以RuCl3·2H2O水溶液为电沉积液,通过恒流电沉积法在钽箔上电沉积一层RuO2·nH2O薄膜;研究了电沉积液初始pH值对制备RuO2·nH2O薄膜的影响.分别采用SEM、EDS、XRD、粒度分析仪(DELSA 440SX analyzer control)对薄膜的形貌、薄膜元素、溶胶的Zeta电位及薄膜的物相进行观察与测试.结果表明,电沉积液初始pH值越高,RuO2·nH2O薄膜越疏松,龟裂纹越大,与基体结合力也越差.初始pH值为2.3时,薄膜的孔隙率最佳,综合性能指标最好.
参考文献
| [1] | Huang YS.;Liao PC. .Preparation and characterization of RuO2 thin films[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1998(1/2):179-197. |
| [2] | Krusin-Elbaum L .Effects of oxygen on the electrical transport in RuO2[J].Thin Solid Films,1989,169(01):17. |
| [3] | Krusin-Elbaum L;Wittmer M .Conducting transition metal oxides:possibilities for RuO2 in VLSI metallization[J].Journal of the Electrochemical Society,1988,135(10):2610. |
| [4] | Kuhn A T;Mortimer C J .Kinetics of chlorine evolution and reduction on titanium supported metal oxidesespecially RuO2 and IrO2[J].Journal of the Electrochemical Society,1973,120(02):231. |
| [5] | Stilwell D E;Park S M .Electrochemistry of conductive polymers(Ⅱ)Electrochem studies on growth properties of polyaniline[J].Journal of Electrochemical Society,1988,135(09):2254. |
| [6] | Zheng JP.;Jow TR.;Cygan PJ. .HYDROUS RUTHENIUM OXIDE AS AN ELECTRODE MATERIAL FOR ELECTROCHEMICAL CAPACITORS[J].Journal of the Electrochemical Society,1995(8):2699-2703. |
| [7] | Lokhande C D;Park H S;Jung K D et al.Electrodeposited ruthenium oxide (RuO2) films for electrochemical supecapacitors[J].Journal of Materials Science,2004,39(13):4313. |
| [8] | Zhitomirsky I .Cathodic electrosynthesis of titanium and ruthenium oxides[J].Materials Letters,1998,33(01):305. |
| [9] | 张琦,郑明森,朱亚薇,董全峰,金明钢,詹亚丁,林祖赓.超级电容器电极材料纳米α-MnO2的制备及性能[J].电池,2005(06):437-439. |
| [10] | Chi-Chang Hu;Kwang-Huei Chang.Cyclic voltammetric deposition-of hydrousruthenium oxide forelectrochemical supercapacitors:effects of the chloridepre-cursor transformation[J].Journal of Power Sources,2002(112):401. |
| [11] | Hu C C;Huang Y H;Chang K H .Annealing effects on the physicochemical characteristics of hydrous ruthenium and ruthenium-iridium oxides for electrochemical supercapacitors[J].Journal of Power Sources,2002,108(01):117. |
| [12] | Park B O;Lokhande C D;Park H S et al.Performance of supercapacitor with electrodeposited ruthenium oxide film electrodes-effect of film thickness[J].Journal of Power Sources,2004,134(07):148. |
| [13] | Zheng J P;Xin Y .Characterization of RuO2 @ xH2O with various water contents[J].Journal of Power Sources,2002,110(07):86. |
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