热解镀铂工艺增强对电极的性能

稀有金属材料与工程, 2013, 42(6): 1130-1133.

热解镀铂工艺增强对电极的性能

辛钢 ^1, , 吴丽琼 ^2, , 黄晓飞 ^3, , 温斌 ^4, , 马廷丽 ^5,

1.大连理工大学精细化工国家重点实验室,辽宁大连116024

2.大连理工大学精细化工国家重点实验室,辽宁大连116024

3.大连理工大学精细化工国家重点实验室,辽宁大连116024

4.燕山大学亚稳材料科学与技术国家重点实验室,河北秦皇岛066004

5.大连理工大学精细化工国家重点实验室,辽宁大连116024

基金项目: National Natural Science Foundation of China(50773008) the Scientific Research Foundation for the Returned Overseas Chinese Scholars,State Education Ministry the Fundamental Research Founds for the Central Universities(DUT10LK30)

关键词：镀铂对电极 , 热分解 , 喷涂 , 印刷法 , 染料敏化太阳能电池

Effect of Enhanced Pyrolysis Platinized Processes on the Performance of Counter Electrodes

Xin Gang ^1, , Wu Liqiong ^2, , Huang Xiaofei ^3, , Wen Bin ^4, , Ma Tingli ^5,

1.大连理工大学精细化工国家重点实验室,辽宁大连116024

2.大连理工大学精细化工国家重点实验室,辽宁大连116024

3.大连理工大学精细化工国家重点实验室,辽宁大连116024

4.燕山大学亚稳材料科学与技术国家重点实验室,河北秦皇岛066004

5.大连理工大学精细化工国家重点实验室,辽宁大连116024

Keywords： platinized counter electrode , pyrolysis , spray , screen-printing , dye-sensitized cell (DSSC)

研究了热解法制备的铂电极,并获得最优制备工艺.结果表明:采用优化工艺热解法制备的铂对电极具有高的光伏效率,其光伏效率与溅射法制备的铂电极接近,该方法有可能实现低成本制备大面积高性能的铂对电极.

参考文献

[1]	O'Regan B;Gr(a)tzel M .[J].Nature,1991,353:737.
[2]	Desilvestro J;Gr(a)tzel M;Kavan L .[J].American Chemical Society,1985,107:2988.
[3]	Gr(a)tzel M .[J].Nature,2001,414:338.
[4]	Gr(a)tzel M;Photovolt Prog .[J].ResApply,2000,8:171.
[5]	Barbe C J;Arendse F;Comte P et al.[J].American Chemical Society,1997,80:3157.
[6]	Wang P;Zakeeruddin M;Comte P et al.[J].American Chemical Society,2003,125:1166.
[7]	Papageorgiou N.;Gratzel M.;Maier WF. .AN IODINE/TRIIODIDE REDUCTION ELECTROCATALYST FOR AQUEOUS AND ORGANIC MEDIA[J].Journal of the Electrochemical Society,1997(3):876-884.
[8]	HauchA;GeorgeA .[J].Electrochimica Acta,2001,46:3457.
[9]	Gr(a)tzel M;Photochem J .[J].PhotobiolA Chem,2004,164:3.
[10]	Nazeeruddin Md K;Angelis F D;Fantacci S et al.[J].American Chemical Society,2005,127:16837.
[11]	Kay A.;Gratzel M. .LOW COST PHOTOVOLTAIC MODULES BASED ON DYE SENSITIZED NANOCRYSTALLINE TITANIUM DIOXIDE AND CARBON POWDER[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,1996(1):99-117.
[12]	Imoto K.;Takahashi K.;Yamaguchi T.;Komura T.;Nakamura J.;Murata K. .High-performance carbon counter electrode for dye-sensitized solar cells[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2003(4):459-469.
[13]	Saito Y;Kubo W;Kitamura T et al.[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,164:153.
[14]	Ma T;Fang X;Akiyama M et al.[J].Electronal Chem,2004,574:77.
[15]	Fang X;Ma T;Akiyama M et al.[J].Thin Solid Films,2005,472:242.
[16]	Fang X;Ma T;Guan G et al.[J].Journal of Photochemistry and Photobiology A:Chemistry,2004,164:179.
[17]	Fang X;Ma T;Guan G et al.[J].Electronal Chem,2004,570:57.
[18]	Ma T;Kida T;Akiyama M et al.[J].Electrochemistry Communications,2003,5:369.
[19]	Lan J L;Wang Y Y;Wana C C et al.[J].Current Applied Physics,2010,10:S168.
[20]	Quinones C;Vallejo W;Mesa F .[J].Appl SurfSci,2011,257:7545.
[21]	Ito S;Ha NLC;Rothenberger G;Liska P;Comte P;Zakeeruddin SM;Pechy P;Nazeeruddin MK;Gratzel M .High-efficiency (7.2%) flexible dye-sensitized solar cells with Ti-metal substrate for nanocrystalline-TiO2 photoanode[J].Chemical communications,2006(38):4004-4006.
[22]	Wei T C;Wan C C;Wang Y Y et al.[J].Applied Physics Letters,2006,88:103122.
[23]	Halme J;Toivola M;Tolvanen A;Lund P .Charge transfer resistance of spray deposited and compressed counter electrodes for dye-sensitized nanoparticle solar cells on plastic substrates[J].Solar Energy Materials and Solar Cells: An International Journal Devoted to Photovoltaic, Photothermal, and Photochemical Solar Energy Conversion,2006(7/8):872-886.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网