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针对酚醛先驱体C/C复合材料液相浸渍制备工艺各组分相的化学转化特性,基于Arrhenius方程建立了C/C复合材料液相浸渍制备工艺力学模型,详细分析了固化-炭化和石墨化两个重要的工艺阶段各组分相的体积变化规律,得到的气孔体积分数与Micro-CT系统扫描处理的细编穿刺C/C复合材料微结构图像中气孔体积分数相吻合,并结合均匀化方法对制备过程材料基体有效弹性模量进行了预测.结果表明:材料基体的有效弹性模量随着致密化次数的增加而增大,在每一次致密化过程中材料基体的有效弹性模量先增大后减小,石墨化工艺过程中材料基体的有效弹性模量达到某一值后保持平稳.

参考文献

[1] 罗瑞盈.碳/碳复合材料制备工艺及研究现状[J].兵器材料科学与工程,1998,21(1):64-69.Luo Ruiying.Present study situation and technology of preparation for carbon/carbon composites[J].Ordnace Material Science and Engineering,1998,21(1):64-69.
[2] 艾艳玲,李铁虎.快速致密化制备C/C复合材料的新发展[J].材料导报,2005,19(7):90-96.Ai Yanling,Li Tiehu.Summary of rapid densification techniques for fabrieation of carbon/carbon composites[J].Materials Review,2005,19(7):90-96.
[3] 姜开宇,李贺军,李克智.2D炭/炭复合材料CVI过程的数值模拟研究[J]..宇航学报,1999,20(4):104-107.Jiang Kaiyu,Li Hejun,Li Kezhi.Numerical simulation of chemical vapor infiltration for 2D C/C composites[J].Journal of Astronautics,1999,20(4):104-107.
[4] Jiang K Y,Li H J,Wang M J.The numerical simulation of thermal-gradient CVI process on positive pressure condition[J].Mater Lett,2002,54:419-423.
[5] 姜开宇,李贺军,侯向辉,李克智.轴对称C/C复合材料等温CVI过程的数值模拟研究[J].西北工业大学学报,2000,18(4):665-668.Jiang Kaiyu,Li Hejun,Hou Xianghui,Li Kezhi.Numerical simulation of isothermal chemical vapor infiltration for axial symmetrical C/C composites[J].Journal of Northwestern Polytechnical University,2000,18(4):665-668.
[6] MoeneR,DekkerJ P,Makkee M,et al.Evalution of isothermal chemical vapor infiltration with Langmuirhinshelwood type kinetics[J].J Electrochem Soc,1994,141(1):282-290.
[7] Kim J,Lee W I.A study on the modeling of carbon/carbon composite pyrolysis process[J].J Korean Soc Composite Mater,1998,11(1):47-54.
[8] Kim J,Lee W I,Khalid Lafdi.Numerical modeling of the carbonization process manufacture of carbon/carbon composites[J].Carbon,2003,41:2625-2634.
[9] Dimitrienko Y I.Modeling of carbon/carbon composite manufacturing process[J].Composites Part A:Applied Science and Manufacturing,1999,30:221-230.
[10] Dimitrienko Y I.Thermal stresses and heat-mass-transfer in ablating composite materials[J].Int J Heat Mass Transfer,1995,38(1):139-146.
[11] LiangJ,Yang W,Wang B L,Du S Y.Modeling of manufacturing processes of carbon matrices composites and prediction of mechanical properties of materials during the process[C]//Kim J K,Wo D Z,Zhou L M.Advances in Composite Materials and Structures.Switzerland:Trans Tech Publications,2007:29-32.
[12] 唐绍锋,梁军,杜善义.含界面相的单向纤维增强复合材料三维应力场的二重双尺度方法[J].复合材料学报,2010,27(1):167-172.Tang Shaofeng,Liang Jun,Du Shanyi.Dual two-scale method for 3D stress computation of unidirectional-fibre reinforced composites considering interphase[J].Acta Materiae Compositae Sinica,2010,27(1):167-172.
[13] Craig W O,Wallace L V,Philip O R,Hwa-Tsu T.Thermal conductivity database of various structural carbon-carbon composite materials,NASA Technical Memorandum 4787[R].Virginia:Langley Research Center· Hampton,1997.
[14] 付东升,张康助,孙福林,姚冬梅.碳/碳复合材料的基体前驱体研究进展[J].化工新型材料,2003,31(6):19-22.Fu Dongsheng,Zhang Kangzhu,Sun Fulin,Yao Dongmei.Research progress in matrix precursors for carbon/carbon composites[J].New Chemical Materials,2003,31(6):19-22.
[15] 梁军,易法军.防热材料高温烧蚀--相变特性的细观研究[J].复合材料学报,2002,19(2):108-112.Liang Jun,Yi Fajun.On ablation and phase-Transformation properties of thermal protective materials at high temperature by micromechanics[J].Acta Materiae Compositae Sinica,2002,19(2):108-112.
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