以无机材料Fe3O4为模板,将在碳纳米管(CNT)功能化后,包裹在模板表面,然后再将苯胺单体接枝在CNT表面,之后采用化学氧化法,将接枝于CNT表面的苯胺单体聚合成聚苯胺(PANI),从而制备CNT/PANI空心球复合材料.用傅立叶变换红外光谱、扫描电子显微镜对复合材料进行成分和形貌的表征.用循环伏安法、恒流充放电和循环寿命等电化学测试手段来表征复合材料的电化学性能.研究结果表明所制备的复合材料比容量可达到185F/g(有机电解液),高于同样条件下所制备的纯PANI和采用一般方法所制备的CNT/PANI复合材料的电化学容量(65F/g,152F/g),显示出良好的应用前景.
参考文献
[1] | Prasad K R;Munichand N .[J].Journal of Power Sources,2002,112(02):443-451. |
[2] | Ying-ke Zhou;Ben-lin He;Wen-jia Zhou .Preparation and Electrochemistry of SWNT/PANI Composite Films for Electrochemical Capacitors[J].Journal of the Electrochemical Society,2004(7):A1052-A1057. |
[3] | Ying-ke Zhou;Ben-lin He;Wen-jia Zhou;Jier Huang;Xiao-hong Li;Bin Wu;Hu-lin Li .Electrochemical capacitance of well-coated single-walled carbon nanotube with polyaniline composites[J].Electrochimica Acta,2004(2):257-262. |
[4] | Dong H;Prasad S;Nyame V et al.[J].Chemistry of Materials,2004,16(03):371-373. |
[5] | Lijia Pan;Lin Pu;Yi Shi;Shiyan Song;Zhou Xu;Rong Zhang;Youdou Zheng .Synthesis of Poly aniline Nanotubes with a Reactive Template of Manganese Oxide[J].Advanced Materials,2007(3):461-464. |
[6] | 杨红生,周啸,张庆武.以多层次聚苯胺颗粒为电极活性物质的超级电容器的电化学性能[J].物理化学学报,2005(04):414-418. |
[7] | Yang Y;Chu Y;Yang FY;Zhang YP .Uniform hollow conductive polymer microspheres synthesized with the sulfonated polystyrene template[J].Materials Chemistry and Physics,2005(1):164-171. |
[8] | Iijima S .[J].Nature,1991,354(6348):56-58. |
[9] | Marc Monthioux;Valdimir L. Kuznetsov .Who should be given the credit for the discovery of carbon nanotubes?[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(9):1621-1623. |
[10] | 邓梅根,杨邦朝,胡永达,汪斌华.基于碳纳米管-聚苯胺纳米复合物的超级电容器研究[J].化学学报,2005(12):1127-1130. |
[11] | 米红宇;张校刚;黄建书 等.[J].功能材料,2007,38:1319-1322. |
[12] | 赵晓锋,江奇,郭亚楠,张楠,单长星,赵勇.有机化学合成法制备碳纳米管/聚苯胺复合材料[J].无机材料学报,2010(01):91-95. |
[13] | 江奇,卢晓英,赵勇,于作龙.碳纳米管微结构的改变对其容量性能的影响[J].物理化学学报,2004(05):546-549. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%