目前,鲜见研究杂质元素含量对铝合金牺牲阳极性能影响的报道.浇铸了不同Si含量的Al-5.00Zn-0.02In-1.00Mg-0.05Ti-xSi-0.10Fe-0.01Cu(质量分数,%)铝合金阳极.采用电化学方法、电感耦合等离子体质谱仪(ICP-MS)和金相显微镜对不同Si含量阳极在海水中的形貌、Al,Zn元素溶解量及电化学性能进行了研究.结果表明:Si的加入改善了铝合金的组织均匀性,Al-5.00Zn-0.02In-1.00Mg-0.05Ti-0.09Si(%)铝合金中的等轴晶较多,阳极表面溶解均匀,电流效率达到92%以上;该合金阳极在0.1 mol/L NaCl溶液中浸泡2h后的Al和Zn溶解量分别为23.00,4.40 g/L,在由海水和Ⅺ组成的溶液中浸泡2,48 h后的扫描电流峰值分别为27,36uA,耐蚀性较强.
参考文献
[1] | Norris JC.;Alexander MR.;Blomfield CJ.;Grundwell RF.;Scantlebury JD. .Quantitative analysis of indium and iron at the surface of a commercial Al-Zn-In sacrificial anode[J].Surface and Interface Analysis: SIA: An International Journal Devoted to the Development and Application of Techniques for the Analysis of Surfaces, Interfaces and Thin Films,2000(1):170-175. |
[2] | Despic A R;Stevanovic R M;Vorkapic A M.A new method of obtaining electrochemically active aluminum[A].Berkeley,1984:A2-19. |
[3] | GB/T 4948-2002.铝-锌-铟系合金牺牲阳极[S]. |
[4] | DNV RP-B401-2005.Cathodic Protection Design[S]. |
[5] | H. Ahlatci .Production and corrosion behaviours of the Al–12Si–XMg alloys containing in situ Mg_2Si particles[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2010(1):122-126. |
[6] | Xu D K;Birbilis N;Lashansky D et al.Effect of solution treatment on the corrosion behaviour of aluminum alloy AA7150:Optimisation for corrosion resistance[J].Corrosion Science,2011,53(01):217-225. |
[7] | 沈行素;吴琦;蒋建新 .Fe、Si杂质含量对电解电容器低压阳极铝箔静电容量的影响[J].电子元件与材料,1995,14(01):1-7. |
[8] | Saffar A H;Ashworth V;Grant W A et al.The role of mercury in the dissolution of aluminum sacrificial anodes:A study using ion implantation[J].Corrosion Science,1978,18(08):687-700. |
[9] | 侯德龙,宋月清,李德富,沈健.铝基牺牲阳极材料的研究与开发[J].稀有金属,2009(01):96-100. |
[10] | William A. Ferrando .Development of a novel composite aluminum anode[J].Journal of Power Sources,2004(1/2):309-314. |
[11] | 赵婷婷,冉伟,齐公台.铝合金牺牲阳极电流效率的损耗分析[J].材料保护,2007(04):58-60. |
[12] | 李凯,马力,闫永贵,吴建华,陈光章.低驱动电位牺牲阳极的研究[J].材料保护,2010(04):95-97. |
[13] | 傅高升,康积行.工业纯铝中铁和硅的作用分析与初探[J].特种铸造及有色合金,1999(Z1):29. |
[14] | The effects of lanthanum on microstructure and electrochemical properties of Al-Zn-In based sacrificial anode alloys[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2009(9):2115. |
[15] | Saidman SB.;Bessone JB.;Garcia SG. .ELECTROCHEMICAL BEHAVIOUR OF AL-IN ALLOYS IN CHLORIDE SOLUTIONS[J].Journal of Applied Electrochemistry,1995(3):252-258. |
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