将含有探针组分的光敏树脂分别在水中、空气中进行紫外光固化,并对固化材料的表面性能进行了研究.固化膜的表面能测定表明,水中固化的材料表面能大于在空气中固化的材料.X射线光电子能谱(x-ray photoelectron spec-troscopy,XPS)分析表明,探针组分在不同固化介质中的运动方式不同;固化过程中组分的不同迁移、基团翻转最终导致了固化膜表面性能的差别.
参考文献
| [1] | Luan B;Liu XY;Nagata J;Cheong WJ .Residual stress analysis - an important consideration for coating of stereolithography polymers[J].Surface & Coatings Technology,2005(2/3):323-330. |
| [2] | Nagasawa A;KitanoT;WatanabeT et al.Control of surface free energy for surface modification by using photocurable resin and surface modifier[J].Sen-I Gakkaishi,2004,60(06):183-187. |
| [3] | Bongiovanni R.;Priola A.;Malucelli G. .MODIFICATION OF SURFACE PROPERTIES OF UV-CURED FILMS IN THE PRESENCE OF LONG CHAIN ACRYLIC MONOMERS[J].Journal of Colloid and Interface Science,1995(2):283-287. |
| [4] | Bertsch A;lorenz H;Renaud P .3D microfabrication by combining microstereolithography and thick resist UV lithography[J].Sensors and Actuators A:Physical,1999,73(1-2):14-23. |
| [5] | 骆燕,王德海.固化氛围对丙烯酸酯紫外光固化材料表面性能的影响[J].辐射研究与辐射工艺学报,2007(01):15-18. |
| [6] | 王德海,骆燕,蔡延庆.探针组分对紫外光固化材料表面性能的影响[J].辐射研究与辐射工艺学报,2006(04):214-218. |
| [7] | 骆燕,王德海,蔡延庆.丙烯酸酯紫外光固化材料表面的XPS研究[J].感光科学与光化学,2006(06):428-435. |
| [8] | Owens D K;Wendt R C .Estimation of the surface free energy of polymers[J].Journal of Applied Polymer Science,1969,13(08):1741-1747. |
| [9] | Asif A;Huang C Y;Shi W F .UV curing behaviors and hydrophilic characteristics of UV curable waterborne hyperbranched aliphatic polyesters[J].Polymers For Advanced Technologies,2003,14(09):609-615. |
| [10] | Fowkes F M .Additivity of interrmolecular forces at interfaces.1 Determination of the contribution to surface and interfacial tensions of dispersion forces in various liquida[J].Physical Chemistry,1963,67:2538-2541. |
| [11] | 吴宁晶,黄礼侃,郑安呐,胡福增,管涌.聚苯乙烯/聚二甲基硅氧烷嵌段与接枝共聚物表面聚集态的研究[J].高分子学报,2005(01):137-141. |
| [12] | Chattopadhyay DK;Panda SS;Raju KVSN .Thermal and mechanical properties of epoxy acrylate/methacrylates UV cured coatings[J].Progress in Organic Coatings: An International Review Journal,2005(1):10-19. |
| [13] | Kassis CM.;Betts DE.;Guan ZB.;Romack TJ.;Desimone JM. Linton RW.;Steehler JK. .XPS STUDIES OF FLUORINATED ACRYLATE POLYMERS AND BLOCK COPOLYMERS WITH POLYSTYRENE[J].Macromolecules,1996(9):3247-3254. |
| [14] | Wulf M.;Michel S.;Grundke K.;Uhlmann P. .Surface tension studies of levelling additives in powder coatings [Review][J].Progress in Organic Coatings: An International Review Journal,2000(2):59-66. |
| [15] | Grundke K.;Osterhold M.;Michel S. .Surface tension studies of additives in acrylic resin-based powder coatings using the Wilhelmy balance technique [Review][J].Progress in Organic Coatings: An International Review Journal,2000(2/4):101-106. |
| [16] | Sangermano M.;Bongiovanni R.;Malucelli G.;Priola A.;Polliclino A. Recca A. .Fluorinated epoxides as surface modifying agents of UV-curable systems[J].Journal of Applied Polymer Science,2003(6):1524-1529. |
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