利用溶剂热法合成了硫代锡酸铯Cs4Sn5S12,单晶X-射线衍射结果表明Cs4Sn5S12属正交晶系,Pbca空间群,a=1.4232(4) nm,b=1.3161 (4) nm,c =1.6372(5) nm,α=90°,Z=4.化合物Cs4 Sn5S12中含有由八面体SnS6和三角双锥SnS5连接形成的层状阴离子[Sn5S12]4-∞.[Sn5S12]4-∞结构中有两种类型硫原子:连接六配位锡原子和五配位锡原子的硫原子以及只与两个五配位锡原子相连的硫原子.紫外-可见漫反射光谱表明Cs4Sn5S12为半导体,禁带宽度为2.3 eV.
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