以稻壳为原料,经磷酸浸渍,在400-600℃干馏炭化,行星式球磨机球磨后用KH570表面处理得到C/SiO2微粉,其进行了XRD衍射、比表面积、孔径分布、红外、扫描电镜和差热等分析表征。C/SiO2微粉样品的比表面积为308m2/g,孔径分布主要集中于80nm-140nm,中位径3.34μm。以C/SiO2微粉为改性剂增强环氧树脂,使复合体系的力学性能较纯环氧体系的有显著提高。
C/SiO2 micropowder was prepared from rice husk through phosphoric acid impregnation, 400 -600℃ carbonization, planetary ball milling, and KH570 surface treating. The micropowder was characterized by means of X-ray powder diffraction (XRD), specific surface area analysis, pore size measurement, infrared absorption spectrum fIR), differential scanning calorimetry (DSC) and scanning electron microscope (SEM). The results showed that the micropowder have a high specific surface area of 308m2/g, the pore size distributing within 80nm-140nm and the median diameter of about 3.34μm. The micropowder was used as a reinforcement modifier to epoxy resin, and some mechanical properties of the modifier composite were singularly enhanced.
参考文献
[1] | 李琳娜,应浩,孙云娟,李雪瑶.我国稻壳资源化利用的研究进展[J].生物质化学工程,2010(01):34-38. |
[2] | 周肇秋,马隆龙,李海滨,吴创之.中国稻壳资源状况及其气化/燃烧发电前景[J].可再生能源,2004(06):7-9. |
[3] | 卫延安,朱春山,蔡春,吕春绪.由稻壳灰制备活性炭的工艺及应用研究[J].中国粮油学报,2003(06):29-33. |
[4] | Tzong-Horng Liou .Preparation and characterization of nano-structured silica from rice husk[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2004(1/2):313-323. |
[5] | 于欣伟;赵国鹏;徐广蕙 等.用稻壳灰制取白炭黑工艺中提取率影响因素研究[J].化学工程,1998,4:51-55. |
[6] | Kalapathy U.;Shultz J.;Proctor A. .A simple method for production of pure silica from rice hull ash[J].Bioresource Technology: Biomass, Bioenergy, Biowastes, Conversion Technologies, Biotransformations, Production Technologies,2000(3):257-262. |
[7] | 欧阳东,陈楷.稻壳灰显微结构及其中纳米SiO2的电镜观察[J].电子显微学报,2003(05):390-394. |
[8] | 赵世琦;云会明 .刚性粒子增韧环氧树脂的研究[J].中国塑料,1999,9:35-39. |
[9] | 张金柱,汪信,陆路德,徐迎宾.纳米无机粒子对塑料增强增韧的"裂缝与银纹相互转化"机理[J].工程塑料应用,2003(01):20-22. |
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