采用溶胶-凝胶法制备了一种新型高岭土/二氧化钛纳米复合电流变液材料.XRD、FT-IR、SEM分析表明TiO2以纳米晶的形态包覆于高岭土表面.电流变性能测试表明,不同的TiO2质量比的复合颗粒电流变液效应不同,且都比纯高岭土电流变有显著提高.同时当复合颗粒中TiO2质量百分比在34%,颗粒硅油体积分数为25%,直流电场为3kV/mm时,高岭土/二氧化钛纳米复合材料电流变液的静屈服应力达3.4kPa,是纯高岭土电流变液的5倍.
Kaolinite/TiO2 nanocomposite particles were prepared by sol-gel technique. The analysis of XRD,FT-IR and SEM shows that the surface of kaolinite is coated by nano-TiO2 crystal. Furthermore the electrorheological effect is associated with the TiO2 mass percent in the nanocomposite particle. When the content of TiO2 in the composite is 34%, E=3kV/mm, and volume fraction is 25%, the yield stress of kaolinite/TiO2 nanocomposite ERF is 3.4 kPa, which is 5 times of that of kaolinite.
参考文献
[1] | Block H, Kelly J P. J. Phys. D: Appl. Phys., 1988, 21: 1661--1667. [2] Halsay T C. Science, 1992, 258: 761--766. [3] 尹剑波, 赵晓鹏. 材料导报, 2000, 14 (9): 10--13. [4] Wang B X, Zhao X P. J. Mater. Chem., 2002, 12: 2869--2871. [5] 董岩, 朱以华, 匡继, 等(DONG Yan, et al). 无机材料学报(Journal of Inorganic Materials), 2001, 16 (5): 839--845. [6] Zhao X P, Yin J B. Chem. Mater., 2002, 14: 2258--2263. [7] Frost R L, Tran T H, Kristof J. Clay Minerals, 1997, 32: 587--596. [8] Wang B X, Zhao X P. J. Mater. Chem., 2002, 12: 1865--1869. [9] 王宝祥, 李佳, 赵晓鹏. 化学学报, 2003, 61 (2): 240--244. [10] 赵晓鹏, 王宝祥, 左朝阳. 高岭土/二氧化钛纳米复合颗粒电流变液材料及其制?备方法. 中国发明专利, 03114668.6,2003. [11] Frost R L, Kristof J, Horvath E, et al. J. Colloid Interface Sci., 1999, 214: 380--388. [12] 赵晓鹏, 尹剑波, 向礼琴. 材料研究学报, 2000, 14: 604--608. |
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