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现代钢铁联合企业的高炉转炉流程是铁煤化工过程,针对该流程中烧结工序排放含二氧化硫烟气的特点,采用软锰矿、菱锰矿脱硫制取硫酸锰。采用菱锰矿调节和控制矿浆的pH值,利用软锰矿中MnO2的氧化性和SO2的还原性,用软锰矿矿浆在填料吸收塔内进行脱硫试验。试验结果表明:二氧化硫的吸收率在95%以上,该工艺还具有湿法除尘的特性,对烟尘的吸收率达90%以上,且副产品硫酸锰的质量能达到工业级,是一种真正实现“综合治理、变废为宝”的脱硫新技术。

The BFconverter route of steelmaking is a chemical process of iron and coal. Sulfur dioxide is released in sintering process which can be absorbed by pyrolusite and mild manganese to produce manganese sulfate. The experiments of removal of SO2 with pyrolusite and mild manganese were performed, and the pH scale of pulp was controlled; utilizing the oxidability of MnO2 and reducibility of SO2, the pyrolusite pulp was put into the absorption tower of padding. The above90% absorptivity of flue dust indicated that wet dust collection was available to this technique, in which the absorptivity of SO2 was above 95%, and the byproduct technical grade manganese sulfate was produced. The technique is proved to be a new technology on:removal of SO2, for waste treatment.

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