从无机硅钝化和有机硅钝化两个方面综述了国内外镀锌钢硅酸盐及硅烷钝化机理的研究进展.其中,无机硅钝化又分为酸性硅酸盐钝化和碱性硅酸盐钝化,有机硅钝化主要是硅烷(偶联剂)钝化.研究表明,碱性硅酸盐钝化和硅烷钝化的机理大致相似,都是钝化液中硅羟基与基体表面的羟基发生脱水缩合而形成钝化膜,酸性硅酸盐钝化的机理则有待进一步研究.提高含硅钝化的耐蚀性和溶液维护是今后研究的热点.
参考文献
[1] | 姜琴,李伟华,侯保荣,张璐.镀锌板无铬钝化技术进展[J].腐蚀与防护,2013(02):101-106. |
[2] | 范云鹰,施绍队,周荣锋,岑启宏,李孟洋.镀锌层硅酸盐无铬黑色钝化工艺[J].材料保护,2012(04):36-38. |
[3] | 李雪,裴和中,张国亮,龙晋明.锌镀层钝化处理的研究现状及展望[J].热加工工艺,2012(16):144-147. |
[4] | 韩克平.镀锌层表面硅酸盐防腐膜的研究[J].腐蚀科学与防护技术,1997(02):167. |
[5] | 李广超.硫脲对镀锌层硅酸盐钝化作用的影响[J].电镀与涂饰,2007(01):10-11,14. |
[6] | 范云鹰,杨晓科,施绍队,刘瑶,陈高伟.镀锌层硅酸盐彩色钝化工艺[J].材料保护,2012(08):37-39. |
[7] | 刘瑶,范云鹰,周荣,施绍对,杨晓科.热镀锌层硅酸盐钝化膜的耐蚀性[J].材料保护,2012(06):19-21. |
[8] | Hara M.;Ichino R.;Okido M.;Wada N. .Corrosion protection property of colloidal silicate film on galvanized steel[J].Surface & Coatings Technology,2003(0):679-681. |
[9] | Socha RP;Pommier N;Fransaer J .Effect of deposition conditions on the formation of silica-silicate thin films[J].Surface & Coatings Technology,2007(12):5960-5966. |
[10] | Robert P. Socha;Jan Fransaer .Mechanism of formation of silica-silicate thin films on zinc[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2005(1/2):45-55. |
[11] | Dalbin S;Maurin G;Nogueira RP;Persello J;Pommier N .Silica-based coating for corrosion protection of electrogalvanized steel[J].Surface & Coatings Technology,2005(2/3):363-371. |
[12] | Yuan, MR;Lu, JT;Kong, G .Effect of SiO2:Na2O molar ratio of sodium silicate on the corrosion resistance of silicate conversion coatings[J].Surface & Coatings Technology,2010(8):1229-1235. |
[13] | Yuan, M.-R.;Lu, J.-T.;Kong, G.;Che, C.-S. .Effect of silicate anion distribution in sodium silicate solution on silicate conversion coatings of hot-dip galvanized steels[J].Surface & Coatings Technology,2011(19):4466-4470. |
[14] | Yuan, M.-R.;Lu, J.-T.;Kong, G.;Che, C.-S. .Self healing ability of silicate conversion coatings on hot dip galvanized steels[J].Surface & Coatings Technology,2011(19):4507-4513. |
[15] | Jaekyu Min;Ji Hoon Park;Hong-Kyun Sohn .Synergistic effect of potassium metal siliconate on silicate conversion coating for corrosion protection of galvanized steel[J].Journal of industrial and engineering chemistry,2012(2):655-660. |
[16] | 吴海江,卢锦堂,陈锦虹.热镀锌钢表面硅烷膜耐蚀性能的初步研究[J].腐蚀与防护,2006(01):14-17. |
[17] | Montemor MF;Ferreira MGS .Analytical characterization of silane films modified with cerium activated nanoparticles and its relation with the corrosion protection of galvanised steel substrates[J].Progress in Organic Coatings: An International Review Journal,2008(3):330-337. |
[18] | Trabelsi W;Cecilio P;Ferreira MGS;Yasakau K;Zheludkevich ML;Montemor MF .Surface evaluation and electrochemical behaviour of doped silane pre-treatments on galvanised steel substrates[J].Progress in Organic Coatings: An International Review Journal,2007(3):214-223. |
[19] | Trabelsi W;Cecilio P;Ferreira MGS;Montemor MF .Electrochemical assessment of the self-healing properties of Ce-doped silane solutions for the pre-treatment of galvanised steel substrates[J].Progress in Organic Coatings: An International Review Journal,2005(4):276-284. |
[20] | 韩利华,马庆国,冯晓健,康举.镀锌层表面KH-560硅烷膜耐蚀性能研究[J].材料工程,2010(06):45-49. |
[21] | 郝建军.镀锌层烷氧基硅烷钝化处理工艺研究[J].电镀与精饰,2008(11):1-4. |
[22] | 林萍,范云鹰.硅酸盐型钝化液各组分对镀锌层钝化膜的影响[C].2009云南省研究生学术论坛论文集,2009:105-109. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%