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通过差示扫描量热分析仪、线膨胀测试仪、扫描电镜等手段研究了Li2O和ZnO的相对含量对Li2OZnO-K2O-SiO2-Al2O3-B2O3体系结合剂及磨具性能的影响.结果发现,随着m(Li2O):m(ZnO)比值的减小,结合剂的软化点温度、耐火度先降低后升高,而结合剂的膨胀系数、流动性以及磨具的抗弯曲强度先增加后减小,结合剂的化学稳定性增强;当m(Li2O)∶m(ZnO)=2时,结合剂的耐火度为770℃,流动性为140.21%,线膨胀系数为6.4267×10-6K-1,化学稳定性好,该结合剂可以实现磨具的低温烧成,防止cBN磨料的高温侵蚀,高温下熔化完全、流动性好,对cBN磨粒的包裹性好,提高了磨具强度,其抗弯曲强度为62.37MPa.

参考文献

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[2] Kazuhiro Fujisaki;Hideo Yokota;Naomichi Furushiro;Yutaka Yamagata;Takashi Taniguchi;Ryutaro Himeno;Akitake Makinouchi;Toshiro Higuchi .Development of ultra-fine-grain binderless cBN tool for precision cutting of ferrous materials[J].Journal of Materials Processing Technology,2009(15/16):5646-5652.
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[6] 王鹏飞,李志宏,朱玉梅.碱金属氧化物对陶瓷结合剂性能的影响[J].稀有金属材料与工程,2007(z1):285-287.
[7] 张永杰,徐晓伟,吴卫江,刘志甫,李玉萍.LiF和B2O3在Al-Si-O陶瓷结合剂中的作用[J].北京科技大学学报,1999(03):255-257.
[8] Daniela Herman;Jan Krzos .Influence of vitrified bond structure on radial wear of cBN grinding wheels[J].Journal of Materials Processing Technology,2009(14):5377-5386.
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