欢迎登录材料期刊网

材料期刊网

高级检索

以Ti、B4C和Fe粉为原料,利用氩弧熔敷技术在Q235钢基体表面制备出原位自生TiC-TiB2增强Fe基复合涂层.利用扫描电镜(SEM)、X射线衍射仪(XRD)对涂层的显微组织进行了分析.并分析了TiC和TiB2颗粒的形成机理和氩弧熔池的凝固特性.实验结果表明:熔敷层组织为TiC和TiB2弥散分布在α-Fe中,熔敷层与基体呈冶金结合,无裂纹、气孔等缺陷;涂层中TiC和TiB2的体积分数约为68%.形成机理主要是以固态扩散机制为主,TiC以小颗粒状和花瓣状先析出,后析出的TiB2多以六边形、短棒状存在,TiB2的组织比较粗大,TiC颗粒比较细小,TiB2的含量大于TiC含量.

参考文献

[1] H. Y. Wang;L. Huang;Q. C. Jiang .In situ synthesis of TiB_2-TiC particulates locally reinforced medium carbon steel-matrix composites via the SHS reaction of Ni-Ti-B_4C system during casting[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2005(1/2):98-104.
[2] 杜宝帅,邹增大,王新洪,李清明.激光熔覆原位自生TiB2-TiC/ FeCrSiB复合涂层研究[J].应用激光,2007(04):269-272.
[3] 王振廷,孟君晟,王永东,胡国梁.原位自生TiCp/Ni60A复合涂层组织结构及长大特性[J].稀有金属材料与工程,2007(z2):709-711.
[4] 马乃恒,方小汉,梁工英,苏俊义.激光熔覆原位合成TiCp/Al复合材料[J].中国有色金属学报,2000(06):843.
[5] 陈颢,李惠琪.等离子束表面冶金原位颗粒增强铁基涂层的研究[J].材料热处理学报,2006(02):114-117.
[6] 王振廷,孟君晟,陈丽丽,周晓辉.感应熔覆原位自生TiC/Ni基复合涂层组织和形成机理[J].材料热处理学报,2007(06):99-103.
[7] He LJ;Zhang XN;Tong CD .Surface modification of pure titanium treated with B4C at high temperature[J].Surface & Coatings Technology,2006(9):3016-3020.
[8] D. Vallauri;V.A. Shcherbakov;A.V. Khitev .Study of structure formation in TiC-TiB_2-Me_xO_y ceramics fabricated by SHS and densification[J].Acta materialia,2008(6):1380-1389.
[9] Locci AM;Orru R;Cao G .Simultaneous spark plasma synthesis and densification of TiC-TiB2 composites[J].Journal of the American Ceramic Society,2006(3):848-855.
[10] 李建林,曹广益,周勇,胡克鏊.高能球磨制备TiB2/TiC纳米复合粉体[J].无机材料学报,2001(04):709-714.
[11] 李敏,李惠东,李惠琪,裴中爱,孙玉宗.同步送粉等离子束表面冶金合金化涂层的凝固组织特性及形成机理[J].焊接学报,2006(03):69-72.
[12] Zhao C.;Tian F.;Peng HR.;Hou JY. .Non-transferred arc plasma cladding of Stellite Ni60 alloy on steel[J].Surface & Coatings Technology,2002(1):80-84.
[13] R. Ramaseshan;S.K. Seshadri;N.G. Nair .Electroless nickel-phosphorus coating on Ti and Al elemental powders[J].Scripta materialia,2001(2):183-189.
[14] 陈冰泉.低碳钢表面氩弧硼-碳合金化工艺研究[J].机械工程学报,2004(02):161-164.
[15] 宋思利,邹增大,王新洪,李清明.钨极氩弧熔敷技术制备含TiC颗粒增强涂层的研究[J].山东大学学报(工学版),2006(03):1-4,12.
[16] 蒋军 .热等静压原位合成TiB<,2>-TiC<,x>复相陶瓷材料[D].西南交通大学,2003.
[17] 梁英教;车荫昌.无机物热力学致据手册[M].沈阳:东北大学出版社,1993
[18] 田浩,耿林,倪丁瑞,孟庆武.TC4合金表面激光熔覆B4C及B4C+Ti粉末涂层的微观组织[J].稀有金属材料与工程,2007(03):420-423.
[19] Antonio M. Locci;Roberto Orru;Giacomo Cao;Zuhair A. Munir .Effect of ball milling on simultaneous spark plasma synthesis and densification of TiC-TiB_2 composites[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2006(1/2):23-29.
[20] 唐建新,程继红,曾照强,苗赫濯.Ti-B4C反应机理和扩散路径的研究[J].无机材料学报,2000(05):884-888.
[21] Klinger L.;Horvitz D.;Gotman I. .In situ processing of TiB2/TiC ceramic composites by thermal explosion under pressure: experimental study and modeling[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2001(1):92-99.
[22] ZHAO Hong;CHENG Yi-bing .Formation of TiB2-TiC composites by reactive sintering[J].Ceramics International,1999,25:353-358.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%