溶液pH对电沉积氧化亚铜薄膜的影响

电镀与涂饰 , 2010, 29(6): 4-7.

溶液pH对电沉积氧化亚铜薄膜的影响

胡飞 ^1, , 胡澄清 ^2, , 刘建成 ^3, , 罗凌虹 ^4, , 吴坚强 ^5,

1.景德镇陶瓷学院,江西,景德镇,333001

2.江西陶瓷工艺美术职业技术学院,江西,景德镇,333001

3.景德镇陶瓷学院,江西,景德镇,333001

4.景德镇陶瓷学院,江西,景德镇,333001

5.景德镇陶瓷学院,江西,景德镇,333001

基金项目: 江西省教育厅基金(GJJ09531) 景德镇市科技局项目江西省科技支撑项目

关键词：氧化亚铜 , 薄膜 , 电沉积 , pH , 择优取向 , 光学性能

Effect of pH on electrodeposition of copper(Ⅰ) oxide

采用醋酸铜-醋酸钠酸性溶液和硫酸铜-乳酸碱性溶液,分析了不同pH下电沉积Cu2O薄膜的形貌及结构,讨论了镀液体系及溶液pH对Cu2O薄膜生长的影响,测定了不同形貌的Cu2O薄膜的光学透射性能.结果表明,溶液的氢氧根、羧基、羟基中的氧原子会影响Cu2O薄膜的结构及形貌.酸性溶液中,Cu2O薄膜易形成混晶结构;而碱性溶液中,随着pH的变化,Cu2O薄膜有不同的择优取向.酸性溶液中Cu2O薄膜形成网状结构,碱性溶液中易形成锥形结构.

参考文献

[1]	OLSEN L C;ADDIS F W;MILLER W .Experimental and theoretical studies of Cu2O solar cells[J].Solar Cells,1982,7(03):247-279.
[2]	OLSEN L C;BOHARA R C;URIE M W .Explanation for low-efficiency Cu2O Schottky-barrier solar cells[J].Applied Physics Letters,1979,34(01):47-49.
[3]	周延春;SWITZER J .溶液温度对电化学沉积氧化亚铜薄膜相成分和显微结构的影响[J].材料研究学报,1996,10(05):512-516.
[4]	Y. Tang;Z. Chen;Z. Jia .Electrodeposition and characterization of nanocrystalline cuprous oxide thin films on TiO_2 films[J].Materials Letters,2005(4):434-438.
[5]	Wijesundera RP;Hidaka M;Koga K;Sakai M;Siripala W .Growth and characterisation of potentiostatically electrodeposited CU2O and Cu thin films[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):241-246.
[6]	Fang Sun;Yupeng Guo;Wenbo Song;Jingzhe Zhao;Lanqin Tang;Zichen Wang .Morphological control of Cu_2O micro-nanostructure film by electrodeposition[J].Journal of Crystal Growth,2007(2):425-429.
[7]	LEOPOLD S;HERRANEN M;CARLSSON J-O et al.In situ pH measurement of the self-oscillating Cu(Ⅱ)-lactate system using an electropolymerised polyaniline film as a micro pH sensor[J].Journal of Electroanalytical Chemistry,2003,547(01):45-52.
[8]	Wang LC;de Tacconi NR;Chenthamarakshan CR;Rajeshwar K;Tao M .Electrodeposited copper oxide films: Effect of bath pH on grain orientation and orientation-dependent interfacial behavior[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2007(5):3090-3095.
[9]	Gao XD;Peng F;Li XM;Yu WD;Qiu JJ .Growth of highly oriented ZnO films by the two-step electrodeposition technique[J].Journal of Materials Science,2007(23):9638-9644.
[10]	陈志钢,唐一文,贾志杰,张丽莎,李家麟,余颖.导电玻片上氧化亚铜膜的电沉积和表征[J].无机材料学报,2005(02):367-372.

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材料期刊网

溶液pH对电沉积氧化亚铜薄膜的影响

Effect of pH on electrodeposition of copper(Ⅰ) oxide

参考文献