埃洛石Al2Si2O5(OH)4·nH2O是一种天然的纳米管材料,基于其中空结构、高长径比、低羟基密度等特性,通过物理、化学手段进行修饰可以获得性能优异的新型功能材料,已成为材料、化学、物理、电子等多学科交叉研究的前沿领域.在介绍埃洛石纳米管结构特性的基础上,系统总结了天然纳米管通过功能修饰制备新材料的国内外最新研究进展,包括生态环境材料、催化材料、仿生材料、有机/无机杂化材料、生物医药材料和储能材料.阐述了其制备技术、表征手段、结构形貌和功能特性等,展示了这些新型功能材料的广阔应用前景.
参考文献
| [1] | Martienssen W;Wijn H P J;Kazei Z A.Magnetic properties of non-metallic inorganic compounds based on transition elements[M].Heidelberg:Springer Berlin Heidelberg,2009:301. |
| [2] | Yueping Ye;Haibin Chen;Jingshen Wu .High impact strength epoxy nanocomposites with natural nanotubes[J].Polymer: The International Journal for the Science and Technology of Polymers,2007(21):6426-6433. |
| [3] | Nicolini, K.P.;Fukamachi, C.R.B.;Wypych, F.;Mangrich, A.S. .Dehydrated halloysite intercalated mechanochemically with urea: Thermal behavior and structural aspects[J].Journal of Colloid and Interface Science,2009(2):474-479. |
| [4] | Luciana Guimaraes;Andrey N. Enyashin;Gotthard Seifert .Structural, Electronic, and Mechanical Properties of Single-Walled Halloysite Nanotube Models[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2010(26):11358-11363. |
| [5] | Viviana Vergaro;Elshad Abdullayev;Yuri M. Lvov .Cytocompatibility and Uptake of Halloysite Clay Nanotubes[J].Biomacromolecules,2010(3):820-826. |
| [6] | 郭宝春;贾德民;杜明亮 等.埃洛石纳米管用于制备聚合物复合材料的方法[P].中国,1746216,2006-03-15. |
| [7] | Yu YT;Qiu HB;Wu XW;Li HC;Li YS;Sakamoto Y;Inoue Y;Sakamoto K;Terasaki O;Che SN .Synthesis and characterization of silica nanotubes with radially oriented mesopores[J].Advanced functional materials,2008(4):541-550. |
| [8] | 李艳,张明侠,赵斌,张世民,阳明书.纳米反应器的研究进展[J].高分子通报,2002(01):24-33. |
| [9] | Tae JW;Jang BS;Kim JR;Kim I;Park DW .Catalytic degradation of polystyrene using acid-treated halloysite clays[J].Solid state ionics,2004(1/4):129-133. |
| [10] | 李宗敏,陈廷方,易发成.贵州遵义埃洛石对Sr、Co、Cs的吸附性能实验研究[J].西南科技大学学报,2007(03):33-37. |
| [11] | Wang J H;Zhang X;Zhang 15 et al.Rapid adsorption of Cr (Ⅵ) on modified halloysite nanotubes[J].Desalination,2010,259(02):22. |
| [12] | Wang X F;Zhou Y;Xu J J et al.Signal-on electrochemiluminescence biosensors based on CdS-carbon nanotube nanocomposite for the sensitive detection of choline and acetylcholin[J].Advanced Functional Materials,2009,19(09):1444. |
| [13] | Wang MS;Peng LM;Wang JY;Chen Q .Shaping carbon nanotubes and the effects on their electrical and mechanical properties[J].Advanced functional materials,2006(11):1462-1468. |
| [14] | Prato M .Controlled nanotube reactions[J].Nature,2010,465(7295):172. |
| [15] | 杨全红,刘敏,成会明,王茂章.纳米碳管的孔结构、相关物性和应用[J].材料研究学报,2001(04):375-386. |
| [16] | Cao XB;Gu L;Zhuge L;Gao WJ;Wang WC;Wu SF .Template-free preparation of hollow Sb2S3 microspheres as supports for Ag nanoparticles and photocatalytic properties of the constructed metal-semiconductor nanostructures[J].Advanced functional materials,2006(7):896-902. |
| [17] | Cuiping Li;Jiguang Liu;Xiaozhong Qu;Zhenzhong Yang .A General Synthesis Approach toward Halloysite-Based Composite Nanotube[J].Journal of Applied Polymer Science,2009(5):2647-2655. |
| [18] | 张道洪;王晶;李廷成 等.一种埃洛石固载铂催化剂及其制备方法和应用[P].中国专利,101879460,2010-01-10. |
| [19] | Fu YB;Zhang LD .Simultaneous deposition of Ni nanoparticles and wires on a tubular halloysite template: A novel metallized ceramic microstructure[J].International Journal of Quantum Chemistry,2005(11):3595-3600. |
| [20] | Yubin Fu;Xuerong Zai .Dielectric Properties of Ceramic Composite with Nanosized Ni on Tubular Halloysite Template Under High Frequency[J].Journal of nanoscience and nanotechnology,2009(3):1964-1971. |
| [21] | D. Papoulis;S. Komarneni;A. Nikolopoulou;P. Tsolis-Katagas;D. Panagiotaras;H.G. Kacandes;P. Zhang;S. Yin;T. Sato;H. Katsuki .Palygorskite- and Halloysite-TiO_2 nanocomposites: Synthesis and photocatalytic activity[J].Applied clay science,2010(1):118-124. |
| [22] | Fang M.;Grant PS.;McShane MJ.;Sukhorukov GB.;Golub VO.;Lvov YM. .Magnetic bio/nanoreactor with multilayer shells of glucose oxidase and inorganic nanoparticles[J].Langmuir: The ACS Journal of Surfaces and Colloids,2002(16):6338-6344. |
| [23] | Ruiz-Hitzky E;Katsuhiko A;Lvov Y M.Bio-inorganic hybrid nanomaterials strategies,syntheses,characterization and applications[M].Chembiochem:a European Journal of Chemical Biology,2008:2333. |
| [24] | Dmitry G. Shchukin;Gleb B. Sukhorukov;Ronald R. Price;Yuri M. Lvov .Halloysite Nanotubes as Biomimetic Nanoreactors[J].Small,2005(5):510-513. |
| [25] | Tierrablanca E;Romero-garcía J;Roman P et al.General biomimetic polymerization of aniline using hematin supported on halloysite nanotubes[J].Applied Catalysis A:General,2010,381(1-2):267. |
| [26] | Du ML;Guo BC;Jia DM .Thermal stability and flame retardant effects of halloysite nanotubes on poly(propylene)[J].European Polymer Journal,2006(6):1362-1369. |
| [27] | Liu MX;Guo BC;Du ML;Cai XJ;Jia DM .Properties of halloysite nanotube-epoxy resin hybrids and the interfacial reactions in the systems[J].Nanotechnology,2007(45):455703-1-455703-9-0. |
| [28] | Lvov Y M;Shchukin D G;M(6)hwald H et al.Halloysite clay nanotubes for controlled release of protective agents[J].ACS Nano,2008,2(05):814. |
| [29] | T.S.Omonov;C.Harrats;G.Groeninckx .Co-continuous and encapsulated three phase morphologies in uncompatibilized and reactively compatibilized polyamide 6/polypropylene/polystyrene ternary blends using two reactive precursors[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(26):12322-12336. |
| [30] | Liu, MX;Guo, BC;Du, ML;Chen, F;Jia, DM .Halloysite nanotubes as a novel beta-nucleating agent for isotactic polypropylene[J].Polymer: The International Journal for the Science and Technology of Polymers,2009(13):3022-3030. |
| [31] | Ning N Y;Yin Q J;Luo F et al.Crystallization behavior and mechanical properties of polypropylene/halloysite composites[J].Polymer,2007,48(25):7374. |
| [32] | Liu, M.;Jia, Z.;Liu, F.;Jia, D.;Guo, B. .Tailoring the wettability of polypropylene surfaces with halloysite nanotubes[J].Journal of Colloid and Interface Science,2010(1):186-193. |
| [33] | Mingliang Du;Baochun Guo;Demin Jia .Newly emerging applications of halloysite nanotubes: a review[J].Polymer international,2010(5):574-582. |
| [34] | Singh MK;Shokuhfar T;Gracio JJD;de Sousa ACM;Fereira JMD;Garmestani H;Ahzi S .Hydroxyapatite modified with carbon-nanotube-reinforced poly(methyl methacrylate): A nanocomposite material for biomedical applications[J].Advanced functional materials,2008(5):694-700. |
| [35] | Dmitri Fix;Daria V. Andreeva;Yuri M. Lvov;Dmitry C. Shchukin;Helmuth Moehwald .Application of Inhibitor-Loaded Halloysite Nanotubes in Active Anti-Corrosive Coatings[J].Advanced functional materials,2009(11):A1-A3,A5,A7. |
| [36] | Elshad Abdullayev;Ronald Priced Dmitry Shchukin;Yuri Lvov .Halloysite Tubes as Nanocontainers for Anticorrosion Coating with Benzotriazole[J].ACS applied materials & interfaces,2009(7):1437-1443. |
| [37] | Shchukin DG;Lamaka SV;Yasakau KA;Zheludkevich ML;Ferreira MGS;Mohwald H .Active anticorrosion coatings with halloysite nanocontainers[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(4):958-964. |
| [38] | Levis SR;Deasy PB .Use of coated microtubular halloysite for the sustained release of diltiazem hydrochloride and propranolol hydrochloride.[J].International Journal of Pharmaceutics,2003(1/2):145-157. |
| [39] | Levis S R;Deasy P B .Characterisation of halloysite for use as microtubular drug delivery system[J].Int Pharrnaceutics,2002,243(1-2):125. |
| [40] | Kelly HM;Deasy PB;Ziaka E;Claffey N .Formulation and preliminary in vivo dog studies of a novel drug delivery system for the treatment of periodontitis.[J].International Journal of Pharmaceutics,2004(1/2):167-183. |
| [41] | Veerabadran NG;Mongayt D;Torchilin V;Price RR;Lvov YM .Organized Shells on Clay Nanotubes for Controlled Release of Macromolecules[J].Macromolecular rapid communications: Publishing the newsletters of the European Polymer Federation,2009(2):99-103. |
| [42] | 席国喜;邢新艳;杨文洁 等.一种复合相变储能材料及其制备方法[P].中国,101798487,2010-08-11. |
| [43] | 陈荣峰;张冰;曹艳霞 .储氢材料埃洛石及其制备方法[P].中国,101070163,2007-11-14. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%