微波辅助离子液体法在无机纳米材料合成中的应用

材料导报, 2008, 22(7): 53-64.

微波辅助离子液体法在无机纳米材料合成中的应用

徐晓冬 ^1, , 高秀敏 ^2, , 刘建清 ^3, , 张密林 ^4,

1.哈尔滨工程大学材料科学与化学工程学院,哈尔滨,150001

2.哈尔滨工程大学材料科学与化学工程学院,哈尔滨,150001

3.哈尔滨工程大学材料科学与化学工程学院,哈尔滨,150001

4.哈尔滨工程大学材料科学与化学工程学院,哈尔滨,150001

基金项目: 高等学校博士学科点专项科研项目(20052017019) 哈尔滨工程大学校科研和教改项目(HEUFT05018)

关键词：微波辅助离子液体法 , 无机纳米材料 , 绿色化学 , 离子液体 , 微波加热

Application of Microwave-assisted Ionic Liquids Method in Synthesis of Inorganic Nano-materials

作为一种新型的绿色化学合成方法,微波辅助离子液体法,融合了离子液体与微波加热法的优点.简要介绍了微波加热和加速化学反应的原理,总结了微波辅助离子液体法合成无机纳米材料的特点,综述了微波辅助离子液体法在无机纳米材料合成中的应用,展望了该方法在无机纳米材料合成方面的应用前景.

参考文献

[1]	张萌,徐晓冬,赵志红,张密林.微波辅助离子液体法在液相合成中的应用[J].化学通报（印刷版）,2007(07):513-520.
[2]	Zhu Y J;Wang W W;Qi R J et al.Microwave-assisted synthesis of single-crystalline tellurium nanorods and nanowires[J].Angewandte Chemie International Edition,2004,43(11):1410.
[3]	金钦汉;戴树珊;黄卡玛.微波化学[M].北京:科学出版社,1999
[4]	Gedye R;Smith F;Westaway K et al.The use of microwave ovens for rapid organic synthesis[J].Tetrahedron Letters,1986,27(03):279.
[5]	Baghurst D R;Chippindale A M;Mingos D M P .Microwave syntheses for super-conducting ceramics[J].Nature,1988,332(24):311.
[6]	张锁江;吕兴梅.离子液体--从基础研究到工业应用[M].北京:科学出版社,2006
[7]	Jiang Y;Zhu YJ .Microwave-assisted synthesis of nanocrystalline metal sulfides using an ionic liquid[J].Chemistry Letters,2004(10):1390-1391.
[8]	Wei-Wei Wang;Ying-Jie Zhu .Shape-controlled synthesis of zinc oxide by microwave heating using an imidazolium salt[J].Inorganic Chemistry Communications,2004(9):1003-1005.
[9]	Li ZH;Liu ZM;Zhang JL;Han BX;Du JM;Gao YN;Jiang T .Synthesis of single-crystal gold nanosheets of large size in ionic liquids[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,2005(30):14445-14448.
[10]	Lanzheng Ren;Lingjie Meng;Qinghua Lu .Fabrication of Octahedral Gold Nanostructures Using an Alcoholic Ionic Liquid[J].Chemistry Letters,2008(1):106-107.
[11]	Jacob D S;Genish I;Klein L et al.Carbon-coated sore shell structured copper and nickel nanoparticles synthesized in an ionic liquid[J].Journal of Physical Chemistry B,2006,110(36):17711.
[12]	J. Wang;J. Cao;B. Fang .Synthesis and characterization of multipod, flower-like, and shuttle-like ZnO frameworks in ionic liquids[J].Materials Letters,2005(11):1405-1408.
[13]	Cao JM;Wang J;Fang BQ;Chang X;Zheng MB;Wang HY .Microwave-assisted synthesis of flower-like ZnO nanosheet aggregates in a room-temperature ionic liquid[J].Chemistry Letters,2004(10):1332-1333.
[14]	曹洁明,王军,房宝青,郑明波,陆红霞,常欣,王海燕.离子液体中不同形貌ZnO纳米材料的合成及表征[J].物理化学学报,2005(06):668-672.
[15]	W.-W. Wang;Y.-J. Zhu;G.-F. Cheng .Microwave-assisted synthesis of cupric oxide nanosheets and nanowhiskers[J].Materials Letters,2006(5):609-612.
[16]	Liang ZH;Zhu YJ .Microwave-assisted synthesis of single-crystalline CuO nanoleaves[J].Chemistry Letters,2004(10):1314-1315.
[17]	Xu X D;Zhang M;Feng J.Shape-controlled synthesis of single-crystalline cupric oxide by microwave heating using an ionic liquid (In press)[J].Materials Letters,2008
[18]	Zhang M;Xu XD;Zhang ML .Microwave-assisted synthesis and characterization of CuO nanocrystals[J].Journal of Dispersion Science and Technology,2008(4):508-513.
[19]	Yang L X;Zhu Y J;Wang W W et al.Synthesis and formation mechanism of nanoneedles and nanorods of manganese oxide octahedral molecular sieve using an ionic liquid[J].Journal of Physical Chemistry B,2006,110(13):6609.
[20]	Ding KL;Miao ZJ;Liu ZM;Zhang ZF;Han BX;An GM;Miao SD;Xie Y .Facile synthesis of high quality TiO2 nanocrystals in ionic liquid via a microwave-assisted process[J].Journal of the American Chemical Society,2007(20):6362-6363.
[21]	Dong WS;Li MY;Liu CL;Lin FQ;Liu ZT .Novel ionic liquid assisted synthesis of SnO2 microspheres[J].Journal of Colloid and Interface Science,2008(1):115-122.
[22]	Jiang Y;Zhu Y J .Microwave-assisted synthesis of sulfide M2S3(M) Bi,Sb) nanorods using an ionic liquid[J].Journal of Physical Chemistry B,2005,109(10):4361.
[23]	Jiang Y;Zhu YJ;Cheng GF .Synthesis of Bi2Se3 nanosheets by microwave heating using an ionic liquid[J].Crystal growth & design,2006(9):2174-2176.
[24]	Gunnar Bilhler;Claus Feldmann .Microwave-Assisted Synthesis of Luminescent LaPO_4:Ce,Tb Nanocrystals in Ionic Liquids[J].Angewandte Chemie,2006(29):4864-4867.
[25]	Zharkouskaya A;Feldmann C;Trampert K;Heering W;Lemmer U .Ionic liquid based approach to luminescent LaPO4 : Ce,Tb nanocrystals: Synthesis, characterization and application[J].European journal of inorganic chemistry,2008(6):873-877.
[26]	Yun-Peng Xu;Zhi-Jian Tian;Shao-Jun Wang;Yue Hu;Lei Wang .Microwave-Enhanced Ionothermal Synthesis of Aluminophosphate Molecular Sieves[J].Angewandte Chemie,2006(24):3965-3970.
[27]	Wang WW;Zhu YJ .Synthesis of PbCrO4 and Pb2CrO5 rods via a microwave-assisted ionic liquid method[J].Crystal growth & design,2005(2):505-507.
[28]	Wei-Wei Wang;Ying-Jie Zhu .Microwave-assisted synthesis of cobalt oxalate nanorods and their thermal conversion to Co_3O_4 rods[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2005(11):1929-1935.
[29]	Jacob DS;Bitton L;Grinblat J;Felner I;Koltypin Y;Gedanken A .Are ionic liquids really a boon for the synthesis of inorganic materials? A general method for the fabrication of nanosized metal fluorides[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(13):3162-3168.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网

微波辅助离子液体法在无机纳米材料合成中的应用

Application of Microwave-assisted Ionic Liquids Method in Synthesis of Inorganic Nano-materials

参考文献