碳酸钙粉热分解产生的CO2对高碳锰铁粉固相脱碳具有很好的脱碳作用,但脱碳过程中物料电磁性能的变化对微波加热的影响很大。将高碳锰铁粉与碳酸钙粉按质量比1∶1均匀混合,在微波场中加热进行固相脱碳反应,脱碳温度分别为900、1 000、1 100、1 200℃,且各保温脱碳60min。用矢量网络分析法测试试样的电磁性能。结果表明,高碳锰铁粉脱碳前后的电磁性能变化很大。脱碳物料的εr′在7.00~10.00范围内,εr″≈0.05。脱碳物料的μr′≈1.00,μr″≈0.00。温度为900和1 200℃时,脱碳物料的电磁性能相近。高碳锰铁粉加热到1 000和1 100℃时,脱碳物料的tanδε和tanδμ最大,微波加热效果良好。
CO2 formed calcium carbonate powders by thermal decomposition had a good effect of decarbonization.The powders of high-carbon ferromanganese and calcium carbonate,were uniformly mixed with the mole ratio(Mass ratio of high-carbon ferromanganese and CO2 was equal to 1),and were heated respectively at 900,1 000,1 100,1 200 ℃ for 60 min in microwave field.Vector network analyzer was used to analyze the electromagnetic properties.The results show that the change of the electromagnetic properties of high carbon ferromanganese powders is apparent before and after the decarburization.The range of εr′ of decarburized high carbon ferromanganese powders is about 7.00-10.00,and εr″≈0.05.The μr′ of decarburized high carbon ferromanganese powders is about 1.00,and μr″≈0.00.The electromagnetic properties of decarburized high carbon ferromanganese powders are similar at 900 and 1 200 ℃.The decarburized high carbon ferromanganese powders with the largest tanδε and tanδμ have better dielectric and magnetic properties,when it is heated in microwave field at 1 000 and 1 100 ℃.
参考文献
[1] | 陈津,潘小娟,王社斌,林原生.锰矿粉利用技术研究[J].铁合金,2007(05):7-12. |
[2] | Thostenson E T;Chou T W .Microwave Processing:Funda- mental and Applications[J].Composites,1999,Part A(30):1055. |
[3] | 周克省,黄可龙,孔德明,李志光.吸波材料的物理机制及其设计[J].中南工业大学学报(自然科学版),2001(06):617-621. |
[4] | 邓秀文.吸波材料研究进展[J].化工时刊,2007(08):58-65. |
[5] | 谢炜,程海峰,楚增勇,陈朝辉.短切中空多孔碳纤维复合材料的吸波性能[J].无机材料学报,2008(03):481-485. |
[6] | Terada, Masao;Itoh, Masahiro;Liu, Jiu Rong;Machida, Ken-ichi .Electromagnetic wave absorption properties of Fe3C/carbon nanocomposites prepared by a CVD method[J].Journal of Magnetism and Magnetic Materials,2009(9):1209-1213. |
[7] | 童国秀,华桥,吴文华,秦明月,李良超,宫培军.液固比对铁粒子形貌、结构、电导率和微波电磁特性的影响[J].中国科学(技术科学),2011(02):239-244. |
[8] | FANG Zhi gang;LI Chu-sen;SUN Jia-yan et al.The Elec tromagnetic Characteristics of Carbon Foams[J].Carbon,2007,45:2873. |
[9] | 廖宇涛,张兴华.多壁碳纳米管电磁参数的研究和吸波性能模拟[J].材料导报,2006(03):138-140. |
[10] | 托鲁基安.岩石与矿物的物理性质[M].北京:石油工业出版社,1990 |
[11] | 冯秀梅,陈津,刘金营.微波场中冶金用石灰电磁性质的研究[J].中国矿业,2006(10):95-97. |
[12] | 赵璐 .碳纤维粉表面化学镀及其电磁性能的研究[D].北京交通大学,2008. |
[13] | 阎守胜.固体物理基础[M].北京:北京大学出版社,2000 |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%