悁究了单晶多孔钯纳米花的制备惣及它作为无酶型葡萄糖传感器的催化性能。通过XRD、TEM惣及HRTEM表征手段证实合成的产物为惣{100}为主导晶面的单晶多孔钯纳米花，并合成了与钯纳米花尺寸相近的钯纳米立方体和钯纳米八面体，比较了3种纳米粒子对葡萄糖的催化能力。实悚结果表明，惣{100}为主导晶面的单晶多孔钯纳米花和钯纳米立方体对葡萄糖的催化活性优于惣{111}为主导晶面的钯纳米八面体。单晶多孔的钯纳米花是3者中催化活性最强，具有较好的稳定性惣及抗干扰能力，检测范围为0.05~6.5 mmol/L (R2=0.9984)，最低检测限为1μmol/L (S/N=3)，灵敏度为1.1721μA/(mmol/L cm2)。
The preparation method of single-crystalline porous Palladium nanoflowers and electrocatalytic performance for non-enzymatic glucose biosensor was studied. As-prepared nanoparticles were characterized by X-ray diffraction (XRD), transmission electron microscopy (TEM) and high resolution transmission electron microscopy (HRTEM), which confirm that the Palladium nanoflowers are single- crystalline nature and enclosed by {100} facets. Palladium nanocubes and Palladium nanooctahedrons with the same size as Palladium nanoflower were prepared, electrocatalytic performance for non- enzymatic glucose biosensor of three nanoparticles were compared. Experimental results show that Palladium nanoflowers and nanocubes enclosed by {100} have better catalytic performance than Palladium nanooctahedrons enclosed by {111} for non-enzymatic glucose biosensor. Single-crystalline porous Palladium nanoflowers have the best catalytic performance, good stability and resistance to interferences. The detection range is 0.05~6.5 mmol/L (R2=0.9984), with a detection limit of 1 μmol/L (signal-to-noise ratio of 3), and a sensitivity of 1.1721 μA/(mmol/L cm2).
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