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印染工业的发展加剧了环境污染,传统的处理染料废水的方法存在许多难以克服的缺点.从保护环境和节省能源的角度出发,人们对TiO2应用在染料污水降解领域的研究给予了较大的关注.本文制备出上转换发光材料掺杂的纳米TiO2光催化剂.用XRD和TEM对这种催化剂进行了表征,通过在可见光下降解亚甲基兰溶液对样品的光催化活性进行了评价,研究了掺杂浓度,样品投放量以及光照时间对催化剂的光催化活性的影响.结果表明掺杂样品在可见光下能有效地分解有机物,而未掺杂样品则产生了大量有毒中间产物,因此上转换发光材料掺杂的TiO2光催化剂在可见光下具有较好的光催化活性.

参考文献

[1] Michael R. Hoffmann;Scot T. Martin;Wonyong Choi;Detlef W. Bahnemann .Environmental Applications of Semiconductor Photocatalysis[J].Chemical Reviews,1995(1):69-96.
[2] Herrmann J M;Guillard C;Pichat P .Heterogeneous photocatalysis:an emerging technology for water treatment[J].Catalysis Today,1993,17(32):7-20.
[3] Ding Z;Lu G Q;Greenfield P F .Role of the crystallite phase of TiO2 in heterogeneous photocatalysis for phenol oxidation in water[J].Journal of Physical Chemistry B,2000,104(19):4815-4820.
[4] Anders Hagfeld;Michael Graetzel .Light-Induced Redox Reactions in Nanocrystalline Systems[J].Chemical Reviews,1995(1):49-68.
[5] Klosek S;Raftery D .Visible light driven V-doped TiO2 photocatalyst and its photooxidation of ethanol[J].Journal of Physical Chemistry B,2001,105(14):2815-2819.
[6] Hongmei Luo;Tsuyoshi Takata;Yungi Lee;Jinfeng Zhao;Kazunari Domen;Yushan Yan .Photocatalytic Activity Enhancing for Titanium Dioxide by Co-doping with Bromine and Chlorine[J].Chemistry of Materials,2004(5):846-849.
[7] Hongyan Liu;Lian Gao .Codoped Rutile TiO_2 as a New Photocatalyst for Visible Light Irradiation[J].Chemistry Letters,2004(6):730-731.
[8] Wei HY.;Wu YS.;Lun N.;Zhao F. .Preparation and photocatalysis of TiO2 nanoparticles co-doped with nitrogen and lanthanum[J].Journal of Materials Science,2004(4):1305-1308.
[9] Ishibashi Ken-ichi .Quantum yields of active oxidative species formed on TiO_2 photocatalyst[J].Journal of Photochemistry and Photobiology, A. Chemistry,2000(1/2):139-142.
[10] Wang J;Wen FY;Zhang ZH;Zhang XD;Pan ZJ;Zhang P;Kang PL;Tong J;Wang L;Xu L .Investigation on degradation of dyestuff wastewater using visible light in the presence of a novel nano TiO2 catalyst doped with upconversion luminescence agent[J].Journal of Photochemistry and Photobiology, A. Chemistry,2006(1/2):189-195.
[11] So CM.;Cheng MY.;Yu JC.;Wong PK. .Degradation of azo dye Procion Red MX-5B by photocatalytic oxidation[J].Chemosphere,2002(6):905-912.
[12] Ding Z;Zhu H Y;Greenfield P F et al.Characterization of pore stucture and coordination of titanium in TiO2 and SiO2-TiO2 sol-pillared clays[J].Journal of Colloid and Interface Science,2001,238(06):267-272.
[13] I.M.Arabatzis;T.Stergiopoulos;P.Falaras;D.Andreeva;S.Kitova;S.G.Neophytides .Characterization and photocatalytic activity of Au/TiO_2 thin films for azo-dye degradation[J].Journal of Catalysis,2003(1):127-135.
[14] 蒋伟川;谭湘萍 .载银TiO2半导体催化剂降解染料水溶液的研究[J].环境科学,1995,16(02):15-19.
[15] Ammar Houas;Hinda Lachheb;Mohamed Ksibi .Photocatalytic degradation pathway of methylene blue in water[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,2001(2):145-157.
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