稀土Gd掺杂对锆基块体非晶合金玻璃形成能力及力学性能的影响

金属学报, 2009, 45(2): 243-248.

稀土Gd掺杂对锆基块体非晶合金玻璃形成能力及力学性能的影响

孙亚娟魏先顺黄永江沈军

(哈尔滨工业大学材料科学与工程学院

School of Materials Science and Engineering

Harbin Institute of Technology

Harbin 150001

基金项目: 国家自然科学基金资助项目50771040

关键词：锆基块体非晶合金 , glass forming ability , mechanical property

EFFECT OF Gd ADDITION ON THE GLASS FORMING ABILITY AND MECHANICAL PROPERTIES IN A Zr–BASED BULK AMORPHOUS ALLOY

SUN Yajuan WEI Xianshun HUANG Yongjiang SHEN Jun

Keywords： Zr--based bulk amorphous alloy , 玻璃形成能力 , 力学性能

适量的Gd掺杂可提高Zr_50.7Cu₂₈Ni₉Al_12.3块体非晶合金的玻璃形成能力, 当Gd元素掺杂量 (原子分数) 为1%时, 即(Zr_50.7Cu₂₈Ni₉Al_12.3)₉₉Gd₁, 柱状非晶合金直径可达16 mm (不掺杂时为14 mm). 稀土Gd掺杂降低了锆基块体非晶合金的断裂强度与塑性变形能力. 随着Gd含量的增加, 其断裂方式由单一的剪切断裂转变为剪切断裂与破碎断裂的复合形式, 且含Gd元素掺杂的非晶合金断口呈现了脉状纹络与纳米周期性条纹共存的特征.

The glass forming ability (GFA) of a newly developed Zr_50.7Cu₂₈Ni₉Al_12.3 alloy can be improved by minor addition of Gd element, for example, the amorphous alloy Zr_50.7Cu₂₈Ni₉Al_12.3 has a critical diameter of 14 mm, but the alloy added by 1%Gd (atomic fraction), (Zr_50.7Cu₂₈Ni₉Al_12.3)₉₉Gd₁,
has 16 mm critical diameter. However, the Gd addition decreases the fracture strength and plastic strain under compressive condition. Meanwhile, with Gd addition increasing, the fracture mode transforms from pure shear to shear with hysterical failure. A combination of vein pattern and nanoscale corrugations can be clearly observed on the fracture surfaces of the alloys with Gd addition.

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