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通过水热生长的预处理步骤在普通玻璃载玻片表面铺设种子层,然后采用旋涂法在处理好的衬底上涂覆前驱体溶胶,成功地制备出沿(002)晶面择优取向生长的Al掺杂的ZnO薄膜(AZO)薄膜.利用X射线衍射分析、扫描电镜表征薄膜形貌,并测定薄膜的透射率及电阻率.研究了种子层对AZO薄膜结晶性能、表面形貌及光电性能的影响.结果表明:种子层减少了薄膜生长初期的非晶成份,促进了薄膜的晶化.薄膜在可见光范围内平均透射率超过85%,导电性能也有所改善.

参考文献

[1] Song D.;Widenborg P.;Chin W.;Aberle AG. .Investigation of lateral parameter variations of Al-doped zinc oxide films prepared on glass substrates by rf magnetron sputtering[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2002(1):1-20.
[2] Kuo SY;Chen WC;Lai FI;Cheng CP;Kuo HC;Wang SC;Hsieh WF .Effects of doping concentration and annealing temperature on properties of highly-oriented al-doped ZnO films[J].Journal of Crystal Growth,2006(1):78-84.
[3] 栗粟,章晓中.ZnO纳米线/纳米棒混合阵列的制备及其光致发光性能研究[J].人工晶体学报,2011(03):567-571.
[4] 陈光羽,何延如,雷志芳,谷士斌,赵冠超,杨荣,孟原,郭铁,李立伟.AZO薄膜刻蚀形貌优化及其在硅基薄膜双结太阳能电池中的应用[J].人工晶体学报,2012(05):1270-1275.
[5] Z.Q. Xu;H. Deng;Y. Li;Q.H. Guo;Y.R. Li .Characteristics of Al-doped c-axis orientation ZnO thin films prepared by the sol-gel method[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2006(2):354-358.
[6] Musat V;Teixeira B;Fortunato E;Monteiro RCC;Vilarinho P .Al-doped ZnO thin films by sol-gel method[J].Surface & Coatings Technology,2004(0):659-662.
[7] V. GOKULAKRISHNAN;S. PARTHIBAN;K. JEGANATHAN.Investigation of Molybdenum Doped ZnO Thin Films Prepared by Spray Pyrolysis Technique[J].Ferroelectrics,2011:126-134.
[8] Meizhen Gao;Xiaonan Wu;Jing Liu;Wenbao Liu .The effect of heating rate on the structural and electrical properties of sol-gel derived Al-doped ZnO films[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(15):6919-6922.
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