利用Thermo-Calc热力学软件计算研究YF45MnV钢中MnS的平衡析出规律及凝固过程中各元素的偏析行为对MnS析出的影响.结果表明:MnS平衡初始析出温度为1421℃,初始析出温度随C、Si、Al含量增加而降低,随Mn、S含量增加而升高;Scheil凝固过程中,计算得到Mn、S的平衡分配系数分别为0.70、0.02,二者随着凝固过程进行在剩余液相中不断偏析富集,达到平衡浓度积后析出MnS.真空感应炉冶炼不同S含量(0.025% ~0.065%)的实验钢,发现钢中硫化物主要为大量细小Ⅱ类MnS+少量尺寸较大的Ⅲ类MnS.随S含量的提高,大尺寸MnS数量增加,沿晶界偏聚分布的情况更为严重.
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