从气相、固相、液相3个方面分别评述了纳米CeO2制备技术的最新研究进展,并对各种制备方法进行了比较分析,得出了各种制备方法的优缺点.与气相法相比,液相沉淀法具有设备简单、无需高真空等苛刻物理条件、易放大等优点;与固相法相比,液相沉淀法制备的粉体纯度高、团聚少,易实现工业化生产,发展前景广阔.但液相沉淀法也存在纳米CeO2产品颗粒团聚、粒度分布不均匀、单分散性差等缺点,可以通过研究纳米CeO2的成核和生长机制、过程影响因素等来改善产品质量.
The research progress of nano-CeO2 preparation is reviewed separately from the gas phase, solid phase and liquid-phase. Advantages and disadvantages of above preparation methods are obtained through comparing and analyzing. Compared with the gas-phase, liquid phase precipitation method exhibits simple equipment, no need of high vacuum,easy to enlarge. Compared with the solid phase method, liquid-phase deposition has the following disadvantages:particle agglomeration, non-uniform particle size distribution, poor monodispersity. It is suggested that studies of nucleation and growth mechanisms and influencing factors of synthesis process can improve product quality.
参考文献
| [1] | 刘伯元,黄锐,赵安赤.非金属纳米材料[J].中国粉体技术,2001(01):12-18. |
| [2] | 倪嘉缵;洪广言.稀土新材料及新流程进展[M].北京:科学出版社,1998 |
| [3] | Chuang Feng-Yi et al.Cerium dioxide/polyaniline core-shell nanocomposites[J].Journal of Colloid and Interface Science,2008,320:194. |
| [4] | Andreas T;Wei Liu et al.Redox activity of nonstoichiometric cerium oxide-based nanocrystalline catalysts[J].Journal of Catalysis,1995,157:42. |
| [5] | Suzuki M;Kagawa M et al.Synthesis of ultrafine singlecomponent oxide particle by the spray ICP technique[J].Journal of Materials Science,1992,27:679. |
| [6] | Guillou N;Nistor L C et al.Microstructural studies of anocrysalline CeO2 produced by gas con-densation[J].Nano-Structured Materials,1997,8(05):545. |
| [7] | 盖广清,董相廷,王进贤,李天乐,徐淑芝.室温固相反应法制备CeO2纳米晶[J].稀有金属材料与工程,2007(z3):437-439. |
| [8] | Tsai Ming-Shyong .Formation of nanocrystalline cerium oxide and crystal growth[J].Journal of Crystal Growth,2005,274(03):632. |
| [9] | Chen Huey-Ing et al.Synthesis of nanocrystalline cerium oxide particles by the precipitation method[J].Ceramics International,2005,31:795. |
| [10] | Zhang Yanwei et al.Effect of preparation method on platinum-ceria catalysts for hydrogen iodide decomposition in sulfur-iodine cycle[J].International Journal of Hydrogen Energy,2008,33:602. |
| [11] | 郭锋,王晓东,宫继成.草酸盐沉淀法制备纳米CeO2研究[J].内蒙古工业大学学报（自然科学版）,2008(01):25-29. |
| [12] | Zhang Qiuli;Yang Zhimao;Ding Bingjun .Synthesis of cerium oxide nanoparticles by the precipitation method[J].Materials Science Forum,2009,610-613:233. |
| [13] | 高岚,屈一新,宋晓岚,满艳茹.共沸精馏法制备氧化铈纳米粉体及其煅烧动力学[J].硅酸盐学报,2005(09):1157-1162. |
| [14] | 袁鹏,李保平,王介强.微波均相沉淀法合成纳米粉体的研究进展[J].中国粉体技术,2008(02):50-53. |
| [15] | Yuan Wenhui;Bi Huaiqing .Structure characterization of nanosized cerium oxide particles prepared by homogeneous precipitation[J].J South China University of Technology,2004,32:52. |
| [16] | Zou Zhiqiang;Meng Ming et al.Synthesis and characterization of CuO/Ce1-x Tix O2 catalysts used for low-temperature CO oxidation[J].Journal of Hazardous Materials,2009,30:835. |
| [17] | 刘锦淮,刘伟,焦正,余增亮.纳米二氧化铈化学共沉淀法制备及结构表征[J].电子元件与材料,2003(07):1-2. |
| [18] | Tang Bing et al.Preparation of nano-sized magnetic particles from spent pickling liquors by ultrasonic-assisted chemical co-precipitation[J].Journal of Hazardous Materials,2009,163:1173. |
| [19] | 郭雨,董秀芳,石国亮,李裕,刘有智.络合沉淀法制备高纯纳米二氧化钛[J].无机盐工业,2006(04):19-21. |
| [20] | Rojas R;Perez MR;Erro EM;Ortiz PI;Ulibarri MA;Giacornelli CE .EDTA modified LDHs as Cu2+ scavengers: Removal kinetics and sorbent stability[J].Journal of Colloid and Interface Science,2009(2):425-431. |
| [21] | Lee Ka-Eun;Wang Mingsong et al.Structural,electrical and optical properties of sol-gel AZO thin filrms[J].Current Applied Physics,2009,9:683. |
| [22] | Kim Nam-Jung;Choi Seung-li et al.Nanostructures and luminescence properties of porous ZnO thin films prepared by sol-gel process[J].Current Applied Physics,2009,9:643. |
| [23] | Chandradass J et al.Effect of different fuels on the aluminaceria composite powders synthesized by sol-gel auto combustion method[J].Journal of Alloys and Compounds,2009,479(1-2):363. |
| [24] | 张伟,邱克辉,陈俊才,柳戌昊.溶胶-凝胶法制备纳米二氧化铈[J].技术与市场（上半月）,2008(04):60-61. |
| [25] | 董相廷;胡耀;张伟 等.聚乙二醇凝胶法制备二氧化铈纳米晶体[J].长春光学精密机械学院学报,1999,22(04):1. |
| [26] | Tok A I Y et al.Hydrothermal synthesis of CeO2 nano-particles[J].J Mater Process Techn,2007,190:217. |
| [27] | Christoph R et al.Microemulsion approach to neodymium,europium,and ytterbium oxide/hydroxide colloids-Effects of precursors and preparation parameters on particle size and crystallinity[J].Journal of Colloid and Interface Science,2008,325:179. |
| [28] | Boutonnet M;Kizling J;Stenius P .The preparation of monodisperse colloidal mater particles from microemulsions[J].Colloids and Surfaces,1982,5:209. |
| [29] | 石硕,鲁润华,汪汉卿.W/O微乳液中CeO2超细粒子的制备[J].化学通报,1998(12):51-53. |
| [30] | 李秀珍,潘湛昌,肖楚民,张环华.纳米二氧化铈的制备方法研究[J].化工装备技术,2002(06):20-22. |
| [31] | Jadhav L D;Chourashiya M G et al.Synthesis of nanocrystalline Gd doped ceria by combustion technique[J].Journal of Alloys and Compounds,2009,470:383. |
| [32] | Slavica Zec;Snezana Boskovic;Branka Kaluderovic .Chemical reduction of nanocrystalline CeO_2[J].CERAMICS INTERNATIONAL,2009(1):195-198. |
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