铝电解惰性阳极的研究和应用对环境、能源和国民经济有着深远的影响.概述了近10年来4种铝电解惰性阳极的最新进展,评述了它们各自的优点及存在的问题,面临的挑战及应用前景.其中金属陶瓷、金属合金和梯度材料是当前研究的重点.尽管它们的设计方案不同,其原理都是利用金属改善阳极的导电导热性、抗热震性和可加工性;陶瓷或在阳极表面形成陶瓷以抵抗熔融冰晶石的腐蚀.
参考文献
| [1] | Edwards L;Kvande H .Inert anodes and other technology changes in the aluminum industry-the benefits[J].challenges and impActa on present technology,2001,53(05):28. |
| [2] | Pawlek R P.Inert anodes: an update[J].Light Metals,2002:449. |
| [3] | Pawlek R P .Recent developments of inert anodes for the primary aluminium industry,PartⅠ[J].Aluminium,1995,71(03):340. |
| [4] | Pawlek R P .Review of the reduction technology sessions,part Ⅱ[J].Aluminium,1996,72(06):400. |
| [5] | Report of the American Society of Mechanical Engineer,Technical Working Group on Inert Anode Technologies:under contract # DE-FC07-98ID13652 to The U.S.Department of Energy,Office of Industrial Technologies,July[R].,1999. |
| [6] | Haarberg G M.The interaction between tin oxide and cryolite-alumina melts, 9th Int Symp On Molten Salts, San Francisco, USA, 22-27 May 1994, Molten salts[M].Electrochemical Sociaety, Inc,1994:568. |
| [7] | Issaeva L et al.Electrochemical behaviour of tin dissolved in cryolite-alumina melts[J].Electrochimica Acta,1997,42(06):1011. |
| [8] | Dol.Densification of 0. 99SnO2-0. 01CuO mixture: evidence for liquid phase sintering[J].Journal of the European Ceramic Society,1992:19. |
| [9] | Galasiu R;Galasiu I;Comanescu I.SnO2-based inert anodes for aluminium electrolysis. PartⅠ: Method for increasing thermal shock resistance, Ⅷ[M].Al Symposium,1995 |
| [10] | Vecchio-Sadus A M.Tin oxide-based ceramics as inert anodes for aluminium smelting: a laboratory study[J].Light Metals,1996:259. |
| [11] | Galasiu R.SnO2-based inert anodes for aluminium electrolysis: Influence of Ag2O on the electrical and electrochemical properties, X[M].Al Syposium Slovak Norwegian Symposium on Aluminium Smelting Technology, Stara Lesna-Ziar nad Hronom,1999:35. |
| [12] | 吴贤熙,毛小浩.铝电解镍基惰性阳极的研究[J].贵州工业大学学报,1999(05):36-41. |
| [13] | 吴贤熙,毛小浩,安利娜,李军旗.铝电解镍基惰性阳极的研究（Ⅱ）[J].贵州工业大学学报（自然科学版）,2000(02):36-39,63. |
| [14] | 于先进,邱竹贤,金松哲.ZnFe2O4基材料在NaF-AlF3-Al2O3熔盐中的腐蚀[J].中国腐蚀与防护学报,2000(05):275-280. |
| [15] | AUGUSTIN C O;Srinivasan L K;Srinivasan K S .Inert anodes for environmentally clean production of aluminiumPart Ⅰ[J].Bulletin of Electrochemistry,1993,9(8-10):502. |
| [16] | Ray S P et al.Inert Anode Containing Metal Oxides,Copper and Nobel Metal[P].US 6126799,2000-10-03. |
| [17] | Chin P;Sides P J;Keller R .The transfer of nickel, iron and copper from hall cell melts into molten alominium[J].Canadian Metallurgical Quarterly,1996,35(01):61. |
| [18] | Olsen E;Thonstad J.The behaviour of nickel ferrite cermet materials as inert anodes[J].Light Metals,1996:249. |
| [19] | Olsen E;Thonstad J .Nickel ferrite as inert anodes in aluminium electrolysis: Part Ⅱ: material performance and long-term testing[J].Journal of Applied Electrochemistry,1999,29(03):301. |
| [20] | Lorentsen O A;Thonstad J;Dewing E W.Solubility of NiO and NiAl2O4 in cryolite-alumina melts[J].Proceedings-Electrochemical Society,2000:428. |
| [21] | Jentofsten T E.Solubility of FeO and FeAl2O4 in cryolite-alumina melts[J].Proceedings-Electrochemical Society,2000:473. |
| [22] | Dewing E. W.;Thonstad J. .Solutions of Iron Oxides in Molten Cryolite[J].Metallurgical and Materials Transactions, A. Physical Metallurgy and Materials Science,2000(4):609-613. |
| [23] | Ray S P;Woods R W .Controlled atmosphere for fabrication of cermet electrodes[P].US 5794112,1997-06-26. |
| [24] | Siba P R;Liu X .Inert anode containing base metal and noble metal useful for the electrolytic production of aluminium[P].US 6162334,1999-02-01. |
| [25] | Ray S P;Liu X;Weirauch D A .Electrolytic production of high purity aluminium using inert anodes[P].US 6217739,1999-11-01. |
| [26] | Sadoway D R .Inert Anode for the Hall-Héroult Cell: The Ultimate Materials Challenge[J].Journal of the Minerals,Metals & Materials Society,2001,53(05):34. |
| [27] | Hryn J N;Pellin M J.A dynamic inert metal anode[J].Light Metals,1999:377. |
| [28] | SEKHAR J A;de Nora V;Liu J J .Ultrastable anodes for aluminium Production cells[P].WO Pat,98/12,363,1996-09-23. |
| [29] | SEKHAR J A.Micropyretically synthesized porous nonconsumable anodes in the Ni-Al-Cu-Fe-X system[J].Light Metals,1997:347. |
| [30] | Duruz J J;de Nora V .Metal-based anodes for aluminium electrowinning cells[P].WO Pat,01/42,534,1999-12-09. |
| [31] | Duruz J J;de Nora V .Aluminium electro- winning cells operating with Ni-Fe alloy anodes[P].WO Pat,01/43,208,1999-12-09. |
| [32] | de Nora V;Duruz J J .Slurry for coating non-carbon metal-based anodes for aluminium production cells[P].WO Pat,99/036,593,1998-07-30. |
| [33] | de Nora V;Duruz J J .Non-carbon metal-based anodes for aluminium production cells[P].WO Pat,99/036,594,1998-07-30. |
| [34] | Duruz J J;de Nora V .Multi-layer non-carbon metal-based anodes for aluminium production cells[P].WO Pat,00/06,800,1999-01-08. |
| [35] | Duruz J J;de Nora V;Crottaz O .Cells for the electrowinning of aluminium having dimensionally stable metal-based anodes[P].WO Pat,00/06,802,1999-01-08. |
| [36] | 郭鉴镜 .美铝惰性阳极试验受阻[J].轻合金加工技术,2002,30(09):22. |
| [37] | Kvande H;Haupin W .Inert anodes for aluminium smelting: energy balances and environ-mental impact[J].Journal of the Minerals,Metals & Materials Society,2001,53(02):13. |
| [38] | Jomar Thonstand;Espen Olsen .Cell Operation and Metal Purity Challenges for the Use of Inert Anodes[J].JOM,2001(5):36-38. |
| [39] | Keniry J .The economics of inert anodes and wettable cathodes for alumiunium reduction cells[J].Journal of the Minerals,Metals & Materials Society,2001,53(05):43. |
| [40] | Craig Brown .Next Generation Vertical Electrode Cells[J].JOM,2001(5):39-42. |
| [41] | Beck T R;Brooks R J .Non consumable anode resistant to oxidation for use in a cell for the electrolytic recovery of aluminium by reduction of aluminium oxide[P].BRPat,application94/00,328,1994-01-25. |
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