{"currentpage":1,"firstResult":0,"maxresult":10,"pagecode":5,"pageindex":{"endPagecode":5,"startPagecode":1},"records":[{"abstractinfo":"通过硅烷偶联剂改性的BaTiO3粒子与聚酰胺酸溶液共混成膜、亚胺化后制备出高介电常数聚酰亚胺/BaTiO3复合膜.考察了BaTiO3粒子的体积分数、粒径大小、偶联剂的种类与用量、频率等对介电性能的影响.研究发现,通过使用偶联剂对BaTiO3粒子进行表面改性、增加粒子的粒径都可以有效提高复合膜的介电常数,膜的介电常数随BaTiO3粒子的体积分数的增加而增加,由粒径为100nm改性BaTiO3制备的复合膜, BaTiO3的体积分数为0.5时,膜在10kHz电场中的介电常数达到35.","authors":[{"authorName":"刘卫东","id":"58ced8ce-ef0f-41d6-9d11-a58044e97653","originalAuthorName":"刘卫东"},{"authorName":"刘小芬","id":"53d22486-1c27-422d-a123-4eec56b23f4c","originalAuthorName":"刘小芬"},{"authorName":"朱宝库","id":"1449d2ba-555c-4992-9541-00a1b460a3e7","originalAuthorName":"朱宝库"},{"authorName":"","id":"29256e45-e7e5-4e17-98f1-f3d930fb647c","originalAuthorName":"谢曙辉"},{"authorName":"徐志康","id":"b2f2c84f-72ec-4ff9-a6d0-7bbbc69827d1","originalAuthorName":"徐志康"}],"doi":"","fpage":"1106","id":"b43b5414-5b19-46d9-be12-4488174da340","issue":"7","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d3a604c7-816f-4d00-8cb4-0b6b1653845e","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"60b2579b-e838-4277-bdf1-bc04ca15ea7b","keyword":"钛酸钡","originalKeyword":"钛酸钡"},{"id":"02bf73e3-7001-4270-982a-26fe77f4bc46","keyword":"复合膜","originalKeyword":"复合膜"},{"id":"b924476a-44b9-4e0c-b070-61470f45761f","keyword":"介电性能","originalKeyword":"介电性能"}],"language":"zh","publisherId":"gncl200707018","title":"聚酰亚胺/钛酸钡复合膜介电性能及其影响因素的研究","volume":"38","year":"2007"},{"abstractinfo":"介绍了dendrimer的模板作用及其用于制备金属、硫化物、合金及高分子等纳米粒子的研究现状,分析了dendrimer的种类和结构、代数、浓度及pH值等对纳米粒子的影响.","authors":[{"authorName":"","id":"8c6a3bf9-30ac-4c6b-8019-121eb7e7548f","originalAuthorName":"谢曙辉"},{"authorName":"朱宝库","id":"52b18a7f-1713-4879-b0dc-43fc6c95b5df","originalAuthorName":"朱宝库"},{"authorName":"魏秀珍","id":"52d8495b-b281-4d20-80ca-95c03069da15","originalAuthorName":"魏秀珍"},{"authorName":"徐志康","id":"b41c3021-cfa4-4b95-8849-e379ad6a6ed7","originalAuthorName":"徐志康"},{"authorName":"徐又一","id":"04e8be94-65c2-4989-85d4-b693c5f3bd09","originalAuthorName":"徐又一"}],"doi":"","fpage":"488","id":"bbbfad0d-600f-446c-9a17-ee974ecf5eab","issue":"5","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d9c34c92-0c55-4a9b-8282-6bb1dfbd2bda","keyword":"超支化高分子","originalKeyword":"超支化高分子"},{"id":"7078e9ee-4ddb-48f6-bee8-5a3841727ce0","keyword":"模板","originalKeyword":"模板"},{"id":"f5ed51c5-abd7-4a88-a97e-359cf4f4c5eb","keyword":"金属","originalKeyword":"金属"},{"id":"7fd2456c-4222-4bc2-8ab4-cba00e0e7298","keyword":"纳米粒子","originalKeyword":"纳米粒子"}],"language":"zh","publisherId":"gncl200305004","title":"Dendrimer的模板作用及其在纳米粒子制备中的应用","volume":"34","year":"2003"},{"abstractinfo":"通过Micheal加成和胺解的交替反应,制得末端基为氨基的聚酰胺-胺型树状分子(PAMAM);研究了第7代PAMAM(G7-NH2)在制备铜纳米粒子过程中的模板作用,通过紫外光谱和透射电镜表征了铜粒子的形成过程以及所得铜粒子的大小.结果表明,铜离子不仅与G7-NH2内部叔胺基形成络合物,还与树状分子外部的伯胺基形成络合物;在得到铜粒子的过程中,G7-NH2具有内模板和外模板作用,铜纳米粒子的尺寸随着铜离子与G7-NH2浓度比例的提高而增大;同时,由于铜纳米粒子为G7-NH2模板所包裹,使其在水中具有良好的分散均匀性和稳定性.但在有氧条件下,铜粒子很容易被氧化为G7-NH2(Cu2+)n络合离子.","authors":[{"authorName":"魏秀珍","id":"47b3dd00-8b30-4e59-8375-6afd3e56e9bf","originalAuthorName":"魏秀珍"},{"authorName":"朱宝库","id":"ec769247-ccc8-4844-8b9b-168bce66ec02","originalAuthorName":"朱宝库"},{"authorName":"","id":"9aef473e-4827-4d90-b6fa-bf371c14caf9","originalAuthorName":"谢曙辉"},{"authorName":"徐又一","id":"6579e2e0-2ca1-469e-b4ce-efc3776f7a6f","originalAuthorName":"徐又一"}],"doi":"","fpage":"1242","id":"ca182145-516e-4269-9273-9a53dc360647","issue":"8","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"f0358734-2049-4bc7-9376-faa4cc5f4d73","keyword":"树状分子","originalKeyword":"树状分子"},{"id":"953f9eb9-6628-48df-9ccb-3c4a8ac1e47c","keyword":"PAMAM","originalKeyword":"PAMAM"},{"id":"4bd918c8-0faf-4ea7-8810-98ff8ec81f66","keyword":"模板作用","originalKeyword":"模板作用"},{"id":"6d8f58b5-16d3-4aa0-9a90-5c6320632cf2","keyword":"铜粒子","originalKeyword":"铜粒子"},{"id":"c25f3673-ab08-4ca4-a8b2-298bc5add9c0","keyword":"稳定化","originalKeyword":"稳定化"}],"language":"zh","publisherId":"gncl200508031","title":"胺基端基树状分子在铜纳米粒子形成过程中的模板及稳定化作用","volume":"36","year":"2005"},{"abstractinfo":"通过将聚酰胺酸溶液与硅烷偶联剂处理的钛酸钡(BaTiO3) 粒子进行溶液共混,亚胺化后得到高介电常数的聚酰亚胺/BaTiO3复合膜.改性后的BaTiO3粒子可以均匀地分散在聚酰亚胺基体中, 制备过程中BaTiO3粒子未发生经晶型改变,而聚酰亚胺分子链的堆积密度有所变化.复合膜的介电常数和介电损耗随着BaTiO3粒子含量的增加而增加,在50%(体积分数)时,介电常数可达35,介电损耗为0.0082(10kHz),而且在相当大的温度和频率范围内保持稳定,是一种综合性能良好的高介电常数材料.","authors":[{"authorName":"朱宝库","id":"5818977b-9180-4c92-a491-e43b100d9d7b","originalAuthorName":"朱宝库"},{"authorName":"","id":"4689612f-f075-4205-a5e8-b6934b8ee2d1","originalAuthorName":"谢曙辉"},{"authorName":"徐又一","id":"224a4dc0-43ba-4425-991f-cd343dd94cbe","originalAuthorName":"徐又一"},{"authorName":"徐志康","id":"15d83566-eeb4-4dcd-8b46-79f023888517","originalAuthorName":"徐志康"}],"doi":"","fpage":"546","id":"d41cd131-1285-481e-866d-eb29cae947fb","issue":"4","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"683fc67f-89a3-4c6a-912b-301c3f5d626b","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"1f003bbb-8743-460a-848d-7372f861de1a","keyword":"钛酸钡","originalKeyword":"钛酸钡"},{"id":"a43f162a-9725-42d4-bf87-b7c506f53775","keyword":"复合膜","originalKeyword":"复合膜"},{"id":"99746318-968b-4375-876a-64963f9b9a54","keyword":"介电性能","originalKeyword":"介电性能"}],"language":"zh","publisherId":"gncl200504019","title":"高介电常数聚酰亚胺/钛酸钡复合膜的制备与性能研究","volume":"36","year":"2005"},{"abstractinfo":"采用溶胶-凝胶法合成出Li和Ti改性的氧化镍(LTNO)粒子,并通过前体溶液共混法首先制备聚酰胺酸/LTNO前体膜,再经亚胺化得到高介电常数聚酰亚胺/LTNO复合膜.研究发现,复合膜的介电性能可以通过调节LTNO的含量以及Li和Ti在LTNO中的比例来进行调控.选用按Li、Ni和Ti的摩尔百分比为0.30:0.68:0.02制备的LTNO粒子做填料,当其体积分数为0.4时,复合膜在100 Hz电场中的介电常数可以达到570.","authors":[{"authorName":"刘卫东","id":"57ddfeae-ff66-412c-85d7-5e0d85d75a48","originalAuthorName":"刘卫东"},{"authorName":"朱宝库","id":"962c138b-0616-40d2-9821-0f51864c8bb0","originalAuthorName":"朱宝库"},{"authorName":"","id":"0bec4a24-edbe-4e9c-9c74-e627aeb937e3","originalAuthorName":"谢曙辉"},{"authorName":"徐志康","id":"61bb5fd6-9bad-4e85-8426-6bd5ad51d765","originalAuthorName":"徐志康"}],"doi":"","fpage":"73","id":"e45c9d5f-2421-4df6-b2e4-81eeadc2bd80","issue":"2","journal":{"abbrevTitle":"GFZCLKXYGC","coverImgSrc":"journal/img/cover/GFZCLKXYGC.jpg","id":"31","issnPpub":"1000-7555","publisherId":"GFZCLKXYGC","title":"高分子材料科学与工程"},"keywords":[{"id":"fd1b43a8-4dd2-46ab-8d89-840d1604162e","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"a431446a-21a7-49e9-81b7-d9a97fdb960f","keyword":"Li和Ti改性的氧化镍","originalKeyword":"Li和Ti改性的氧化镍"},{"id":"309a0cfc-0fdc-4da6-80ce-a92034349565","keyword":"复合膜","originalKeyword":"复合膜"},{"id":"ab7cc260-cbff-48ce-96d1-3c77c30ad758","keyword":"介电性能","originalKeyword":"介电性能"}],"language":"zh","publisherId":"gfzclkxygc200902022","title":"聚酰亚胺/LTNO复合膜介电性能及其影响因素","volume":"25","year":"2009"},{"abstractinfo":"通过前体溶液共混和原位聚合两种方法首先制备聚酰胺酸/BaTiO3前体膜,再经亚胺化得到高介电常数聚酰亚胺/BaTiO3复合膜.考察了不同制备方法、BaTiO3粒子的粒径大小、填充方式等对介电性能的影响.研究发现,通过增加粒子的粒径、使用原位聚合法和采用双模式填充方法都可以有效提高复合膜的介电常数.使用单模式填充方法,由粒径为100nm的改性BaTiO3通过原位聚合法制备得到的复合膜,当BaTiO3的体积分数为0.5时,在10kHz电场中膜的介电常数可以达到45.","authors":[{"authorName":"刘卫东","id":"8f16920a-f2f3-4dd4-ad79-3b355f17a26a","originalAuthorName":"刘卫东"},{"authorName":"朱宝库","id":"f0406b8a-15f6-4a30-9228-74720b5eb271","originalAuthorName":"朱宝库"},{"authorName":"","id":"12d1e627-0f94-419e-b874-e2e9930cc55a","originalAuthorName":"谢曙辉"},{"authorName":"徐志康","id":"aa0f1a5b-cec3-4387-8b28-186604c8bf35","originalAuthorName":"徐志康"}],"doi":"","fpage":"264","id":"e5f72777-15be-4010-a014-5c9c94b9c0b0","issue":"2","journal":{"abbrevTitle":"GNCL","coverImgSrc":"journal/img/cover/GNCL.jpg","id":"33","issnPpub":"1001-9731","publisherId":"GNCL","title":"功能材料"},"keywords":[{"id":"d0935da7-597e-41b4-9ff5-956e1f5e9e07","keyword":"聚酰亚胺","originalKeyword":"聚酰亚胺"},{"id":"905eedcc-63d9-4a86-926a-d239c2cab0a3","keyword":"钛酸钡","originalKeyword":"钛酸钡"},{"id":"bceb6e10-3ec3-44d8-b12d-8f2f4f4c785b","keyword":"复合膜","originalKeyword":"复合膜"},{"id":"206670e9-0b40-47cf-95ba-b47880a1374e","keyword":"介电性能","originalKeyword":"介电性能"}],"language":"zh","publisherId":"gncl200802026","title":"聚酰亚胺/钛酸钡复合膜介电性能及其影响因素的研究(Ⅱ)","volume":"39","year":"2008"},{"abstractinfo":"以Zn(NO3)2红的混合溶液为沉积液,采用阴极电化学沉积法在ITO导电玻璃上制备了纳米多孔ZnO/红复合膜.考察了电化学预处理过程和红浓度对薄膜晶体结构、微观形貌和光学性能的影响.结果表明,引入短时间的电化学预处理过程能提高复合薄膜中ZnO的结晶质量,并诱导ZnO沿c轴定向生长.随着电沉积液中染料浓度的增大,所得薄膜的结晶质量下降,薄膜由六角晶颗粒逐渐向纳米多孔结构转变.当沉积液中红浓度为50μmol/L 时所得复合薄膜具有最大膜厚,装载的红量最高.以该复合膜为光阳极制作了太阳能电池原型器件,其开路电压为0.49V,短路电流为0.67mA/cm2,总光电转换效率为0.105%.
","authors":[{"authorName":"甘小燕","id":"8050054d-7490-45c1-acb9-5491b1d63cea","originalAuthorName":"甘小燕"},{"authorName":"李效民","id":"5da665eb-e6d5-4160-96c6-4e3cfc9e565b","originalAuthorName":"李效民"},{"authorName":"高相东","id":"aa8af556-21d2-45a1-b853-d646fa03b2dc","originalAuthorName":"高相东"},{"authorName":"于伟东","id":"adc3cd8f-6dec-4570-bf53-76d16f7547db","originalAuthorName":"于伟东"},{"authorName":"诸葛福伟","id":"f78c4b3b-1231-4e9d-96d6-65f0d1f76215","originalAuthorName":"诸葛福伟"}],"categoryName":"|","doi":"10.3724/SP.J.1077.2009.00073","fpage":"73","id":"7c5477a0-66ec-462c-90e7-e334bef120d4","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"c35b98ff-18e1-4ae0-a1ee-73721e678d83","keyword":"ZnO","originalKeyword":"ZnO"},{"id":"993647dd-a73c-4425-af60-10c99eedfa16","keyword":" Eosin Y","originalKeyword":" Eosin Y"},{"id":"df5f1990-5232-4dfa-b0a1-2d2fdde97684","keyword":" electrodeposition","originalKeyword":" electrodeposition"},{"id":"d7a77995-1cfb-40b7-b070-482112687348","keyword":" dye-sensitised solar cell","originalKeyword":" dye-sensitised solar cell"}],"language":"zh","publisherId":"1000-324X_2009_1_12","title":"电化学沉积法制备纳米多孔ZnO/红复合薄膜","volume":"24","year":"2009"},{"abstractinfo":"以Zn(NO3)2和红的混合溶液为沉积液,采用阴极电化学沉积法在ITO导电玻璃上制备了纳米多孔ZnO/红复合膜.考察了电化学预处理过程和红浓度对薄膜晶体结构、微观形貌和光学性能的影响.结果表明,引入短时间的电化学预处理过程能提高复合薄膜中ZnO的结晶质量,并诱导ZnO沿c轴定向生长.随着电沉积液中染料浓度的增大,所得薄膜的结晶质量下降,薄膜由六角晶颗粒逐渐向纳米多孔结构转变.当沉积液中红浓度为50μmol/L 时所得复合薄膜具有最大膜厚,装载的红量最高.以该复合膜为光阳极制作了太阳能电池原型器件,其开路电压为0.49V,短路电流为0.67mA/cm2,总光电转换效率为0.105%.","authors":[{"authorName":"甘小燕","id":"e224fb9b-f61a-44fb-85b3-28536e1661c0","originalAuthorName":"甘小燕"},{"authorName":"李效民","id":"ec7f0405-dfcc-4588-83b0-1980dd3c8803","originalAuthorName":"李效民"},{"authorName":"高相东","id":"86b9a57b-44fd-4107-9bb4-d964a723813a","originalAuthorName":"高相东"},{"authorName":"于伟东","id":"cb77f0d4-d62e-4c26-baca-f78dabd26685","originalAuthorName":"于伟东"},{"authorName":"诸葛福伟","id":"ab2d9711-c91f-44f1-b1a7-975ca92f0e49","originalAuthorName":"诸葛福伟"}],"doi":"","fpage":"73","id":"52b9ada3-aa72-4234-9f3c-7a054ab3b572","issue":"1","journal":{"abbrevTitle":"WJCLXB","coverImgSrc":"journal/img/cover/WJCLXB.jpg","id":"62","issnPpub":"1000-324X","publisherId":"WJCLXB","title":"无机材料学报"},"keywords":[{"id":"9420b651-b558-4c64-85b3-c461256fb0be","keyword":"ZnO","originalKeyword":"ZnO"},{"id":"be15765d-4a46-49f0-afeb-980ae194053c","keyword":"红","originalKeyword":"曙红"},{"id":"b9285961-2798-4354-985a-f3216b821f65","keyword":"电化学沉积","originalKeyword":"电化学沉积"},{"id":"0b8e4fc4-e8f6-44f4-8501-1b765f58f81e","keyword":"染料敏化太阳能电池","originalKeyword":"染料敏化太阳能电池"}],"language":"zh","publisherId":"wjclxb200901016","title":"电化学沉积法制备纳米多孔ZnO/红复合薄膜","volume":"24","year":"2009"},{"abstractinfo":"研究了染料红B与盐酸异丙嗪的结合反应.在pH=3.50的Walpole介质中,红B本身的共振光散射信号较弱,与盐酸异丙嗪结合形成离子缔合物后,体系的共振光散射明显增强,并且光散射增强强度与盐酸异丙嗪在一定浓度范围内成正比,据此建立了一种高灵敏测定盐酸异丙嗪的方法.在体系的最大散射波长363 nm处,测得盐酸异丙嗪的线性范围为7.5×10-8~4.5×10-6 g/mL,检测限为1.8×10-8 g/mL,用于盐酸异丙嗪片剂、针剂、人血清及尿样中盐酸异丙嗪的测定,结果令人满意.","authors":[{"authorName":"冯素玲","id":"97451c88-03c0-4f6a-bf3f-949237513e7f","originalAuthorName":"冯素玲"},{"authorName":"PAN Zi-Hong","id":"0f77f091-434f-49e7-9edc-6065cd3d8934","originalAuthorName":"PAN Zi-Hong"},{"authorName":"潘自红","id":"cfce1571-2b1b-4c4e-8069-f6ec702dd95d","originalAuthorName":"潘自红"},{"authorName":"樊静","id":"e52b7a00-c9ac-456b-9fc5-521c8abfc4c2","originalAuthorName":"樊静"}],"doi":"10.3969/j.issn.1000-0518.2008.12.015","fpage":"1444","id":"b06218e1-27a2-422a-a6a1-e1c0b15b46f1","issue":"12","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"55d0636b-4d44-4dab-abdf-3030a8612fb5","keyword":"盐酸异丙嗪","originalKeyword":"盐酸异丙嗪"},{"id":"121908fc-0ab4-4aac-8f62-a31cfd00d354","keyword":"红B","originalKeyword":"曙红B"},{"id":"94da5d7e-558c-41db-aa50-5c1962430d83","keyword":"共振光散射","originalKeyword":"共振光散射"}],"language":"zh","publisherId":"yyhx200812015","title":"红B共振光散射法测定微量的盐酸异丙嗪","volume":"25","year":"2008"},{"abstractinfo":"在pH=1.98缓冲溶液中,双嘧达莫可与染料探针红Y通过相互结合,产生以315nm为特征峰的共振光散射(RLS)增强信号.在该特征波长下测定的增强共振光散射强度(△IRLS)与双嘧达莫浓度在一定范围内呈线性关系,据此建立了测定痕量双嘧达莫的共振光散射法.当红Y的浓度为3.0×10-5mol/L时,双嘧达莫的检出限可达16.1nmol/L.同时进行了实际样品的测定,相对标准偏差在1.3%~2.5%之间,回收率为(99.2±3.3)%~(102.0±1.7)%.","authors":[{"authorName":"赵小","id":"6e9fec60-f0c0-4131-bc33-e74145aa1aba","originalAuthorName":"赵小辉"},{"authorName":"牛卫芬","id":"5bb22167-04be-4bc6-97ea-a8757b7e775e","originalAuthorName":"牛卫芬"}],"doi":"10.3969/j.issn.1000-0518.2008.06.016","fpage":"693","id":"9c7c1603-020f-4844-ae49-5e33dd4d4f2e","issue":"6","journal":{"abbrevTitle":"YYHX","coverImgSrc":"journal/img/cover/YYHX.jpg","id":"73","issnPpub":"1000-0518","publisherId":"YYHX","title":"应用化学"},"keywords":[{"id":"dee3c523-2dc8-49a0-acc9-3ffb5ae50a2e","keyword":"双嘧达莫","originalKeyword":"双嘧达莫"},{"id":"56546245-850f-4c5a-9cd0-2c15f6b48983","keyword":"红Y","originalKeyword":"曙红Y"},{"id":"5e2e9033-1e31-4b20-88e9-6d1a11625ae8","keyword":"共振光散射","originalKeyword":"共振光散射"}],"language":"zh","publisherId":"yyhx200806016","title":"红Y共振光散射法测定双嘧达莫","volume":"25","year":"2008"}],"totalpage":24,"totalrecord":235}