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Mn distribution and austenite morphology at the early stage of intercritical annealing of 5Mn steel were investigated. It was experimentally demonstrated that a newly formed 20 nm-thick austenite was formed without the partitioning of Mn. The el-emental analysis conifrmed that the growth of austenite should be controlled by the diffusion of C prior to the diffusion of Mn at a low heating rate. The austenite growth started under negligible-partitioning local equilibrium mode and then switched to partition-ing local equilibrium mode. Mn segregation at the γ/α interface suggested that the collector plate mechanism was the essential way of Mn partitioning at the early stage of austenite growth.

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