在医用镁合金功能化表面改性技术中,仿生钝化具有其他方法无可比拟的优越性.利用仿生钝化技术,可在镁合金表面原位制备兼具优异生物相容性、生物活性和降解控制功能的生物磷灰石膜层,全面满足镁合金生物医用对表面质量的苛刻要求.本文分别从前处理、钝化工艺、钝化后处理等方面,综述了医用镁合金仿生钝化技术的研究进展,并展望了医用镁合金仿生钝化技术的发展趋势.
参考文献
| [1] | 张佳,宗阳,付彭怀,袁广银,丁文江.镁合金在生物医用材料领域的应用及发展前景[J].中国组织工程研究与临床康复,2009(29):5747-5750. |
| [2] | 黄晶晶,任伊宾,张炳春,杨柯.镁及镁合金的生物相容性研究[J].稀有金属材料与工程,2007(06):1102-1105. |
| [3] | 张永君,严川伟,王福会,曹楚南.镁的应用及其腐蚀与防护[J].材料保护,2002(04):4-6. |
| [4] | 付涛,徐可为.仿生法沉积磷灰石层的研究进展[J].生物医学工程学杂志,2001(01):116-118. |
| [5] | 崔忠波,陈民芳.医用金属材料表面仿生处理研究进展[J].天津理工大学学报,2006(02):18-22. |
| [6] | Ibasco S;Tamimi F;Meszaros R .Magnesium-sputtered titanium for the formation of bioactive coatings.[J].Acta biomaterialia,2009(6):2338-2347. |
| [7] | BARREREA F;BLITTERSWIJK C A V;GROOT K D et al.Nucleation of biomimetic Ca-P coatings on Ti6Al4V from a SBF×5 solution:influence of magnesium[J].Biomaterials,2002,23(10):2211-2220. |
| [8] | Masanari Tomozawa;Sachiko Hiromoto .Microstructure of hydroxyapatite- and octacalcium phosphate-coatings formed on magnesium by a hydrothermal treatment at various pH values[J].Acta materialia,2011(1):355-363. |
| [9] | 夏琦兴,姚忠平,张亚军,李梁梁,姜兆华.镁合金微弧氧化陶瓷膜的组织结构及耐腐蚀性能[J].材料保护,2011(05):14-16. |
| [10] | Wang HX;Guan SK;Wang X;Ren CX;Wang LG .In vitro degradation and mechanical integrity of Mg-Zn-Ca alloy coated with Ca-deficient hydroxyapatite by the pulse electrodeposition process.[J].Acta biomaterialia,2010(5):1743-1748. |
| [11] | Kweh SW;Khor KA;Cheang P .An in vitro investigation of plasma sprayed hydroxyapatite (HA) coatings produced with flame-spheroidized feedstock.[J].Biomaterials,2002(3):775-785. |
| [12] | A. Rabiei;B. Thomas;B. Neville;J.W. Lee;J. Cuomo .A novel technique for processing functionally graded HA coatings[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2007(3):523-528. |
| [13] | Guochao Qi;Sam Zhang;K.A. Khor;Chunming Liu;Xianting Zeng;Wenjian Weng;Min Qian .In vitro effect of magnesium inclusion in sol-gel derived apatite[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2008(16):5176-5180. |
| [14] | 刘通,张永君.医用镁合金降解控制技术的研究进展[J].材料导报,2010(21):86-89,100. |
| [15] | 李龙川 .纯镁表面改性与生物相容性的研究[D].重庆大学,2004. |
| [16] | 付永昌,刘强,柳清菊.基于生物矿化的仿生合成技术及其应用[J].材料导报,2008(z3):272-275. |
| [17] | 郭洁 .通过仿生法在医用镁合金表面制备羟基磷灰石涂层的研究[D].武汉理工大学,2009. |
| [18] | 宋云京,李木森,温树林.仿生法制备生物陶瓷涂层的最新研究进展[J].材料导报,2002(05):33-35. |
| [19] | Gu XN;Zheng W;Cheng Y .A study on alkaline heat treated Mg-Ca alloy for the control of the biocorrosion rate.[J].Acta biomaterialia,2009(7):2790-2799. |
| [20] | TAN L L;WANG Q;GENG F et al.Preparation and characterization of Ca-P coating on AZ31 magnesium alloy[J].Transactions of Nonferrous Metals Society of China,2010,20(02):s648-s654. |
| [21] | 龚沛 .通过仿生法在纯镁表面制备磷灰石涂层的研究[D].武汉理工大学,2008. |
| [22] | Xu L;Pan F;Yu G;Yang L;Zhang E;Yang K .In vitro and in vivo evaluation of the surface bioactivity of a calcium phosphate coated magnesium alloy.[J].Biomaterials,2009(8):1512-1523. |
| [23] | HU J;WANG C;REN W C et al.Microstructure evolution and corrosion mechanism of dicalcium phosphate dihydrate coating on magnesium alloy in simulated body fluid[J].Materials Chemistry and Physics,2010,119(1/2):294-298. |
| [24] | LIU G Y;HU J;DING Z K et al.Bioactive calcium phosphate coating formed on micro-arc oxidized magnesium by chemical deposition[J].Applied Surface Science,2011,257(06):2051-2057. |
| [25] | 郭洁,王欣宇,唐舟,朱伟.通过仿生法在镁合金表面制备羟基磷灰石涂层的研究[J].现代生物医学进展,2009(12):2267-2269. |
| [26] | Sachiko Hiromoto;Akiko Yamamoto .High corrosion resistance of magnesium coated with hydroxyapatite directly synthesized in an aqueous solution[J].Electrochimica Acta,2009(27):7085-7093. |
| [27] | Kokubo T;Takadama H .How useful is SBF in predicting in vivo bone bioactivity?[J].Biomaterials,2006(15):2907-2915. |
| [28] | Lorenz C;Brunner JG;Kollmannsberger P .Effect of surface pre-treatments on biocompatibility of magnesium.[J].Acta biomaterialia,2009(7):2783-2789. |
| [29] | 龚沛,王欣宇,郭洁.通过仿生法在纯镁表面制备羟基磷灰石涂层的研究[J].化工中间体,2008(03):17-20. |
| [30] | Satish S. Singh;Abhijit Roy;Boeun Lee .Aqueous deposition of calcium phosphates and silicate substituted calcium phosphates on magnesium alloys[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2011(20):1695-1702. |
| [31] | Stulajterova R;Medvecky L .Effect of calcium ions on transformation brushite to hydroxyapatite in aqueous solutions[J].Colloids and Surfaces, A. Physicochemical and Engineering Aspects,2008(1/3):104-109. |
| [32] | Masanari Tomozawa;Sachiko Hiromoto .Growth mechanism of hydroxyapatite-coatings formed on pure magnesium and corrosion behavior of the coated magnesium[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2011(19):8253-8257. |
| [33] | Tomozawa, M.;Hiromoto, S.;Harada, Y. .Microstructure of hydroxyapatite-coated magnesium prepared in aqueous solution[J].Surface & Coatings Technology,2010(20):3243-3247. |
| [34] | X.-B. Chen;N. Birbilis;T.B. Abbott .A simple route towards a hydroxyapatite-Mg(OH)_2 conversion coating for magnesium[J].Corrosion Science: The Journal on Environmental Degradation of Materials and its Control,2011(6):2263-2268. |
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