采用变温装置,在-30℃至-190℃温度范围内我们对冰行进了原位低温拉曼光谱测量.并利用光谱分析软件对冰的拉曼光谱带行进了分析,得到O-H键振动的三个拉曼峰随温度的变化规律.应用氢键理论对实验结果进行了分析,结果表明O-H键的v3(Eg)反对称伸缩振动和v1(B1g)不同向对称伸缩振动受氢键影响较大,并且v3(E)的拉曼峰位与温度成很好的线性关系有潜在的应用价值.
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