熔融盐法是利用熔融盐作反应物或兼作熔剂,在固液态间进行反应,可以有效降低反应温度和缩短反应时间,合成出符合计量比以及结晶发育良好的正极材料,是合成锂离子正极插层材料一种新的有效的方法.分析了镍系锂离子电池正极材料的结构特点和现阶段存在的问题,并就近年来国内外关于采用熔融盐法合成镍系锂离子电池正极材料的现状,结合实际的研究情况进行了综述.
参考文献
[1] | Nishida Y;Nakane K;Satoh T .Synthesis and properties of gallium-doped LiNiO2 as the cathode material for Lithium secondary batteries[J].Journal of Power Sources,1997,68(02):561. |
[2] | C.-C. Chang;J. Y. Kim .Synthesis and Electrochemical Characterization of Divalent Cation-Incorporated Lithium Nickel Oxide[J].Journal of the Electrochemical Society,2000(5):1722-1729. |
[3] | Pouillerie C.;Croguennec L. .Synthesis and characterization of New LiNi_(1-y)Mg_yO_2 Positive Electrode Materials for Lithium Ion Batteries[J].Journal of the Electrochemical Society,2000(6):2061-2069. |
[4] | Guilmard M;Rougier A;Grune M et al.Effects of alumi num on the structural and electrochemical properties of LiNiO2[J].Journal of Power Sources,2003,115(02):305. |
[5] | Wulff H.;Rao MM.;Scholz F. .Crystallographic evidence for the formation of a continuous series of mixed crystals between NiO and LiNiO2[J].Chemistry of Materials,2003(4):988-993. |
[6] | Tsutomu Ohzuku;Atsushi Ueda;Masatoshi Nagayama.Comparative study of LiCoO2,LiNi1/2CO1/2O2 and LiNiO2 for 4 Volt secondary lithium cells[J].Electrochimica Acta,1993(38):1159. |
[7] | Kanno R;Kubo H;Kawamoto Y et al.Phase relationship and lithium deintercalation in lithium nickel oxides[J].Journal of Solid State Chemistry,1994,110(02):216. |
[8] | Lee K K;Yoon W S;Kim K B et al.Thermal behavior and the decomposition mechanism of electrochemically delithiated Li1-xNiO2[J].Journal of Power Sources,2001,97-98:321. |
[9] | Arai H;Sakurai Y .Characteristics of LixNiO2 obtained by chemical delithiation[J].Journal of Power Sources,1999,81-82:401. |
[10] | Li W.;Currie C. .MORPHOLOGY EFFECTS ON THE ELECTROCHEMICAL PERFORMANCE OF LINI1-XCOXO2[J].Journal of the Electrochemical Society,1997(8):2773-2779. |
[11] | Lee Yun-sung Sun;Yang-Kook;Nahm Kee-suk.Synthesis and characterization of LiNiO2 cathode material prepared by an adiphic acid-assisted sol-gel method for lithium secondary batteries[J].Solid-State Ionicis,1999(18):159. |
[12] | Kweon H J;Kim G B;Lim H S.Synthesis of LixNi0.85Co0.15O2 the PVA-precursor method and charge-discharge characteristics of a lithium ion battery using this material as cathode[J].Journal of Power Sources,1999(83):84. |
[13] | Ni J F;Zhou H H;Chen J T et al.Molten salt synthesis and electrochemical properties of spherical LiFePO4 particles[J].Materials Letters,2007,61(4-5):1260. |
[14] | Han Chi-Hwan;Hong Young-Sik;ParkChang Moon et al.Synthesis and electrochemical properties of lithium cobalt oxidesprepared by molten-salt synthesis using theeutectic mixture of LiCl-Li2CO3[J].Journal of Power Sources,2001,92:905. |
[15] | Kim J H;Myung S T;Sun Y K .Molten salt synthesis of LiNi0.5Mn1.5O4 spinel for 5 V class cathode material of Li-ion secondary battery[J].Electrochimica Acta,2004,49(02):219. |
[16] | Wen L;Lu Q;Xu G X .Molten salt synthesis of spherical LiNi0.5Mn1.5O4 cathode materials[J].Electrochimica Acta,2006,51(21):4388. |
[17] | Reddy M V;Subba Rao G V;Chowdari BVR .Synthesis and electrochemical studies of the 4V cathode,Li (Ni2/3Mn1/3)O2[J].Journal of Power Sources,2006,160(02):1369. |
[18] | Reddy M V;Subba Rao G;Chowdari BVR .Synthesis by molten salt and cathodic properties of Li (Ni1/3CO1/3Mn1/3)O2[J].Journal of Power Sources,2006,159(01):263. |
[19] | Ha H W;Jeong K H;Kim K .Effect of titanium substitution in layered LiNiO2 cathode material prepared by molten salt synthesis[J].Journal of Power Sources,2006,161(01):606. |
[20] | Jeong K H;Ha H W;Nan J Y et al.Zr-doped Li[Ni0.5-xMn0.5-xZr2x]O2 (x=0,0.025) as cathode material for lithium ion batteries[J].Electrochimica Acta,2005,50(27):5349. |
[21] | 汤宏伟,朱志红,常照荣,陈中军.低共熔混合锂盐相图的绘制及应用[J].物理化学学报,2007(08):1265-1268. |
[22] | 常照荣,齐霞,吴锋,汤宏伟,徐秋红.固相-熔融盐法合成LiNiO2粉体及其电化学性能[J].硅酸盐学报,2006(03):329-333. |
[23] | 常照荣,齐霞,吴锋,汤宏,孙东.低共熔混合锂盐合成LiNi0.8Co0.2O2的研究[J].应用化工,2005(09):535-538. |
[24] | 常照荣,齐霞,吴锋,汤宏伟,王蒋亮.低共熔混合锂盐合成Co和Al共掺杂的LiNiO2[J].化学工程,2006(12):50-53. |
[25] | 汤宏伟,朱志红,常照荣,陈中军.高密度锂离子正极材料前驱体Ni0.8Co0.2(OH)2的制备[J].功能材料,2007(10):1717-1719. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%