总结了近年来聚乳酸合成的研究成果,详细介绍了乳酸2种聚合机理:乳酸的直接聚合及丙交酯开环聚合的理论研究进展,比较了各自的优缺点,归纳了影响聚乳酸降解的因素,并概述了聚乳酸制品的应用及生产,对聚乳酸的发展前景进行了展望.
参考文献
| [1] | 麦杭珍;赵耀明 .聚乳酸的成型加工及降解性能[J].塑料工业,2001,28(05):28. |
| [2] | 章悦庭,睦伟民,俞显芳.生物降解三元共混材料聚乳酸/淀粉/聚乙烯的研制[J].中国纺织大学学报,1997(02):34-38. |
| [3] | 李士范.采用玉米资源开发可生物降解纤维--聚乳酸纤维[J].广西化纤通讯,2001(02):19-21. |
| [4] | Masanobu Ajioka;Katashi Enomoto;Kazuhiko Suzuki .Basic Properties of Polylactic Acide Produced by the Direct Condensation Polymerization of Lacic Acid[J].Bulletin of the Chemical Society of Japan,1995,68:2125. |
| [5] | 王征,王婷,赵学明.直接缩合法合成聚乳酸[J].天津大学学报,2000(01):48-50. |
| [6] | Dubois Ph;Jacobs C et al.Mechanism and Kinetics of lactide Homopolymerization by Aluminum Isopropoxide[J].Macromolecules,1991,24:2266. |
| [7] | 秦志忠;杨百春;曹雪琴 .生物降解材料-聚乳酸的直接合成研究[J].合成技术及应用,2000,15(01):12. |
| [8] | 赵耀明,张军,麦杭珍.直接缩聚法合成聚乳酸的研究[J].合成纤维,2001(03):3-5,8. |
| [9] | Seong Ihf Woo;Bong Oh Kim et al.Polymerization of Aqueous Lactic Acid to Prepare Molecular Weight Poly(lactic acid)by Chain-extending With Hexamethylene Diisocyanace[J].Polymer Bulletin,1995,33:415. |
| [10] | Patrick V Bonsignore .Production of High Molecular Weigh Polylactic Acid[P].United States Patent,5 470 944,1995. |
| [11] | Kari Hiltunen;Jukka V SeppAl et al.Use of Hydroxyl Terminated Prepolymer in Urethane Synthesis[J].Journal of Applied Polymer Science,1997,63:1091. |
| [12] | Moon S I;Lee C W et al.Melt/solid Polycondensation of l-lactic acid:an alternatire route to poly (L-lactic acid)with high molecular weight[J].Polymer,2001,42:5059. |
| [13] | 娄玲,尹静波,高战团,梁奇志,董丽松,陈学思,景遐斌.L-丙交酯和聚L-乳酸的制备与性能[J].高分子材料科学与工程,2003(02):72-75. |
| [14] | 邓先模;袁明龙 .生物降解性聚酯的合成方法[P].CN:96117591,1996. |
| [15] | John wiley .Synthesis of PDLLA Hpmppolymers with Different Molecular Weight[J].Journal of Applied Polymer Science,1996,59:561. |
| [16] | Ching-Huei Huang;Fa-Cherng Wang;Bao-Tsan Ko;Te-Liang Yu;Chu-Chieh Lin .Ring-Opening Polymerization of #epsilon#-Caprolactone and L-Lactide Using Alumium Thiolates as Intiator[J].Macromolecules,2001(3):356-361. |
| [17] | Maria Ryner;Kajsa Stridsberg;Ann-Christine Albertsson;Henrik von Schenck;Mats Svensson .Mechanism of Ring-Opening Polymerization of 1,5-Dioxepan-2-one and L-Lactide with Stannous 2-Ethylhexanoate. A Theoretical Study[J].Macromolecules,2001(12):3877-3881. |
| [18] | Henrik yon schenck;Maria Ryner .Ring-Opening Polymerization of Lactones and lactides with Sn ( Ⅳ ) and Al ( Ⅲ )Initiators[J].Macromolecules,2002(35):1556. |
| [19] | Katherine B Aubrecht;Marc A Hillmyer .Polymerization of lactide by Monomeric Sn( Ⅱ ) Alkoxide Complexes[J].Macromolecules,2002(35):644. |
| [20] | Krichedorf H R;Bjorn Fechner .Resorbable Networks by Combined Ring-expansion Polymerization and Ring-openingPolymerization of ε-Caprolactone or D,L-lactide[J].Macromolecules,2001,34:3514. |
| [21] | 由英才;鲁格;申玉晖.聚乳酸的合成应用及降解研究[J].中国生物医学工程学报,1985(04):244. |
| [22] | De Jong S J;Arias E R et al.New Insights into the Hydrolytic Degredation of Poly(lactic acid):participation of the alkohol terminus[J].Polymer,2001,42:2795. |
| [23] | Hironbu Fukuzaki;Masaku Yoshida .Synthesis of Copoly(D,L-lactic acid) with Relatively low Molecular Weight and in Vitro Degredation[J].European Polymer Journal,1989(25):1019. |
| [24] | 王征 .直接缩合法合成聚乳酸的研究及工艺条件的筛选[D].天津:天津大学,2000. |
| [25] | Cam D.;Marucci M. .INFLUENCE OF RESIDUAL MONOMERS AND METALS ON POLY (L-LACTIDE) THERMAL STABILITY[J].Polymer: The International Journal for the Science and Technology of Polymers,1997(8):1879-1884. |
| [26] | Seppo Vainionpaa;Pentti Rokkanen .Surgical Applications of Biodegradable Polymers in Human Tissues[J].Prog Polym Vol,1989,14:679. |
| [27] | 眭伟民;戎戟;俞显芳 等.聚乳酸的合成及性能的研究[J].中国纺织大学学报,1996,22(05):9. |
| [28] | Hideto Tsuji;Shinya Miyauchi .Poly(L-lactide): 7. Enzymatic hydrolysis of free and restricted amorphous regions in poly(L-lactide) films with different crystallinities and a fixed crsytalline thickness[J].Polymer: The International Journal for the Science and Technology of Polymers,2001(9):4463-4467. |
| [29] | 麦杭珍 .可生物降解材料——聚乳酸的研究[D].华南理工大学,2001. |
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