采用不同种类增稠剂制备了乳胶漆,系统考察了乳胶漆的粘度随不同种类增稠剂用量的变化规律,并对其增稠机理进行了研究.实验结果表明:乳胶漆粘度随蒙脱石粉用量的增加而平缓增大;在相同用量下,乳胶漆粘度随纤维素用量的增加而增大的顺序由快到慢依次为:羟乙基纤维素(HEC)>羟丙基甲基纤维素(HPMC)>甲基纤维素(MC);相同用量下,乳胶漆粘度随合成高分子类增稠剂用量的增加而增大的顺序由快到慢依次为:碱溶胀缔合型增稠剂(HASE)>缔合型聚氨酯增稠剂(HEUR)>丙烯酸碱溶胀型增稠剂(ASE);随pH值调节剂用量增加,以AMP-95作pH值调节剂的乳胶漆pH值呈直线上升趋势,用氨水作pH值调节剂时的pH值变化较平缓;分别以无机类、纤维素类和HEUR作增稠剂时配制出的乳胶漆粘度随pH值的增加基本保持不变,以碱溶胀型增稠剂配成的乳胶漆粘度随pH值的增加而增大,后趋于平缓.
参考文献
[1] | Kevin W McCreight;Rebecca Stockl;Carlo Testa et al.Development of low VOC additives to extend the wet edge and open time of aqueous coatings[J].Progress in Organic Coatings,2011,72(1-2):102. |
[2] | Vlad Cristea, M.;Riedl, B.;Blanchet, P. .Enhancing the performance of exterior waterborne coatings for wood by inorganic nanosized UV absorbers[J].Progress in Organic Coatings: An International Review Journal,2010(4):432-441. |
[3] | Samy A. Madbouly;Joshua U. Otaigbe .Recent advances in synthesis, characterization and Theological properties of polyurethanes and POSS/polyurethane nanocomposites dispersions and films[J].Progress in Polymer Science,2009(12):1283-1332. |
[4] | Maestro A;Gonzalez C;Gutierrez JM .Interaction of surfactants with thickeners used in waterborne paints: A rheological study[J].Journal of Colloid and Interface Science,2005(2):597-605. |
[5] | 黄承都,韦藤幼,李怀菊,童张法.剥离型葡萄糖酸蒙脱石的制备及其表征[J].高校化学工程学报,2009(01):160-165. |
[6] | Gaillard N;Claverie J;Guyot A .Synthesis and characterization of block-copolymer surfactants with specific interactions with associative thickeners[J].Progress in Organic Coatings: An International Review Journal,2006(2):98-109. |
[7] | Wenjun Wu;Greg D.Shay .Tailoring HASE Rheology Through Polymer Design:Effects of Hydrophobe Size,Acid Content,And Molecular Weight[J].JCT research,2005(6):423-433. |
[8] | Y.Saito;H.Ogura;Y.Otsubo .Rheological behavior of silica suspensions in aqueous solutions of associating polymer[J].Colloid and polymer science,2008(13):1537-1544. |
[9] | Xiaoli Zhu;Chen Wang;Xiang Zheng Kong .Preparation and rheological properties of SEM-25 containing associative thickener latexes and their mechanisms of thickening[J].Polymer bulletin,2010(7):677-690. |
[10] | A. Kaci;M. Chaouche;P-A. Andreani .Influence of bentonite clay on the rheological behaviour of fresh mortars[J].Cement and Concrete Research,2011(4):373-379. |
[11] | Xiang Zheng Kong,Chen Wang,Xu Bao Jiang,Xiao Li Zhu.A novel associative latex thickener using ethoxylated behenyl methacrylate as functional monomer[J].中国化学快报(英文版),2010(05):616-619. |
[12] | Quadrat O;Horsky J;Snuparek J .Effect of styrene units in latices of acrylate copolymers with structured particles on the thickening with associative thickeners[J].Progress in Organic Coatings: An International Review Journal,2004(3):166-171. |
[13] | 樊益棠.膨润土对于建筑砂浆性能的影响及机理探讨[J].武汉理工大学学报,2005(10):116-118. |
[14] | 陈立军,张心亚,黄洪,沈慧芳,陈焕钦.缔合增稠剂的制法及影响增稠效果的因素[J].涂料工业,2005(11):30-35. |
[15] | 徐峰;朱晓波;邹侯招.实用建筑涂料技术[M].北京:化学工业出版社,2003 |
[16] | 李若慧,胡泊,程伊前.增稠剂对乳胶漆的粘度和光泽的影响[J].涂料工业,2003(01):6-9. |
[17] | Robert J;Srinivasa R;Richard D et al.Associative polymers bearing n-alkyl hydrophobes:Rheological (e)vid(e)nc(e) for microgel-like behavior[J].Journal of Rheology,1999,43(05):1175. |
[18] | 林宣益.乳胶漆[M].北京:化学工业出版社,2004 |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%