LSGM固体电解质薄膜制备的研究进展

金属功能材料, 2011, 18(3): 84-88.

LSGM固体电解质薄膜制备的研究进展

石敏 ^1, , 庞志成 ^2, , 蒋云志 ^3, , 左如忠 ^4, , 许育东 ^5, , 王雷 ^6, , 于桂洋 ^7, , 陈云帮 ^8, , 王丽 ^9, , 伍光 ^10,

1.合肥工业大学,材料科学与工程学院,安徽合肥230009

2.合肥工业大学,材料科学与工程学院,安徽合肥230009

3.合肥工业大学,材料科学与工程学院,安徽合肥230009

4.合肥工业大学,材料科学与工程学院,安徽合肥230009

5.合肥工业大学,材料科学与工程学院,安徽合肥230009

6.合肥工业大学,材料科学与工程学院,安徽合肥230009

7.合肥工业大学,材料科学与工程学院,安徽合肥230009

8.合肥工业大学,材料科学与工程学院,安徽合肥230009

9.合肥工业大学,材料科学与工程学院,安徽合肥230009

10.合肥工业大学,材料科学与工程学院,安徽合肥230009

基金项目: 合肥工业大学2010年大学生创新性实验计划项目(cxsy102096) 教育部高等学校博士学科点专项科研基金新教师项目(200803591037) 合肥工业大学博士学位专项基金(GDBJ2008-008) 合肥工业大学2009年科技创新群体项目

关键词：固体电解质 , LSGM薄膜 , 薄膜制备方法

Prospect of Research on Preparing LSGM Electrolyte Film

Sr和Mg掺杂的稀土钙钛矿型氧化物LaGaO3(LSGM)是具有广泛应用前景的固体电解质材料.本文综述了LSGM薄膜制备的主要方法,讨论了各种方法的优缺点,最后对LSGM薄膜制备方法的进一步研究方向进行了展望.

参考文献

[1]	衣宝廉.燃料电池-原理·技术·应用[M].北京:化学工业出版社,2003:1-2.
[2]	景晓燕,李茹民,张密林.SOFC用固体电解质薄膜制备方法进展[J].应用科技,2000(02):19-21.
[3]	Minh N Q .Ceramic Fuel Cells[J].Journal of the American Chemical Society,1993,76(03):563-588.
[4]	Ishihara T;Matsuda H;Takita Y .Doped LaGaOa perovskite type oxide as a new oxide ionic conductor[J].Journal of the American Chemical Society,1994,116(09):3801-3803.
[5]	Goodenough J B;Feng M .A superior oxide-ion electrolyte[J].European Journal of Solid State and Inorganic Chemistry,1994,31(8-9):663-667.
[6]	刘铭飞 .中温陶瓷膜燃料电池制备科学研究与性能表征[D].中国科学技术大学,2008.
[7]	阎景旺,董永来,于春英,江义.中温固体氧化物燃料电池阳极基底及负载型电解质薄膜的研制[J].无机材料学报,2001(05):804-814.
[8]	Jinhua Piao;Kening Sun;Naiqing Zhang;Shen Xu .A study of process parameters of LSM and LSM-YSZ composite cathode films prepared by screen-printing[J].Journal of Power Sources,2008(1):288-295.
[9]	Ge X D;Huang X Q et al.Screen-printed thin YSZ films used as electrolytes for solid oxide fuel cells[J].Journal of Power Sources,2006,159(02):1048-1050.
[10]	张春成 .实用丝网印刷技术[J].印刷世界,2000,14(01):18-19.
[11]	Pelosato R;Sora I N et al.Preparation and characterisation of supported La0.83 Sr0.17 Ga0.83 Mg0.17 O2.83 thick films for application in IT-SOFCs[J].Solid-State Ionicis,2004,175(1-4):87-92.
[12]	Howatt G N;Breckenridge R G et al.Fabrication of thin ceramic sheets for capacitors[J].Journal of the American Ceramic Society,1947,30(01):237-242.
[13]	Howatt G N .Method of producting high dielectric high insulation ceramic plates[P].U S Pat,2582993,1952-10-06.
[14]	贺连星;温廷琏;吕之奕 .流延法制备陶瓷燃料电池电解质膜的研究进展[J].材料科学与工程,1997,15(03):15-18.
[15]	Fukui T;Ohara S et al.Performance of intermediate temperature sold oxide fuel cells with La (Sr)Ga(Mg)O3 electrolyte film[J].Journal of Power Sources,2002,106(1-2):142-145.
[16]	Zhang J;Liang E J et al.Rapid synthesis of La0.9 Sr0.1 Ga0.8 Mg0.2O3-(8)electrolyte by a CO2 laser and its electric properties for intermediate temperature solid state oxide full cells[J].Journal of Power Sources,2010,195(19):6758-6763.
[17]	M. Shi;N. Liu;Y.D. Xu .Preparation of electrolyte foils La_(0.85)Sr_(0.15)Ga_(0.85)Mg_(0.15)O_(2.85) (LSGM) by means of tape casting[J].Journal of Materials Processing Technology,2005(2):179-183.
[18]	Sasaki, K;Muranaka, M;Suzuki, A;Terai, T .Synthesis and characterization of LSGM thin film electrolyte by RF magnetron sputtering for LT-SOFCS[J].Solid state ionics,2008(21/26):1268-1272.
[19]	Bangwu Liu;Lidan Tang;Yue Zhang .Preparation And Characterization Of La_(0.9)sr_(0.1)ga_(0.8)mg_(0.2)o_(3-δ) Thin Film On The Porous Cathode For Sofc[J].International journal of hydrogen energy,2009(1):440-445.
[20]	Y. Yoo .Fabrication and characterization of thin film electrolytes deposited by RF magnetron sputtering for low temperature solid oxide fuel cells[J].Journal of Power Sources,2006(1):202-206.
[21]	Preparation of Ni-Fe bimetallic porous anode support for solid oxide fuel cells using LaGaO_3 based electrolyte film with high power density[J].Journal of Power Sources,2010(19):P.6294.
[22]	Ishihara T;Eto H;Yu J W.Intermediate temperature solid oxide fuel cells using LaGaO3 based oxide film deposited by PLD method[J].International Journal of Hydrogen Energy,2010
[23]	Kanazawa S.;Ito T.;Yamada K.;Ohkubo T.;Nomoto Y.;Ishihara T.;Takita Y. .Preparation of doped LaGaO3 films by pulsed laser deposition[J].Surface & Coatings Technology,2003(0):508-511.
[24]	Yan J W;Matsumoto H et al.Preparation of LaGaO3-based perovskite oxide film by a pulsed-laser ablation method and application as a solid oxide fuel cell electrolyte[J].Journal of Power Sources,2006,157(02):714-719.
[25]	Mathews T.;Antony MP.;Sellar JR.;Muddle BC.;Manoravi P. .Fabrication of La1-xSrxGa1-yMgyO3-(x plus y)/2 thin films by pulsed laser ablation[J].Solid state ionics,2000(1/4):397-402.
[26]	Bozza, Francesco;Polini, Riccardo;Traversa, Enrico .High performance anode-supported intermediate temperature solid oxide fuel cells (IT-SOFCs) with La0.8Sr0.2Ga0.8Mg0.2O3-delta electrolyte films prepared by electrophoretic deposition[J].Electrochemistry communications,2009(8):1680-1683.
[27]	Sora IN;Pelosato R;Simone A;Montanaro L;Maglia F;Chiodelli G .Characterization of LSGM films obtained by electrophoretic deposition (EPD)[J].Solid state ionics,2006(19/25):1985-1989.
[28]	Mathews T.;Sellar JR.;Muddle BC.;Rabu N. .Fabrication of La1-xSrxGa1-yMgyO3-(x+y)/2 thin films by electrophoretic deposition and its conductivity measurement[J].Solid state ionics,2000(1/4):111-115.

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