用差示扫描量热(DSC)研究了尼龙612的等温结晶动力学.实验结果表明,在所研究的等温结晶温度范围内(184℃、186℃、188℃、190℃、192℃),尼龙612达到最大结晶速率时的时间、半结晶期和动力学结晶速率常数分别为:O.12min、0.19 min、0.22 min、0.29 min、0.59 min;0.15 min、0.22 min、0.24 min、0.33 min、0.64 min和22.03 min<'-1>、23.28min<'-1>、8.85 min<'-1>、5.15 min<'-1>、1.93 min<'-1>.等温结晶过程符合Avrmi方程,二次结晶现象不明显.在等温结晶过程中得到的Avrmi指数n在1.81～2.32之间,由理论分析可知,尼龙612等温结晶是一维生长和二维盘状生长.由Arrhenius方程求得尼龙612的等温结晶活化能ΔE=-209.5 kJ/mol.
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