用溶液法合成了一维配合物 [Cu(NPG)2(H2O)2]·CH3CH2OH (HNPG=邻苯二甲酰甘氨酸),并对其进行了元素分析,红外光谱,热重分析,磁性和X射线单晶衍射实验.单晶结构分析表明该晶体属于三斜晶系,P-1空间群,晶胞系数a= 0.47674(12) nm,b= 0.11319(3) nm,c = 0.11614(3) nm,α = 106.468(4) °,β= 100.114(5) °,γ= 94.358(5) °,V= 0.5864(3) nm3,Z= 1.配合物是由CuO6八面体通过共顶点连接构成一维链状结构,分子间氢键对分子间的结构稳定起到重要的作用;配合物存在弱的反铁磁性.
参考文献
[1] | Hagrman P J;Hagrman D;Zubieta J et al.Infinite Secondary Units and Forbidden Carenation in Metal-organic Framework[J].Angewandte Chemie International Edition,1999,38:2638-2684. |
[2] | Wang S N;Xing H;Li Y Z et al.Unprecedented Interweaving of Single-helical and Unequal Double-helical Chains into Chiral Metal-organic Open Frameworks with Multiwalled Tubular Structures[J].Accounts of Chemical Research,2001,34:239-247. |
[3] | 高山,张现发,霍丽华,程晓丽,赵辉.一维链状4-硝基-3-羧甲基苯异丙酸镉配位聚合物{[Cd(3-CNPP)(Py)3]·2H2O}n的合成、晶体结构及热稳定性研究[J].无机化学学报,2005(08):1195-1198. |
[4] | Xue XA.;Wang XS.;Wang LZ.;Xiong RG.;Abrahams BF.;You XZ.;Xue ZL. Che CM. .Hydrothermal preparation of novel Cd(II) coordination polymers employing 5-(4-pyridyl)tetrazolate as a bridging ligand[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2002(25):6544-6546. |
[5] | Banglin Chen;Nathan W.Ockwig;Andrew R.Millward;Damacio S.Contreras;Omar M.Yaghi .High H_2 Adsorption in a Microporous Metal-Organic Framework with Open Metal Sites[J].Angewandte Chemie,2005(30):4745-4749. |
[6] | Jesse L;Rowsell L;Yaghi O M .Strategies for Hydrogen Storages in Metal-organic Framework[J].Angew.Chem.In.Ed,2005,44:4670-4679. |
[7] | Chen BL;Ockwig NW;Fronczek FR;Contreras DS;Yaghi OM .Transformation of a metal-organic framework from the NbO to PtS net[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,2005(2):181-183. |
[8] | Yaghi O M;Jernigan R;Li H.Construction of a New Open-framework Solid from 1,3,5-cyclohexanetricarboxylate and Zinc(II) Building Blocks[J].Journal of The Chemical Society-Dalton Transactions,1997:2383-2386. |
[9] | Sheldrick G M.Program for X-ray Crystal Structure Refinement[M].Germany:Gttingen University,1997 |
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