LiFePO4以其价格低廉、稳定性好、循环性能好和无毒等优点,有望成为下一代锂离子电池的正极材料,但是LiFePO4电导率低和锂离子扩散系数小限制了它的实用化.碳包覆作为一种非常有效的导电改性方法,受到极大关注.在碳包覆中采用不同的碳源和不同的碳包覆方法,对LiFePO4的电化学性能影响不同.结合国内外的研究现状,综述了LiFePO4/C复合材料制备过程中不同碳源以及不同的碳包覆方法对其电化学性能影响的研究进展.
参考文献
[1] | Padhi AK.;Goodenough JB.;Nanjundaswamy KS. .PHOSPHO-OLIVINES AS POSITIVE-ELECTRODE MATERIALS FOR RECHARGEABLE LITHIUM BATTERIES[J].Journal of the Electrochemical Society,1997(4):1188-1194. |
[2] | Ravet N;Chouinard Y;Magnan J F et al.Electroactivity of natural and synthetic triphylite[J].Journal of Power Sources,2001,97(08):503. |
[3] | Ho Chul Shin;Sung Bin Park;Ho Jang;Kyung Yoon Chung;Won Il Cho;Chang Sam Kim;Byung Won Cho .Rate performance and structural change of Cr-doped LiFePO{sub}4/C during cycling[J].Electrochimica Acta,2008(27):7946-7951. |
[4] | Delacourt C;Poizot P;Levasseur S et al.Size effects on carbon-free LiFePO4 powders[J].Electrochemical and Solid-State Letters,2006,9(07):A352. |
[5] | Ravet N;Chouinard Y;Magnan J F et al.EIectroactivity of natural and synthetic triphylite[J].Journal of Power Sources,2001,97-98:503. |
[6] | Wei-Jun Zhang .Comparison of the Rate Capacities of LiFePO_4 Cathode Materials[J].Journal of the Electrochemical Society,2010(10):A1040-A1046. |
[7] | Feng Yu;Jingjie Zhang;Yanfeng Yang;Guangzhi Song .Reaction mechanism and electrochemical performance of LiFePO_4/C cathode materials synthesized by carbothermal method[J].Electrochimica Acta,2009(28):7389-7395. |
[8] | 何雨石,廖小珍,马紫峰,原鲜霞,王保峰,蒋逸.LiFePO4/C复合正极材料的制备及其电化学性能研究[J].稀有金属材料与工程,2007(09):1644-1648. |
[9] | Ke Wang;Rui Cai;Tao Yuan;Xing Yu;Ran Ran;Zongping Shao .Process investigation, electrochemical characterization and optimization of LiFePO{sub}4/C composite from mechanical activation using sucrose as carbon source[J].Electrochimica Acta,2009(10):2861-2868. |
[10] | Bing Huang;Xiaodong Zheng;Dongmei Jia;Mi Lu .Design and synthesis of high-rate micron-sized, spherical LiFePO_4/C composites containing clusters of nano/microspheres[J].Electrochimica Acta,2010(3):1227-1231. |
[11] | Qian J F;Zhou M;Cao Y L et al.Template-free hydrothermal synthesis of nanoembossed mesoporous LiFePO4 microspheres for high-performance lithium-lon batteries[J].Journal of Physical Chemistry C,2010,114(08):3477. |
[12] | Yoshihiro Kadoma;Jung-Min Kim;Katsutoshi Abiko;Keitaro Ohtsuki;Koichi Ui;Naoaki Kumagai .Optimization of electrochemical properties of LiFePO_4/C prepared by an aqueous solution method using sucrose[J].Electrochimica Acta,2010(3):1034-1041. |
[13] | Wang Y;Wang J;Yang J et al.High-rate LiFePO4 electrode material synthesized by a novel route from FePO4 @2H2 O[J].Advanced Functional Materials,2006(16):2135. |
[14] | Fei Gao;Zhiyuan Tang;Jianjun Xue .Preparation and characterization of nano-particle LiFePO{sub}4 and LiFePO{sub}4/C by spray-drying and post-annealing method[J].Electrochimica Acta,2007(4):1939-1944. |
[15] | Linghui Yu;Qiaosheng Liu;Haihui Wang .Synthesis of LiFePO4-C cathode materials using a green and low-cost method[J].Ionics,2009(6):689-692. |
[16] | Xuedong Yan;Guiling Yang;Jing Liu;Yucui Ge;Haiming Xie;Xiumei Pan;Rongshun Wang .An effective and simple way to synthesize LiFePO_4/C composite[J].Electrochimica Acta,2009(24):5770-5774. |
[17] | Feng Yu;Jingjie Zhang;Yanfeng Yang;Guangzhi Song .Preparation and characterization of mesoporous LiFePO_4/C microsphere by spray drying assisted template method[J].Journal of Power Sources,2009(1):794-797. |
[18] | Di Zhang;Rui Cai;Yinke Zhou;Zongping Shao;Xiao-Zhen Liao;Zi-Feng Ma .Effect of milling method and time on the properties and electrochemical performance of LiFePO_4/C composites prepared by ball milling and thermal treatment[J].Electrochimica Acta,2010(8):2653-2661. |
[19] | 马新胜,徐永刚,黄新虎,张洁,徐云龙,于建国.PEG分子量对LiFePO4/C纳米复合正极材料结构与电化学性能的影响[J].合成化学,2010(04):410-414. |
[20] | 徐亮,徐峙晖,赖琼钰,陈联梅,吉晓洋.LiFePO4/C正极材料的液相合成及电化学性能研究[J].功能材料,2007(08):1316-1319. |
[21] | Wang L N;Zhan X C;Zhang Z G et al.A soft chemistry synthesis routine for LiFePO4/C using a novel carbon source[J].Journal of Alloys and Compounds,2008,456(1-2):461. |
[22] | Daiwon Choi;Prashant N. Kumta .Surfactant based sol-gel approach to nanostructured LiFePO_4 for high rate Li-ion batteries[J].Journal of Power Sources,2007(2):1064-1069. |
[23] | Yanghui Huang;Haibo Ren;Zhenghe Peng;Yunhong Zhou .Synthesis of LiFePO_4/carbon composite from nano-FePO_4 by a novel stearic acid assisted rheological phase method[J].Electrochimica Acta,2009(1):311-315. |
[24] | Jae-Kwang Kim;Jae-Won Choi;Ghanshyam S. Chauhan;Jou-Hyeon Ahn;Gil-Chan Hwang;Jin-Beom Choi;Hyo-Jun Ahn .Enhancement of electrochemical performance of lithium iron phosphate by controlled sol-gel synthesis[J].Electrochimica Acta,2008(28):8258-8264. |
[25] | Zhihui Xu;Liang Xu;Qiongyu Lai;Xiaoyang Ji .A PEG assisted sol-gel synthesis of LiFePO_4 as cathodic material for lithium ion cells[J].Materials Research Bulletin: An International Journal Reporting Research on Crystal Growth and Materials Preparation and Characterization,2007(5):883-891. |
[26] | Yong Zhang;Hui Feng;Xingbing Wu;Lizhen Wang;Aiqin Zhang;Tongchi Xia;Huichao Dong;Minghao Liu .One-step microwave synthesis and characterization of carbon-modified nanocrystalline LiFePO{sub}4[J].Electrochimica Acta,2009(11):3206-3210. |
[27] | Yung-Da Cho;George Ting-Kuo Fey;Hsien-Ming Kao .The effect of carbon coating thickness on the capacity of LiFePO_4/C composite cathodes[J].Journal of Power Sources,2009(1):256-262. |
[28] | Wilcox JD;Doeff MM;Marcinek M;Kostecki R .Factors influencing the quality of carbon coatings on LiFePO4[J].Journal of the Electrochemical Society,2007(5):A389-A395. |
[29] | 余红明,郑威,曹高劭,赵新兵.优化碳包覆对正极材料LiFePO_4/C高倍率性能的影响[J].物理化学学报,2009(11):2186-2190. |
[30] | 杨绍斌,于川,邱素芬.正极材料磷酸铁锂的复合掺碳改性研究[J].电源技术,2009(08):658-661. |
[31] | Xueliang Li;Weidong Wang;Chengwu Shi;Hua Wang;Yan Xing .Structural and electrochemical characterization of LiFePO_4/C prepared by a sol-gel route with long- and short-chain carbon sources[J].Journal of solid state electrochemistry,2009(6):921-926. |
[32] | Huseyin Goktepe;Halil Sahan;Fatma Kilic .Improved of cathode performance of LiFePO4/C composite using different carboxylic acids as carbon sources for lithium-ion batteries[J].Ionics,2010(3):203-208. |
[33] | Wang X;Huang Y;Jia D et al.Preparation and characterization of high-rate and long-cycle LiFePO4/C nanocomposite as cathode material for lithium-ion battery[J].Journal of Solid State Electrochemistry,2010,14:1. |
[34] | Yong Zhang;Hui Feng;Xingbing Wu;Lizhen Wang;Aiqin Zhang;Tongchi Xia;Huichao Dong;Minghao Liu .One-step microwave synthesis and characterization of carbon-modified nanocrystalline LiFePO{sub}4[J].Electrochimica Acta,2009(11):3206-3210. |
[35] | 张俊喜,曹小卫,张铃松,颜立成,张万友.LiFePO4表面碳包覆方法中碳源的碳化及碳源选择[J].化学通报(印刷版),2009(04):313-319. |
[36] | Ke Wang;Rui Cai;Tao Yuan;Xing Yu;Ran Ran;Zongping Shao .Process investigation, electrochemical characterization and optimization of LiFePO{sub}4/C composite from mechanical activation using sucrose as carbon source[J].Electrochimica Acta,2009(10):2861-2868. |
[37] | Yoshihiro Kadoma;Jung-Min Kim;Katsutoshi Abiko;Keitaro Ohtsuki;Koichi Ui;Naoaki Kumagai .Optimization of electrochemical properties of LiFePO_4/C prepared by an aqueous solution method using sucrose[J].Electrochimica Acta,2010(3):1034-1041. |
[38] | 王国宝,王先友,舒洪波,王英平.LiFePO_4/C复合材料的固相合成及碳源的影响[J].电池,2009(06):340-342. |
[39] | 张冬云,张培新,林木崇,刘琨,袁秋华,许启明,罗仲宽,任祥忠.碳包覆LiFePO4的结构与性能研究[J].无机材料学报,2011(03):265-270. |
[40] | 于锋,张敬杰,杨岩峰,宋广智.不同碳源对多孔球形LiFePO4/C复合材料的影响[J].无机化学学报,2009(01):42-46. |
[41] | Dragana Jugovic;Dragan Uskokovic .A review of recent developments in the synthesis procedures of lithium iron phosphate powders[J].Journal of Power Sources,2009(2):538-544. |
[42] | Hsu KF;Tsay SY;Hwang BJ .Synthesis and characterization of nano-sized LiFePO4 cathode materials prepared by a citric acid-based sol-gel route[J].Journal of Materials Chemistry: An Interdisciplinary Journal dealing with Synthesis, Structures, Properties and Applications of Materials, Particulary Those Associated with Advanced Technology,2004(17):2690-2695. |
[43] | Youyong Liu;Chuanbao Cao;Jing Li .Enhanced electrochemical performance of carbon nanospheres-LiFePO_4 composite by PEG based sol-gel synthesis[J].Electrochimica Acta,2010(12):3921-3926. |
[44] | L.Q. Sun;R.H. Cui;A.F. Jalbout;M.J. Li;X.M. Pan;R.S. Wang;H.M. Xie .LiFePO_4 as an optimum power cell material[J].Journal of Power Sources,2009(1):522-526. |
[45] | Lim H H;Jang I C;Lee S B et al.The important role of adipie acid on the synthesis of nanoerystalline lithium iron phosphate with high rate performance[J].Journal of Alloys and Compounds,2010,495(01):181. |
[46] | Zhaohui Chen;J. R. Dahn .Reducing Carbon in LiFePO_4/C Composite Electrodes to Maximize Specific Energy, Volumetric Energy, and Tap Density[J].Journal of the Electrochemical Society,2002(9):A1184-A1189. |
[47] | 习小明,刘鲁平,李运姣,彭明.共沉淀法制备LiFePO4/C复合材料的结构与性能[J].矿冶工程,2007(06):76-78. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%