ZnS纳米晶须的溶剂热法制备及机理研究

稀有金属材料与工程, 2004, 33(z1): 254-257.

ZnS纳米晶须的溶剂热法制备及机理研究

钟敏 ^1, , 韩高荣 ^2, , 赵高凌 ^3, , 翁文剑 ^4, , 杜丕一 ^5, , 沈鸽 ^6,

1.浙江大学,浙江,杭州,310027

2.浙江大学,浙江,杭州,310027

3.浙江大学,浙江,杭州,310027

4.浙江大学,浙江,杭州,310027

5.浙江大学,浙江,杭州,310027

6.浙江大学,浙江,杭州,310027

基金项目: 教育部跨世纪优秀人才培养计划国家自然科学基金(69890230,59902006)

关键词：溶剂热法 , 硫化锌 , 纳米晶须

Formation and Mechanism of ZnS Nanowhiskers via Solvothermal Route

在120℃下反应12 h,用乙二胺为溶剂,通过溶解热法制备出六方纤锌矿型的ZnS纳米晶须.ZnS纳米晶须的结构为定向排列的条纹状纹理.ZnS纳米晶须在乙二胺中的生长过程可以用溶剂配位分子模板机理加以解释.并讨论了乙二胺作为样品形态结构导向配位分子模板的作用.采用X射线衍射(XRD),透射电子显微镜(TEM),红外吸收光谱(IR)对样品进行了表征.

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ZnS纳米晶须的溶剂热法制备及机理研究

Formation and Mechanism of ZnS Nanowhiskers via Solvothermal Route

参考文献