.B):523-527.
[26] Skinner SJ.;Kilner JA. .Oxygen diffusion and surface exchange in La2-xSrxNiO4+delta[J].Solid state ionics,2000(1/4):709-712.
[27] Ishihara T;Miyoshi S;Furuno T;Sanguanruang O;Matsumoto H .Mixed conductivity and oxygen penneability of doped Pr2NiO4-based oxide[J].Solid state ionics,2006(35/36):3087-3091.
[28] Mauvy F.;Bassat JM.;Boehm E.;Manaud JP.;Dordor P.;Grenier JC. .Oxygen electrode reaction on Nd2NiO4+delta cathode materials: impedance spectroscopy study[J].Solid state ionics,2003(1/2):17-28.
[29] Aguadero, A;Alonso, JA;Escudero, MJ;Daza, L .Evaluation of the La2Ni1-xCUxO4+delta system as SOFC cathode material with 8YSZ and LSGM as electrolytes[J].Solid state ionics,2008(11/12):393-400.
[30] Montenegro Hernández A;Mogni L;Caneiro A .La2 NiO4+δas cathode for SOFC:Reactivity study with YSZ and CGO electrolytes[J].International Journal of Hydrogen Energy,2010,35:6031.
[31] Anderson P S;Kirk C A;Knudsen J et al.Structural characterizations of REBaCo2 O6-δ phases (RE =Pr,Nd,Sm,Eu,Gd,Tb,Dy,Ho)[J].Solid State Sciences,2005,7(10):1149.
[32] A.A. Taskin;A.N. Lavrov;Yoichi Ando .Fast oxygen diffusion in A-site ordered perovskites[J].Progress in Solid State Chemistry,2007(2/4):481-490.
[33] Frontera C;Caneiro A;Carrillo A E et al.Tailoring oxygen content on PrBaCo2O5+δ.layered cobaltites[J].Chemistry of Materials,2005,17(22):5439.
[34] Albert Tarancon;Stephen J. Skinner;Richard J. Chater .Layered perovskites as promising cathodes for intermediate temperature solid oxide fuel cells[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(30):3175-3181.
[35] Tarancon A;Pena-Martinez J;Marrero-Lopez D;Morata A;Ruiz-Morales JC;Nunez P .Stability, chemical compatibility and electrochemical performance of GdBaCo_2O_5+x layered perovskite as a cathode for intermediate temperature solid oxide fuel cells[J].Solid state ionics,2008(40):2372-2378.
[36] Kim J H;Cassidy M et al.Advanced electrochemical properties of LnBa0.5Sr0.5Co2O5+δ(Ln=Pr,Sm,and Gd)as cathode materials for IT-SOFC[J].Journal of the Electrochemical Society,2009,156(06):B682.
[37] Kim Y N;Kim J H;Manthiram A .Effect of Fe substitution on the structure and properties of LnBaCo2-xFexO5+δ(Ln=Nd and Gd) cathodes[J].Journal of Power Sources,2010,195:6411.
[38] Chen D;Ran R;Shao Z P et al.Intermediate temperature electrochemical performance of a polycrystalline PrBaCo2O5+δ cathode on samarium-doped ceria electrolyte[J].Journal of Power Sources,2009,188:96.
[39] Zhou Q;He T;He Q et al.SmBaCo2O5+δdouble-perovskite structure cathode material for intermediate temperature solid oxide fuel cells[J].Journal of Power Sources,2008,185:754.
[40] Zhou QJ;He TM;He Q;Ji Y .Electrochemical performances of LaBaCuFeO5+x and LaBaCuCoO5+x as potential cathode materials for intermediate-temperature solid oxide fuel cells[J].Electrochemistry communications,2009(1):80-83.
[41] Packer, RJ;Stuart, PA;Skinner, SJ .Structural characterisation of the Ce1-xLaxNbO4+delta solid solution series: In-situ high-temperature powder diffraction studies[J].Journal of Solid State Chemistry,2008(6):1445-1455.
[42] Vullum, F;Grande, T .Oxygen stoichiometry and transport properties of cerium niobate[J].Solid state ionics,2008(21/26):1061-1065.
[43] Skinner S J;Packer R J;Bayliss R D.Redox chemistry of the novel fast oxide ion conductor CeNbO4+δ determined through an in-situ spectroscopic technique[J].Solid-State Ionicis,2010
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%