锂离子电池聚阴离子型硅酸盐正极材料的研究进展

材料导报, 2009, 23(11): 28-31.

锂离子电池聚阴离子型硅酸盐正极材料的研究进展

左朋建 ^1, , 王振波 ^2, , 尹鸽平 ^3, , 程新群 ^4, , 杜春雨 ^5, , 徐宇虹 ^6, , 史鹏飞 ^7,

1.哈尔滨工业大学化工学院,哈尔滨,150001

2.哈尔滨工业大学化工学院,哈尔滨,150001

3.哈尔滨工业大学化工学院,哈尔滨,150001

4.哈尔滨工业大学化工学院,哈尔滨,150001

5.哈尔滨工业大学化工学院,哈尔滨,150001

6.哈尔滨工业大学化工学院,哈尔滨,150001

7.哈尔滨工业大学化工学院,哈尔滨,150001

基金项目: 高等学校博士学科点专项科研基金新教师基金(200802131064) 中国博士后科学基金(20070420860) 哈尔滨工业大学科研创新基金(HIT.NSRIF.2008.25) 国家自然科学基金(20673032)

关键词：锂离子电池 , 正极材料 , 硅酸盐材料 , 量子化学计算 , 电化学性能

Research Progress on Poly-anionic Silicate Cathode Materials for Lithium Ion Batteries

综述了硅酸盐正极材料的设计、特性、制备及电化学性能,介绍了基于密度泛函理论的量子化学计算在锂离子电池材料设计中的方法和理论,认为进一步开展Li2MSiO4及其复合材料的理论和实验研究可以获得性能优异的高容量正极材料.

参考文献

[1]	Winter M.;Spahr ME.;Novak P.;Besenhard JO. .Insertion electrode materials for rechargeable lithium batteries [Review][J].Advanced Materials,1998(10):725-763.
[2]	聚阴离子型锂离子电池正极材料研究进展[J].化学进展,2005(04):604-613.
[3]	Tarascon J;Armand M M .Issues and challenges facing rechargeable lithium batteries[J].Nature,2001,414:359.
[4]	Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194.
[5]	Armand M;Gauhtier M;Magnan J F et al.Method for synthesis of carbon-coated redox materials with controlled size[P].W,WO02/27823,2002-04-04.
[6]	Kokalj A;Dominko R;Mali G et al.Beyond one-electron reaction in Li cathode materials:Designing Li2MnxFe1-XSiO4[J].Chemistry of Materials,2007,19:3633.
[7]	Nyten A;Stjerndahl M;Rensmo H;Siegbahn H;Armand M;Gustafsson T;Edstrom K;Thomas JO .Surface characterization and stability phenomena in Li2FeSiO4 studied by PES/XPS[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(34):3483-3488.
[8]	Nyten A;Kamali S;Haggstrom L;Gustafsson T;Thomas JO .The lithium extraction/insertion mechanism in Li2FeSiO4[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2006(23):2266-2272.
[9]	Nyten A;Abouimrane A;Armand M;Gustafsson T;Thomas JO .Electrochemical performance of Li2FeSiO4 as a new Li-battery cathode material[J].Electrochemistry communications,2005(2):156-160.
[10]	Arroyo de-Dompablo M E;Morcrette M;Tarascon J M .A computational investigation on fluorinated-polyanionic compound as positive electrode for lithium batteries[J].Journal of Power Sources,2007,174(02):1251.
[11]	Prakash AS;Rozier P;Dupont L;Vezin H;Sauvage F;Tarascon JM .Electrochemical reactivity of Li2VOSiO4 toward Li[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(2):407-412.
[12]	Padhi AK.;Masquelier C.;Okada S.;Goodenough JB.;Nanjundaswamy KS. .EFFECT OF STRUCTURE ON THE FE3+/FE2+ REDOX COUPLE IN IRON PHOSPHATES[J].Journal of the Electrochemical Society,1997(5):1609-1613.
[13]	Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194.
[14]	Padhi AK.;Masquelier C.;Goodenough JB.;Nanjundaswamy KS. .MAPPING OF TRANSITION METAL REDOX ENERGIES IN PHOSPHATES WITH NASICON STRUCTURE BY LITHIUM INTERCALATION[J].Journal of the Electrochemical Society,1997(8):2581-2586.
[15]	Dompablo, MEAD;Rozier, P;Morcrette, M;Tarascon, JM .Electrochemical data transferability within LiyVOXO4 (X = Si, Ge0.5Si0.5, Ge, Si0.5As0.5, Si0.5P0.5, As, P) polyoxyanionic compounds[J].Chemistry of Materials,2007(10):2411-2422.
[16]	Arroyo-de Dompablo ME;Armand M;Tarascon JM;Amador U .On-demand design of polyoxianionic cathode materials based on electronegativity correlations: An exploration of the Li2MSiO4 system (M = Fe, Mn, Co, Ni)[J].Electrochemistry communications,2006(8):1292-1298.
[17]	Larsson P;Ahuia R;Nyten A;Thomas JO .An ab initio study of the Li-ion battery cathode material Li2FeSiO4[J].Electrochemistry communications,2006(5):797-800.
[18]	Wu S Q;Zhang J H;Zhu Z Z et al.Structural and electronic properties of the Li-ion battery cathode material LixCoSiO4[J].Current Applied Physics,2007,7:611.
[19]	Arroyo-de Dompablo ME;Amador U;Garcia-Alvarado F .An experimental and computational study of the electrode material olivine-LiCoAsO4[J].Journal of the Electrochemical Society,2006(4):A673-A678.
[20]	Z.L. Gong;Y.X. Li;Y. Yang .Synthesis and electrochemical performance of Li_2CoSiO_4 as cathode material for lithium ion batteries[J].Journal of Power Sources,2007(2):524-527.
[21]	Dominko R;Bele M;Gaberscek M;Meden A;Remskar M;Jamnik J .Structure and electrochemical performance of Li2MnSiO4 and Li2FeSiO4 as potential Li-battery cathode materials[J].Electrochemistry communications,2006(2):217-222.
[22]	R. Dominko;D.E. Conte;D. Hanzel;M. Gaberscek;J. Jamnik .Impact of synthesis conditions on the structure and performance of Li_2FeSiO_4[J].Journal of Power Sources,2008(2):842-847.
[23]	Moskon J;Dominko R;Gaberscek M et al.Citrate-derived carbon nsnocoatings for poorly conducting cathode--A detailed study using TiO2 substrate materials[J].Journal of the Electrochemical Society,2006,153:A1805.
[24]	Joze Moskon;Robert Dominko;Romana Cerc-Korosec;Miran Gaberscek;Janez Jamnik .Morphology and electrical properties of conductive carbon coatings for cathode materials[J].Journal of Power Sources,2007(2):683-688.
[25]	Yi-Xiao Li;Zheng-Liang Gong;Yong Yang .Synthesis and characterization of Li_2MnSiO_4/C nanocomposite cathode material for lithium ion batteries[J].Journal of Power Sources,2007(2):528-532.
[26]	Gong Z L;Li Y X;Yang Y .Synthesis and characterization of Li2MnxFe1-xSiO4 as a cathode material for lithium-ion battettries[J].Electrochemical and Solid-State Letters,2006,9(12):A542.

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锂离子电池聚阴离子型硅酸盐正极材料的研究进展

Research Progress on Poly-anionic Silicate Cathode Materials for Lithium Ion Batteries

参考文献