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采用脱氯化氢的方法合成了聚（2-甲氧基-5-十二烷氧基）对苯乙炔（PMODOPV）。利用热蒸发法在铜基片上制备氧化锌纳米线,以此为负极直接旋涂聚合物溶液,制备结构为氧化铟锡（ITO）/聚乙撑二氧噻吩-聚（苯乙烯磺酸盐）（PEDOT∶PSS）/PMODOPV/ZnO/Cu的光伏器件。考察了器件的光伏特性以及纳米线的加入对光伏器件的影响。研究发现,加入ZnO纳米线制备的器件具有高的开路电压和短路电流,在标准AM1.5太阳光模拟灯照射下（1000W/cm^2）,器件的短路电流达到了5.37×10^-3A/cm^2,开路电压达到了1.01V,功率转换效率相应地达到了1.37%,其中功率转换效率与没有掺杂氧化锌纳米线的PMODOPV器件相比有明显提高。文中在氧化锌纳米线上旋涂PMODOPV获得活性层,从其膜表面的SEM图中可以看出,氧化锌纳米线类似网状的交织在聚合物的膜层中,纳米线与聚合物实现了微观尺度的结合。

Poly（2-methoxyl-5-dodecoxyl p-phenyl vinylene）（PMODOPV） was prepared by dehydrochlorination process with p-methoxylphenol and p-diphenol as raw materials.The zinc oxide nanowires,which were formed on the Cu substrates,were used directly as negative electrode materials for photovoltaic devices.As the active layer,the dissolved PMOCOPV was spin-coated on the nanowires.The photovoltaic devices were made with the structure of indium tin oxide（ITO）/poly（3,4-ethylenedioxythiophene）-poly（styrenesulfonate）（PEDOT∶PSS）/PMOCOPV/ZnO/Cu.The solar power conversion efficiency of PMODOPV/ZnO nanowires device is 1.37%,the short-circuit current density（Jsc） and open-circuit voltage（Voc） are 5.37×10^-3 A/cm^2,1.01V respectively.SEM images of ZnO nanowires overlaid of PMODOPV indicate that ZnO nanowires are coated by polymer,and a micrometer-scale combination is achieved.