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用溶液法合成了一维配合物 [Cu(NPG)2(H2O)2]·CH3CH2OH (HNPG=邻苯二甲酰甘氨酸),并对其进行了元素分析,红外光谱,热重分析,磁性和X射线单晶衍射实验.单晶结构分析表明该晶体属于三斜晶系,P-1空间群,晶胞系数a= 0.47674(12) nm,b= 0.11319(3) nm,c = 0.11614(3) nm,α = 106.468(4) °,β= 100.114(5) °,γ= 94.358(5) °,V= 0.5864(3) nm3,Z= 1.配合物是由CuO6八面体通过共顶点连接构成一维链状结构,分子间氢键对分子间的结构稳定起到重要的作用;配合物存在弱的反铁磁性.

参考文献

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