对普通竹炭进行了表面化恘处理,并研究了此竹炭对Au(III)的吸附性能。实验结果表明:改性后竹炭对Au(III)的吸附性能有明显的提高,且吸附过程从以物理吸附为主转化为以化恘吸附为主。如果条件控制得当,吸附率可达97%以上,说明处理后的竹炭可以有效回收水相中的Au(III)。红外图谱和元素分析对改性前后的竹炭表征的结果表明:含氧基团和含氮基团的含量有明显的增加,且含氧基与含氮基与Au(III)配位成键。
Surface of ordinary bamboo-charcoal was pretreated with chemical methods, and the adsorption performance of the bamboo-charcoal for Au(III) was investigated. Results showed that the adsorption capacity of the modified bamboo-charcoal for Au(III) was elevated remarkably. The adsorption process was changed from the physical adsorption to the chemical adsorption. If the condition is properly controlled, The adsorption rate could reach more than 97%. Therefore, the bamboo-charcoal can effectively be used to recycle Au(III) in aqueous. Fourier transform infrared (FT-IR) spectrometer, element analysis demonstrated that the contents of O-containing groups and N-containing groups on the bamboo-charcoal surface were increased. The sorption mechanism showed that O-containing groups and N-containing groups on the bamboo-charcoal were combined with Au (III) to form coordination bond.
参考文献
[1] | 丁良鑫,王士瑞,郑小龙,陈煜,陆天虹,曹殿学,唐亚文.炭载体改性对炭载Pd催化剂电催化性能的影响[J].物理化学学报,2010(05):1311-1316. |
[2] | 张启伟,王桂仙.改性竹炭对银(I)的吸附性能与机理[J].贵金属,2009(02):22-25. |
[3] | 杨坤彬,彭金辉,郭胜惠,张利波,黄孟阳,夏洪应,张世敏.提金活性炭的研究现状及其展望[J].黄金,2007(01):46-50. |
[4] | 吴开金.竹节制备提金活性炭及其表征[J].林业科学,2009(12):124-128. |
[5] | 于化江,张立艳,赵梅青.高锰酸钾改性活性炭对Au3+的吸附性能研究[J].河北师范大学学报(自然科学版),2010(03):329-331. |
[6] | 北川浩;铃木廉一郎;鹿政理.吸附的基础与设计[M].北京:化学工业出版社,1983:33-45. |
[7] | 复旦大学.物理化学实验[M].北京:高等教育出版社,1993:187-197. |
[8] | GB/T 12496.8-1999.木质活性炭试验方法碘吸附值的测定[S].北京:中国标准出版社,1999. |
[9] | 张叔良;易大年;吴天明.红外光谱分析与新技术[M].上海:中国医药科技出版社,1993:76-125. |
[10] | Van Deventer J S J;van der Merwe P F .The mechanism of elution of gold cyanide from activated carbon[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1994,25(08):829-838. |
[11] | 王桂仙,张启伟,张晓燕.改性竹炭对钯(Ⅱ)的吸附性能研究[J].贵金属,2011(03):42-45. |
[12] | 鹿政理.吸附的基础与设计[M].北京:化学工业出版社,1983:33-36. |
[13] | 朱云,胡汉,郭淑仙.活性炭吸附铂和钯的实验研究[J].稀有金属,2001(06):474-477. |
[14] | 傅献彩;沈文霞;姚天杨.物理化学[M].北京:高等教育出版社,2006:68-370. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%