The interaction parameters for various phases in the Ti-W and Pd-W systems were calcula- ted using phase diagram information by means of a numerical procedure.The approach differs significantly from the trial and error method and has the advantage of being very robust in the sense that one can make full use of the accurate experimental phase diagram data and deal with situations which are difficult or even impossible for the trial and error method. Using calculated parameters and lattice stability values for Ti,W and Pd given in literature, the diagrams of the above systems were recalcula- ted.The results are in good agreement with experimental information.
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