研究了高温时效前后的310不锈钢样品在气氛总压为1 05Pa，2.3%SO2/S2/8.8%N2气氛中600℃下的高温硫腐蚀行为.利用金相、扫描电镜/ 能谱及Ｘ射线衍射等分析其腐蚀形貌、成分及结构.结果表明：经时效处理的310不锈钢比未 时效处理者腐蚀严重，前者以晶间腐蚀为主，后者以均匀腐蚀为主.310不锈钢于700℃，100 00 h时效后在晶界大量析出σ相，使晶界附近贫Cr，降低了其抗硫腐蚀性能.
The sulfidation behavior of 310SS (Stainless Steel) before and affer high-temperature aging treatment has been studied in the gas mi xture of 2.3%SO2-S2-8.8%N2 under 105 Pa at 600℃.The morphology of c orrosion products and scale structure were examined with OM,SEM/EDX and XRD.It i s found that the aged sample suffered more severe corrosion than the unaged samp le.Corrosion type of the aged 310SS is intergrainular,whereas corrosion type of unaged 310SS is uniform.The formation of σ phase due to aging treatment at 700 ℃ for 1000h,reduced Cr content on boundaries in 310SS,which results in the de crease of corrosion resistance of 310SS.
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