以导电聚合物作为电解质的塑料锂离子电池被认为是迄今锂电池发展最新水平,研制性能优良的聚合物电解质是生产该种锂离子电池的关键技术,因此对聚合物电解质的表征是必不可少的步骤.电导率、扩散系数、迁移数和电化学窗口是表征聚合物电解质的重要指标.文中介绍了塑料锂离子电池用聚合物电解质性能的表征方法,给出了交流阻抗、浓差极化、断电流、线性伏安扫描等实验方法,并对其作了分析和讨论.
参考文献
[1] | Munichandraiah N;Shukla A K;Scanlon L G et al.[J].Journal of Power Sources,1996,66:201-206. |
[2] | 岩久正裕;小山日升 .[J].工业材料(日本),1999,47(02):52-55. |
[3] | Murata K;Izuchi S;Yoshihisa Y .[J].Electrochimica Acta,2000,45:1501-1508. |
[4] | 明石宽之;世界孝二;生山清一 .[J].工业材料(日本),1999,47(02):56-59. |
[5] | 宫木义行 .フヲンシヌルケロワヤ[J].工业材料(日本),1999,47(02):60-64. |
[6] | Ferry A;Doeff D M;De Jonghe L C .[J].Journal of the Electrochemical Society,1998,145(05):1586-1592. |
[7] | Ma YP.;Fuller TF.;Doeff MM.;Dejonghe LC.;Newman J.;Doyle M. .THE MEASUREMENT OF A COMPLETE SET OF TRANSPORT PROPERTIES FOR A CONCENTRATED SOLID POLYMER ELECTROLYTE SOLUTION[J].Journal of the Electrochemical Society,1995(6):1859-1868. |
[8] | Doyle M.;Newman J. .ANALYSIS OF TRANSFERENCE NUMBER MEASUREMENTS BASED ON THE POTENTIOSTATIC POLARIZATION OF SOLID POLYMER ELECTROLYTES[J].Journal of the Electrochemical Society,1995(10):3465-3468. |
[9] | Sun H Y;Sohn H J;Yamanoto O et al.[J].Journal of the Electrochemical Society,1999,146(05):1672-1676. |
[10] | Christie L;Christie A M;Vincent C A .[J].Electrochimica Acta,1999,44:2909-2913. |
[11] | Doeff M M;Georen P;Qiao J et al.[J].Journal of the Electrochemical Society,1999,146(06):2024-2028. |
[12] | Hwang K S;Lee C W;Yoon T H et al.[J].Journal of Power Sources,1999,79:225-230. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%