基于溶胶-凝胶原理的有机硅橡胶原位增强新方法有效地解决了填料在聚合物基体中的分散和团聚问题,可得到具有更好机械性能和耐热性能的有机硅材料.根据填料性质的不同,详细介绍了各种原位增强方法、增强机理及表征手段,比较了25°C时未增强及不同浓度填料原位增强聚合物材料的应力-应变等温线,并简要描述了原位增强工艺的前景.
参考文献
| [1] | Q. Wendy Yuan;James E. Mark .Reinforcement of poly(dimethylsiloxane) networks by blended and in-situ generated silica fillers having various sizes, size distributions, and modified surfaces[J].Macromolecular chemistry and physics,1999(1):206-220. |
| [2] | Sohoni G B;Mark J E .Thermal stability of in situ filled siloxane elastomers[J].Journal of Applied Polymer Scinece,1992,45(10):1763. |
| [3] | Mark J E;Pan S J .Reinforcement of polydimethylsiloxane networks by in-situ precipitation of silica:A new method for preparation of filled elastomers[J].MAKROMOLEKULARE CHEMIE-RAPID COMMUNICATIONS,1982,3:681. |
| [4] | Mark J E;Pan S J .Reinforcement of poly(dimethylsiloxane)networks by in-situ precipitation of silica:a new method for preparing filled elastomers[J].Polym Preprints(American Chemical Society Division of Polymer Chemistry),1982,23(02):191. |
| [5] | 姜承永 .硅橡胶就地填充补强的新方法[J].合成橡胶工业,1991,14(02):140. |
| [6] | Jiang C Y;Mark J E .The effect of relative humidity on the hydrolytic precipitation of silica into an elastomeric network[J].Colloid and Polymer Science,1984,262:758. |
| [7] | Ning Y P;RIGBI Z;Mark J E .H:ydrolysis of several ethylethoxysilanes to yield deformable filler particles[J].Polymer Bulletin,1985,13:153. |
| [8] | Sur G S;Mark J E .Comparisons among dome tetra-alkoxysilanes in the hydrolytic precipitation of silica into elastomeric networks[J].Makromolekulare Chemie,1986,187:2861. |
| [9] | Mark J E;Jiang C Y;Tang M Y .Simultaneous curingand filling of elastomers[J].Macromolecules,1984,17:2613. |
| [10] | Tang M Y;Mark J E .Elastomeric properties of bimodal networks prepared by a simultaneous curing-filling technique[J].Polymer Engineering & Science,1985,25(01):29. |
| [11] | Mark J E;Sur G S .Reinforcing effects from silica-type fillers containing hydrocarbon groups[J].Polymer Bulletin,1985,14:325. |
| [12] | Ning Y P;Mark J E .Treatment of filler-reinforced silicone elastomers to maximize increases in ultimate strength[J].Polym Bull(Berlin Germany),1984,12(05):407. |
| [13] | BREINER J.M.;MARK J.E.;BEAUCAGE G. .Dependence of Silica Particle Sizes on Network Chain Lengths, Silica Contents, and Catalyst Concentrations in In Situ-Reinforced Polysiloxane Elastomers[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(13):1421-1427. |
| [14] | Wang S B;Mark J E .In-situ precipitation of reinforcing titania fillers[J].Polym Bull(Berlin Germany),1987,17(03):271. |
| [15] | Clarson S J;Mark J E .Reinforcement of elastomeric poly (methylphenylsiloxane)by the in-situ precipitation of titania[J].Polym Commu,1989,30(09):275. |
| [16] | Suresh Murugesan;James E. Mark;Gregory Beaucage .Structure-property relationships for poly(dimethylsiloxane) networks in-situ filled using titanium 2-ethylhexoxide and zirconium N-butoxide[J].Polymer Preprints,2001(1):188-189. |
| [17] | Clarson S J;Mccarthy D W;Mark J E .Reinforcement of poly(methylphenylsnoxane)elastomers by the in-situ precipitation of silica and titania[J].Polym Preprints(American Chemical Society Division of Polymer Chemistry),1989,30(01):298. |
| [18] | Wang Shuhong;Mark J E .Reinforcement of elastomeric poly(dimethylsiloxane)by glassy poly(diphenylsiloxane)[J].Journal of Materials Science,1990,25(1A):65. |
| [19] | Burnside;Shelly D;Giannelis et al.Synthesis andproperties of new poly(dimethylsiloxane)nanocomposites[J].Chemistry of Materials,1995,7(09):1597. |
| [20] | Ning Y P;Mark J E .Precipitation of reinforcing filler into polydimethylsiloxane prior to its end linking into elastomeric networks[J].Journal of Applied Polymer Scinece,1985,30(08):3519. |
| [21] | Leezenberg;Pieter B;Frank et al.In situ precipitation of silica in dansyl-labeled poly(dimethylsiloxane)elastomers[J].Chemistry of Materials,1995,7(10):1784. |
| [22] | Dewimille L;Bresson B;Bokobza L .Synthesis, structure and morphology of poly (dimethylsiloxane) networks filled with in situ generated silica particles[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(12):4135-4143. |
| [23] | Chandima Kumudinie;James E. Mark .Tearing energies for in-situ reinforced poly(dimethylsiloxane) networks[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2000(1):61-66. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%