研究了不锈钢冶炼工艺中EAF渣的资源利用特性和渣中铬的浸出特性,结果表明:EAF渣呈碱性,渣中物相主要有CazSiOa、Ca3Mg(SiO4)2、MgCr2O4等,值得关注的CrzP3质量分数为2.92%,具有较高的回收价值,但是渣中的金属元素基本上均匀分布在各粒度段中,因此其回收利用具有一定的困难。钢渣中铬的浸出测试结果表明:EAF渣中的铬在去离子水中浸出量与钢渣粒径成反比,与反应时间、液固比成正比,电磁搅拌改善了浸出的动力学条件,有利于铬的浸出,浸出液中的Cr(VI)占浸出总铬的50%以上。在酸性情况下,浸出铬的质量增加,但均以毒性较小的形态存在。
The structure and properties of EAF slag and it's leaching behavior of Cr were studied. The results indicate that the main minerals in the EAF slag are CazSiO4 , Ca3Mg(SiO4 )2 and MgCr2O4. The content of Cr203 in EAF slag is 2.92 %. The slag are suitable for beneficial reuse, hut metals in EAF slag are distributed evenly among every particle size. The leaching tests of Cr in slag show that the ratio of Cr leaching rate from slag in deionized water was inversely-proportional to particle size, and directly proportional to leaching time and liquid to solid ratio. Electromagnetic stirring improve the kinetic condition and improve Cr leaching rate. In deionized water, the percentage of Cr(VI) is higher than 50% in all the Cr leached from EAF slag. In acid solution, the volume of Cr leaching from slag increases but all the Cr are in the form of Cr( Ⅲ ).
参考文献
[1] | Dirk Durinck;Sander Arnout;Gilles Mertens .Borate Distribution in Stabilized Stainless-Steel Slag[J].Journal of the American Ceramic Society,2008(2):548-554. |
[2] | 王海燕.一钢公司不锈钢炉渣处理工艺设计[J].宝钢技术,2004(02):22-24,28. |
[3] | Pai-Haung Shih;Zong-Zheng Wu;Hung-Lung Chiang .Characteristics of bricks made from waste steel slag[J].Waste Management,2004(10):1043-1047. |
[4] | Caijun Shi .Steel Slag-Its Production, Processing, Characteristics, and Cementitious Properties[J].Journal of Materials in Civil Engineering,2004(3):230-236. |
[5] | Van Dessel J .Recycling and Valorisation of Stainless Steel Slags[R].Brussels:Belgian Building Research Institute,2002. |
[6] | de Bock L;Van den Bergh H .Stainless Steel Slags in Hydraulic Bound Mixtures for Road Construction 2:Case Studies in Belgium[R].Belgium:Belgian Road Research Centre(BRRC),2004. |
[7] | 陈子宏,马国军,肖海明,陈长松,高建明.不锈钢冶炼电炉渣结构性质及浸出行为研究[J].武汉科技大学学报(自然科学版),2009(05):466-470. |
[8] | 孙家瑛,王志新.不锈钢钢渣的污染特性[J].粉煤灰,2005(04):11-12. |
[9] | Rai D;Sass B M;Moore D A .Chromium(111)Hydrolysis Constants and Solubility of Chromium( 111 )Hydroxide[J].Inorganic Chemistry,1987,26:345. |
[10] | DusingDC;BishopPL;KeenerTC .Effect of Redox Potential on Leaching From Stabilized/Solidified Waste Materials[J].Journal of the Air And Waste Management Association,1992,42:56. |
[11] | GB5085.7-2007.危险废物鉴别标准浸出毒性鉴别[S].北京:中国环境科学出版社,2007. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%