利用磁控溅射技术通过氮化Ga2O3/Ta薄膜,合成大量的一维单晶纤锌矿型氮化镓纳米线.用X射线衍射、扫描电子显微镜、高分辨透射电子显微镜,选区电子衍射和光致发光谱对制备的氮化镓进行了表征.结果表明;制备的GaN纳米线是六方纤锌矿结构,其直径大约20~60 nm,其最大长度可达10 μm左右.室温下光致发光谱测试发现363 nm处的较强紫外发光峰.另外,简单讨论了氮化镓纳米线的生长机制.
Single crystalline wurzite GaN nanowires were synthesized through ammoniating Ga2O3/Ta films by RE magnetron sputtering.The products were characterized by X-ray diffraction (XRD),scanning electron microscopy (SEM),high-resolution transmission electron microscopy (HRTEM),selected-area electron diffraction (SAED) and photoluminescence (PL).The results show that the nanowires have a hexagonal wurtzite structure with diameters ranging from 20 nm to 60 nm and lengths typically up to 10 μm.The PL spectrum exhibits a strong UV light emission at 363 nm.The growth mechanism of the crystalline GaN nanowires is discussed briefly.
参考文献
[1] | Yi S N;Jong H N;Kwan H et al.[J].Applied Physics Letters,2007,90:101 901. |
[2] | Nakamura S .[J].Science,1998,281:956. |
[3] | Morales A M;Lieber C M .[J].Science,1998,279:208. |
[4] | Han WQ;Fan S S;Li Q Q et al.[J].Science,1997,277:12 879. |
[5] | Goldberger;He R;Zhang Y .[J].Nature,2003,422:599. |
[6] | Duan XF.;Lieber CM. .Laser-assisted catalytic growth of single crystal GaN nanowires[J].Journal of the American Chemical Society,2000(1):188-189. |
[7] | Zhang;Zhang L D;Wang X F et al.[J].Journal of Chemical Physics,2001,115:5714. |
[8] | Lyu SC.;Cha OH.;Suh EK.;Ruh H.;Lee HJ.;Lee CJ. .Catalytic synthesis and photoluminescence of gallium nitride nanowires[J].Chemical Physics Letters,2003(1/2):136-140. |
[9] | Perlin P;Jauberthiecarillon C et al.[J].Physical Review B:Condensed Matter,1992,45:83. |
[10] | Sun L;Xue C;Sun C et al.[J].Materials Letters,2007,61:5220. |
[11] | Monemar B .[J].Physical Review B:Condensed Matter,1974,10:676. |
[12] | Korotkov R Y;Reshchikov M A;Wessels B W .[J].Physica B,1999,273:80. |
[13] | Kim T Y;Lee S H;Mo Y H et al.[J].Journal of Crystal Growth,2003,257:97. |
[14] | Xu BS;Zhai LY;Liang J;Ma SF;Jia HS;Liu XG .Synthesis and characterization of high purity GaN nanowires[J].Journal of Crystal Growth,2006(1):34-39. |
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