通过XRD、SEM、质谱和等温动力学性能测试等方法研究了Mg2CoH5/PrH3复合添加对Li-Mg-N-H体系动力学性能的影响.结果表明,以Mg2CoH5/PrH3复合体替代MgH2与LiNH2进行复合,该体系放氢反应过程中Mg2CoH5与LiNH2反应同时原位弥散析出Co,在Co和PrH3共同作用下该体系的放氢速率明显提高,在180℃、0.1 MPa下Mg2CoH5/PrH3+LiNH2体系50 min完成放氢过程.
参考文献
[1] | Chen P;Xiong ZT;Luo JZ;Lin JY;Tan KL .Interaction of hydrogen with metal nitrides and imides[J].Nature,2002(6913):302-304. |
[2] | Luo W .[J].Journal of Alloys and Compounds,2004,381:284-287. |
[3] | Chen P;Xiong Z et al.[J].Journal of Physical Chemistry,2003,B 107:10967-10970. |
[4] | David, WIF;Jones, MO;Gregory, DH;Jewell, CM;Johnson, SR;Walton, A;Edwards, PP .A mechanism for non-stoichiometry in the lithium amide/lithium imide hydrogen storage reaction[J].Journal of the American Chemical Society,2007(6):1594-1601. |
[5] | Liu, YF;Zhong, K;Luo, K;Gao, MX;Pan, HG;Wang, QD .Size-Dependent Kinetic Enhancement in Hydrogen Absorption and Desorption of the Li-Mg-N-H System[J].Journal of the American Chemical Society,2009(5):1862-1870. |
[6] | Ma, LP;Fang, ZZ;Dai, HB;Kang, XD;Liang, Y;Wang, PJ;Wang, P;Cheng, HM .Effect of Li3N additive on the hydrogen storage properties of Li-Mg-N-H system[J].Journal of Materials Research,2009(6):1936-1942. |
[7] | Sudik A;Yang J et al.[J].Physical Chemistry,2007,C 111:6568-6573. |
[8] | Luo S;Flanagan T B;Luo W .[J].Journal of Alloys and Compounds,2007,440:L13-L17. |
[9] | Liu Y;Hu J et al.[J].Materials Research,2007,22:1339-1345. |
[10] | Chen Y;Wang P et al.[J].International Journal of Hydrogen Energy,2007,32:1262-1268. |
[11] | Lewis G J;Sachtler J W A et al.[J].Journal of Alloys and Compounds,2007,446-447:355-359. |
[12] | Xiong Z;Wu G et al.[J].Journal of Alloys and Compounds,2006,417:190-194. |
[13] | Li Q;Chou K C et al.[J].International Journal of Hydrogen Energy,2004,29:843-849. |
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