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通过凝胶渗透色谱、红外光谱、白度和力学性能分析,研究了丙烯腈-丁二烯-苯乙烯聚合物(ABS)材料从2012年夏季始12个月内在中国新疆若羌地区典型暖温带大陆性荒漠干旱气候下的自然老化行为.结果表明,在户外曝露1个月后,ABS结构中产生羰基、羟基等含氧基团,相对分子质量降低,表面黄化,材料由韧性破坏转变为脆性破坏.随着曝露时间的延长,白度不断降低,羰基、羟基含量增加,分子链断裂加剧,拉伸强度、冲击强度逐渐减小.曝露12个月后,拉伸强度和冲击强度分别降低了43%和34%.

参考文献

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