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富锂锰基正极材料xLi2 MnO3·(1-x)LiMO2具有高比容量(200~300mAh/g),能很好地满足锂电池在小型电子产品和电动汽车等领域的使用要求,是最具潜力的下一代动力锂离子电池正极材料.介绍了富锂锰基正极材料xLi2MnO3·(1-x)LiMO2的结构特征及其充放电机理;总结了这类材料的合成方法以及改性方法;揭示了该材料的研究现状和亟待解决的问题;并展望了其今后的发展方向.

参考文献

[1] Bruno Scrosati;Jusef Hassoun;Yang-Kook Sun .Lithium-ion batteries. A look into the future[J].Energy & environmental science: EES,2011(9):3287-3295.
[2] Jeffrey W. Fergus .Recent developments in cathode materials for lithium ion batteries[J].Journal of Power Sources,2010(4):939.
[3] Belov, D;Yang, MH .Investigation of the kinetic mechanism in overcharge process for Li-ion battery[J].Solid state ionics,2008(27/32):1816-1821.
[4] Titipun Thongtem;Somchai Thongtem .Characterization of Li_(1-x)Ni_(1+x)O_2 Prepared Using Succinic Acid as a Complexing Agent[J].Inorganic materials,2006(2):202-209.
[5] Yunjian Liu;Xinhai Li;Huajun Guo;Zhixing Wang;Qiyang Hu;Wenjie Peng;Yong Yang .Electrochemical performance and capacity fading reason of LiMn_2O_4/graphite batteries stored at room temperature[J].Journal of Power Sources,2009(1):721-725.
[6] M.Stanley Whittingham .Lithium Batteries and Cathode Materials[J].Chemical Reviews,2004(10):4271-4301.
[7] Michael M. Thackeray;Sun-Ho Rang;Christopher S. Johnson .Li2MnO3-stabilized LiMO2 (M = Mn, Ni, Co) electrodes for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(30):3112-3125.
[8] Johnson CS;Li NC;Lefief C;Thackeray MM .Anomalous capacity and cycling stability of xLi(2)MnO(3)center dot(1-x)LiMO2 electrodes (M = Mn, Ni, Co) in lithium batteries at 50 degrees C[J].Electrochemistry communications,2007(4):787-795.
[9] Thackeray MM;Johnson CS;Vaughey JT;Li N;Hackney SA .Advances in manganese-oxide 'composite' electrodes for lithium-ion batteries[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2005(23):2257-2267.
[10] Lu ZH.;Chen ZH.;Dahn JR. .Lack of cation clustering in Li[NixLi1/3-2x/3Mn2/3-x/3]O-2 (0 < x <= 1/2) and Li[CrxLi(1-x)/3Mn(2-2x)/3]O-2 (0 < x < 1)[J].Chemistry of Materials,2003(16):3214-3220.
[11] Kim J S;Johnson C S;Vaughey J T et al.Electrochemical and structural properties of xLi2M' O3 · (1-x) LiMn0.5-Ni0.5O2 electrodes for lithium batteries (M=Ti,Mn,Zr;0《x≤0.3)[J].Chemistry of Materials,2004,16(10):1996.
[12] M. Balasubramanian;J. McBreen;I. J. Davidson .In Situ X-Ray Absorption Study of a Layered Manganese-Chromium Oxide-Based Cathode Material[J].Journal of the Electrochemical Society,2002(2):A176-A184.
[13] Pan CJ.;Lee YJ.;Ammundsen B.;Grey CP. .Li-6 MAS NMR studies of the local structure and electrochemical properties of Cr-doped lithium manganese and lithium cobalt oxide cathode materials for lithium-ion batteries[J].Chemistry of Materials,2002(5):2289-2299.
[14] W.C. West;R.J. Staniewicz;C. Ma;J. Robak;J. Soler;M.C. Smart;B.V. Ratnakumar .Implications of the first cycle irreversible capacity on cell balancing for Li_2MnO_3-LiMO_2 (M = Ni, Mn, Co) Li-ion cathodes[J].Journal of Power Sources,2011(22):9696-9701.
[15] Alastair D. Robertson;Peter G. Bruce .The origin of electrochemical activity in Li_2MnO_3[J].Chemical communications,2002(23):2790-2791.
[16] Armstrong AR;Holzapfel M;Novak P;Johnson CS;Kang SH;Thackeray MM;Bruce PG .Demonstrating oxygen loss and associated structural reorganization in the lithium battery cathode Li[Ni0.2Li0.2Mn0.6]O-2[J].Journal of the American Chemical Society,2006(26):8694-8698.
[17] Robertson AD.;Bruce PG. .Mechanism of electrochemical activity in Li2MnO3[J].Chemistry of Materials,2003(10):1984-1992.
[18] J. Li;R. Kloepsch;M.C. Stan;S. Nowak;M. Kunze;M. Winter;S. Passerini .Synthesis and electrochemical performance of the high voltage cathode material Li[Li0.2Mn0.56Ni0.16Co0.08]O2 with improved rate capability[J].Journal of Power Sources,2011(10):4821-4825.
[19] Xiao-Jian Guo;Yi-Xiao Li;Min Zheng;Jian-Ming Zheng;Jie Li;Zheng-Liang Gong;Yong Yang .Structural And Electrochemical Characterization Of xLi[Li_(1/3)Mn_(2/3)]O_2·(1-x)Li[Ni_(1/3)Mn_(1/3)Co_(1/3)]O_2 (0 <= x <= 0.9) As Cathode Materials For Lithium Ion Batteries[J].Journal of Power Sources,2008(2):414-419.
[20] Jae-Hwan Lim;Hyunjoo Bang;Ki-Soo Lee;K. Amine;Yang-Kook Sun .Electrochemical characterization of Li_2MnO_3-Li[Ni_(1/3)Co_(1/3)Mn_(1/3))O_2-LiNiO_2 cathode synthesized via co-precipitation for lithium secondary batteries[J].Journal of Power Sources,2009(1):571-575.
[21] D.-K. Lee;S.-H. Park;K. Amine .High capacity Li[Li_(0.2)Ni_(0.2)Mn_(0.6)]O_2 cathode materials via a carbonate co-precipitation method[J].Journal of Power Sources,2006(2):1346-1350.
[22] Dapeng Wang;Ilias Belharouak;Gary M. Koenig, Jr .Growth mechanism of Ni_(0.3)Mn_(0.7)CO3 precursor for high capacity Li-ion battery cathodes[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2011(25):9290-9295.
[23] Kim JH.;Park CW.;Sun YK. .Synthesis and electrochemical behavior of Li[Li0.1Ni0.35-x/2CoxMn0.55-x/2]O-2 cathode materials[J].Solid state ionics,2003(1/2):43-49.
[24] Karthikeyan K;Amaresh S;Iee G W et al.Electrochemical performance of cobalt free,Li1.2 (Mn0.32 Ni0.32 Fe0.16) O2 cathodes for lithium batteries[J].Electrochimica Acta,2012,68(30):246.
[25] Wu F;Lu H Q;Su Y F et al.Preparation and electrochemical performance of Li-rich layered cathode material,Li[Ni0.2Li0.2Mn0.6]O2,for lithium-ion batteries[J].Journal of Applied Electrochemistry,2010,40(04):783.
[26] Kang SH;Kempgens P;Greenbaum S;Kropf AJ;Amine K;Thackeray MM .Interpreting the structural and electrochemical complexity of 0.5Li(2)MnO(3)center dot 0.5LiMO(2) electrodes for lithium batteries (M = Mn0.5-xNi0.5-xCo2x, 0 <= x <= 0.5)[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2007(20):2069-2077.
[27] Tang Z H;Wang Z X;Li X H et al.Preparation and electrochemical properties of Co-doped and none-doped Li[LixMn0.6(1-x) Ni0.35(1-x)]O2 cathode materials for lithium battery batteries[J].Journal of Power Sources,2012,204(15):187.
[28] C. Madhu;Joshua Garrett;Venkatesan Manivannan .Synthesis and characterization of oxide cathode materials of the system (1-x-y)LiNiO2·xLi2MnO3·yLiCoO2[J].Ionics,2010(7):591-602.
[29] Yu L Y;Qiu W H;Lian F et al.Understanding the phenomenon of increasing capacity of layered 0.65Li[Li1/3-Mn2/3]O2 · 0.35Li (Ni1/3 Co1/3 Mn1/3) O2[J].Journal of Alloys and Compounds,2009,471(1-2):317.
[30] Xingkang Huang;Qingshun Zhang;Haitao Chang .Hydrothermal Synthesis of Nanosized LiMnO_2-Li_2MnO_3 Compounds and Their Electrochemical Performances[J].Journal of the Electrochemical Society,2009(3):A162-A168.
[31] Jaephil Cho;Yoojin Kim;Min Gyu Kim .Synthesis and Characterization of Li[Ni0.41Li0.08Mn0.51]O2 Nanoplates for Li Battery Cathode Material[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2007(7):3192-3196.
[32] He W;Qian J F;Cao Y L et al.Improved electrochemical performances of nanocrystalline Li[Li0.2 Mn0.54 Ni0.13 Co0.13]-O2 cathode material for Li-ion batteries[J].RSC Adv,2012,2(08):3423.
[33] Young Jun Hong;Jung Hyun Kim;Min Ho Kim;Yun Chan Kang .Electrochemical properties of 0.3Li_2MnO_3·0.7LiNi_(0.5)Mn_(0.5)O_2 composite cathode powders prepared by large-scale spray pyrolysis[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2012(8):2022-2026.
[34] Kim Y;Hong Y;Kim MG;Cho J .Li-0.93[Li0.21Co0.28Mn0.51]O-2 nanoparticles for lithium battery cathode material made by cationic exchange from K-birnessite[J].Electrochemistry communications,2007(5):1041-1046.
[35] Zheng, JM;Li, J;Zhang, ZR;Guo, XJ;Yang, Y .The effects of TiO2 coating on the electrochemical performance of Li[Li0.2Mn0.54Ni0.13CO0.13]O-2 cathode material for lithium-ion battery[J].Solid state ionics,2008(27/32):1794-1799.
[36] West W C;Soler J;Smart M C et al.Electrochemical behavior of layered solid solution Li2MnO3-LiMO2 (M =Ni,Mn,Co) Li-ion cathodes with and without alumina coatings[J].Journal of the Electrochemical Society,2011,158(08):A883.
[37] H. Deng;I. Belharouak;C. S. Yoon;Y.-K. Sun;K. Amine .High Temperature Performance of Surface-Treated Li_(1.1)Ni_(0.15)Co_(0.1)Mn_(0.55) O_(1.95) Layered Oxide[J].Journal of the Electrochemical Society,2010(10):A1035-A1039.
[38] Liu, J.;Wang, Q.;Reeja-Jayan, B.;Manthiram, A. .Carbon-coated high capacity layered Li[Li_(0.2)Mn _(0.54)Ni_(0.13)Co_(0.13)]O_2 cathodes[J].Electrochemistry communications,2010(6):750-753.
[39] Wu Y;Murugan A V;Manthiram A .Surface modification of high capacity layered Li[Li0.2 Mn0.54 Ni0.13 Co0.13]O2 cathodes by A1PO4[J].Journal of the Electrochemical Society,2008,155(09):A635.
[40] Q. Y. Wang;J. Liu;A. Vadivel Murugan .High capacity double-layer surface modified Li[Li_(0.2)Mn_(0.54)Ni_(0.13)Co_(0.13)]O2 cathode with improved rate capability[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2009(28):4965-4972.
[41] Jiao L F;Zhang M;Yuan H T et al.Effect of Cr doping on the structural,electrochemical properties of Li[Li0.2-Ni0.2-x/2Mn0.6-x/2Crx]Ox(x=0,0.02,0.04,0.06,0.08)as cathode materials for lithium secondary batteries[J].Journal of Power Sources,2007,167(01):178.
[42] Lian, F.;Gao, M.;Qiu, W.H.;Axmann, P.;Wohlfahrt-Mehrens, M. .Fe-doping effects on the structural and electrochemical properties of 0.5Li _2MnO _3?0.5LiMn _(0.5)Ni _(0.5)O _2 electrode material[J].Journal of Applied Electrochemistry,2012(6):409-417.
[43] Song B H;Lai M O;Lu L .Influence of Ru substitution on Li-rich 0.55Li2 MnO3 · 0.45LiNi1/3 Cov3 Mn1/3 O2 cathode for Li-ion batteries[J].Electrochimica Acta,2012,80(01):187.
[44] Park S H;Sun Y K .Synthesis and electrochemical properties of layered Li[Li0.15 Ni(0.275-x/2) Alx Mn(0.575-x/2)]O2 materials prepared by sol-gel method[J].Journal of Power Sources,2003,119-121(01):161.
[45] Denis Y. W. Yu;Katsunori Yanagida;Hiroshi Nakamura .Surface Modification of Li-Excess Mn-based Cathode Materials[J].Journal of the Electrochemical Society,2010(11):A1177-A1182.
[46] Johnson CS;Kim JS;Lefief C;Li N;Vaughey JT;Thackeray MM .The significance of the Li2MnO3 component in 'composite' xLi(2)MnO(3) center dot (1-x)LiMn0.5Ni0.5O2 electrodes[J].Electrochemistry communications,2004(10):1085-1091.
[47] Abouimrane, A.;Compton, O.C.;Deng, H.;Belharouak, I.;Dikin, D.A.;Nguyen, S.T.;Amine, K. .Improved rate capability in a high-capacity layered cathode material via thermal reduction[J].Electrochemical and solid-state letters,2011(9):A126-A129.
[48] Gallaghera K G;Kang S H;Park S U et al.xLi2MnO3 @(1-x) LiMO2 blended with LiFePO4 to achieve high energy density and pulse power capability[J].Journal of Power Sources,2011,196(22):9702.
[49] Gao J;Kim J;Manthiram A .High capacity Li[Li0.2Mn0.54Ni0.13Co0.13]O-2-V2O5 composite cathodes with low irreversible capacity loss for lithium ion batteries[J].Electrochemistry communications,2009(1):84-86.
[50] Gim J;Song J;Park H et al.Synthesis and characterization of integrated layered nanocomposites for lithium ion batteries[J].Nanoscale Res Lett,2012,7(01):60.
[51] Kim MG;Jo M;Hong YS;Cho J .Template-free synthesis of Li[Ni0.25Li0.15Mn0.6]O-2 nanowires for high performance lithium battery cathode[J].Chemical communications,2009(2):218-220.
[52] Wei G Z;Lu X;Ke F S et al.Crystal habit-tuned nanoplate material of Li[Li1/3-2x/3 NixMn2/3-x/3]O2 for high-rate performance lithium-ion batteries[J].Advanced Materials,2010,22(39):4364.
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