介绍了一种新型储氢材料--金属一有机框架物(Metal-organic framework,MOFs).该材料具有许多优异的性能,如密度小、比表面积大、气孔率高等,并可通过组装来控制框架物的结构和孔径的大小,是一种具有发展前景的新型储氢材料.在总结、评述MOFs储氯材料制备、表征、储氢性能及其影响因素等研究进展的基础上提出了今后的研究重点和发展方向.
参考文献
[1] | Wigley T M L;Richels R;Edmonds J A .Economic and environmental choices in the stabilization of atmospheric CO2 concentrations[J].Nature,1996,379:240. |
[2] | Sailor W C;Bodansky D;Braun C et al.A nuclear solution to climate change[J].Science,2000,288:1177. |
[3] | Turner J A .A realizable renewable energy future[J].Science,1999,285:687. |
[4] | Lee J Y;Pan L;Jagiello J et al.Achieving high density of adsorbed hydrogen in microporous metal organic frameworks[J].Advanced Materials,2005,17:2703. |
[5] | Rowsell J L C;Yaghi O M .Strategies for hydrogen storage in metal-organic frameworks[J].Angewandte Chemie International Edition,2005,44:4670. |
[6] | Milliken J.DOE storage program and targets/workshop expectations[A].Argonne:Argonne National Laboratory,2002 |
[7] | chemical & engineering news with annual index Group .New palladium oxidation state?[J].Chemical and engineering news: "news edition" of the American Chemical Society,2002(2):8-0. |
[8] | Froudakis GE. .Hydrogen interaction with carbon nanotubes: a review of ab initio studies [Review][J].Journal of Physics. Condensed Matter,2002(17):R453-R465. |
[9] | Loiseau T;Mnguerra H;Ferey G et al.Synthesis and structural characterization of a new open-framework zinc terephthalate Zn3 (OH)z (bdc)2@2DEF,with infinite Zn(μ3-OH)-Zn chains[J].Journal of Solid State Chemistry,2005,178:621. |
[10] | Chun H;Dybtsev D N;Kim H et al.Synthesis,X-ray crystal structures,and gas sorption properties of pillared square grid nets based on paddle-wheel motifs:Implications for hydrogen storage in porous materials[J].Chemistry-A European Journal,2005,11:3521. |
[11] | Rosi NL.;Eckert J.;Eddaoudi M.;Vodak DT.;Kim J.;O'Keeffe M.;Yaghi OM. .Hydrogen storage in microporous metal-organic frameworks[J].Science,2003(5622):1127-1129. |
[12] | Lee JY;Olson DH;Pan L;Emge TJ;Li J .Microporous metal-organic frameworks with high gas sorption and separation capacity[J].Advanced functional materials,2007(8):1255-1262. |
[13] | Sibefio-Pe'rez D Y;Wong-Foy A G;Yaghi O M et al.Raman Spectroscopic investigation of CH4 and N2 adsorption in metal-organic frameworks[J].Chemistry of Materials,2007,19:3681. |
[14] | Pawsey S;Moudrakovski I;Ripmeester J et al.Hyperpolarized 129Xe nuclear magnetic resonance studies of isoreticular metal-organic frameworks[J].Journal of Physical Chemistry C,2007,111:6060. |
[15] | El-Kaderi HM;Hunt JR;Mendoza-Cortes JL;Cote AP;Taylor RE;O'Keeffe M;Yaghi OM .Designed synthesis of 3D covalent organic frameworks.[J].Science,2007(5822):268-272. |
[16] | Chae HK;Siberio-Perez DY;Kim J;Go Y;Eddaoudi M;Matzger AJ .A route to high surface area, porosity and inclusion of large molecules in crystals[J].Nature,2004(6974):523-527. |
[17] | Eddaoudi M;Moler D B;Li H et al.Modular chemistry:Secondary building units as a basis for the design of highly porous and robust metal-organic carboxylate frameworks[J].Accounts of Chemical Research,2001,34:319. |
[18] | Pan L;Liu H M;Lei X G et al.A recyclable nanoporous material suitable for ship-in-bottle synthesis and large hydrocarbon sorption[J].Angewandte Chemie International Edition,2003,42:542. |
[19] | Uemura K.;Kitagawa S.;Kondo M.;Fukui K.;Kitaura R.;Chang HC. Mizutani T. .Novel flexible frameworks of porous cobalt(III) coordination polymers that show selective guest adsorption based on the switching of hydrogen-bond pairs of amide groups[J].Chemistry: A European journal,2002(16):3586-3600. |
[20] | Kamiyama A;Noguchi T;Kajiwara T et al.A graphitelike complex with large cavities constructed with the complex ligand[NiⅡ (bpca)2][J].Angewandte Chemie International Edition,2000,39:3130. |
[21] | Chen B L;Eddsoudi M;Hyde S T et al.Interwoven metalorganic framework on a periodic minimal surface with extralarge pores[J].Science,2001,29:1021. |
[22] | Wong-Foy A G;Matzger A J;Yaghi O M .Exceptional H2 saturation uptake in microporous metal-organic frameworks[J].JACS Commun,2006,128:3494. |
[23] | Park H;Britten JF;Mueller U;Lee J;Li J;Parise JB .Synthesis, structure determination, and hydrogen sorption studies of new metal-organic frameworks using triazole and naphthalenedicarboxylic acid[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(6):1302-1308. |
[24] | Li Y;Liu Y;Wang Y et al.Hydrogen storage properties of[M(Py) {Ni(CN)4}](M=Fe,Co,Ni)[J].International Journal of Hydrogen Energy,2007,32:3411. |
[25] | Hirscher M;Panella B .Hydrogen storage in metal-organic frameworks[J].Scripta Materialia,2007,56:809. |
[26] | Yaghi OM .A tale of two entanglements[J].Nature materials,2007(2):92-93. |
[27] | Chen B L;Ockwig N W;Millward A R et al.High H2 Adsorption in a microporous metal-organic framework with open metal sites[J].Angewandte Chemie International Edition,2005,44:4745. |
[28] | Clark A.The theory of adsorption and catalysis[M].New York:Academic Press,Inc,1970 |
[29] | Sagara T;Klassen J;Ortony J;Ganz E .Binding energies of hydrogen molecules to isoreticular metal-organic framework materials - art. no. 014701[J].The Journal of Chemical Physics,2005(1):14701-0. |
[30] | Hübner O;Gl(o)ss A;Fichtner M et al.On the interaction of dihydrogen with aromatic systems[J].Journal of Physical Chemistry A,2004,108:3019. |
[31] | Zhao X B;Xiao B;Fletcher A J et al.Hysteretic adsorption and desorption of hydrogen by nanoporous metal-organic frameworks[J].Science,2004,306:1012. |
[32] | Sudik A C;Wong-Foy A G;Yaghi O M .A metal-organic framework with a hierarchical system of pores and tetrahedral building blocks[J].Angewandte Chemie International Edition,2006,45:2528. |
[33] | Kaye S S;Dailly A;Yaghi O M et al.Impact of preparation and handling on the hydrogen storage properties of Zn40(1,4-benzenedicarboxylate)3 (MOF-5)[J].Journal of the American Chemical Society,2007,129:14176. |
[34] | Perles J;Iglesias M;Ruiz-Valero C et al.Metal-organic scandium framework.Useful material for hydrogen storage and catalysis[J].Chemistry of Materials,2005,17:5837. |
[35] | B'enard P;Chahine R;Chandonia P A et al.Comparison of hydrogen adsorption on nanoporous materials[J].Journal of Alloys and Compounds,2007,446-447:380. |
[36] | Skoulidas A I .Molecular dynamics simulations of gas diffusion in metal-organic frameworks:Argon in CuBTC[J].Journal of the American Chemical Society,2004,126:1356. |
[37] | Sagara T;Klassen J;Ganz E .Computational study of hydrogen binding by metal-organic framework-5[J].The Journal of Chemical Physics,2004(24):12543-12547. |
[38] | Frost H;Düuren T;Snurr R Q .Effects of surface area,free volume,and heat of adsorption on hydrogen uptake in metal-organic frameworks[J].Journal of Physical Chemistry B,2006,110:9565. |
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